Abstract:
A method for predicting selective performance of an adsorbent is disclosed. The adsorbent is selected from a list of metals and/or metal cations for use in removing contaminants as thiophene derivatives in hydrocarbon feed. The metals or metal cations are identified from a list having a positive value for Erel, wherein the metal or metal cation having the largest value for Erel is the most selective adsorbent.
Abstract:
Acetic acid is produced by oxidation of methane with an oxygen-containing gas in the presence of an acid selected from concentrated sulfuric acid and fuming sulfuric acid, a palladium-containing catalyst and a promoter, preferably a copper or iron salt. The addition of a promoter and O2 to a system that includes a palladium-containing catalyst such as PdCl2 increases the rate of acetic acid formation from methane by more than an order of magnitude as compared with prior art and, in addition, inhibits the precipitation of Pd black.
Abstract:
A process for the production of lower alkyl alkoxyacetates, preferably methyl methoxyacetate, by reaction of a di-(lower alkoxy)methane, preferably dimethoxymethane, with the acid form of a medium-pore or large-pore zeolite catalyst, preferably the acid form of faujasite, ZSM-5, mordenite, or beta, in the gas phase at atmospheric or near-atmospheric pressures.
Abstract:
An ionized gas plasma is established in an electrical field in contact with a non-vapor volume monomer (liquid and/or solid). The plasma causes polymerization of the monomers which are of the phosphazene or carborane type.
Abstract:
An ionized gas plasma is established in an electrical field in contact with a non-vapor volume monomer (liquid and/or solid). The plasma causes polymerization of the monomers which are of the phosphazene or carborane type.
Abstract:
The present invention relates to a process for preparing high purity inorganic higher oxides of the alkali and alkaline earth metals by subjecting the hydroxide of the alkali or alkaline earth metal to a radio frequency discharge sustained in oxygen. The invention is particularly adaptable to the production of high purity potassium superoxide (KO.sub.2) by subjecting potassium hydroxide to glow discharge sustained in oxygen under the pressure of about 0.75 to 1.00 torr.
Abstract:
Acetyl anhydrides such as acetyl sulfate are produced by a process for comprising contacting methane and carbon dioxide in an anhydrous environment in the presence of effective amounts of a transition metal catalyst and a reaction promoter, and an acid anhydride compound, and optionally an acid. The acetyl anhydride can be contacted with water to produce acetic acid or with an alcohol to produce a product comprising an acetate ester and that may also comprise acetic acid. Optionally, water in stoichiometric amounts or less, with respect to the acetic anhydride, may be fed to a continuous process of this type to produce some acetic acid in situ.
Abstract:
An ionized gas plasma is established in an electrical field in contact with a non-vapor volume of monomer (liquid and/or solid). The plasma creates active polymerization sites in the monomer volume to initiate propagation of polymerization therein. After initiation, the partially-polymerized monomer volume is postpolymerized in the absence of the ionized gas plasma to yield a very high molecular weight polymer which may be essentially free of cross-linking in desirable forms including commercial quantities of bulk self-supporting polymer or a coating. Suitable monomers include liquid vinyl monomers (e.g., methyl, methacrylate) and solid crystalline monomers (e.g., 1,3,5-trioxane).
Abstract:
A method for predicting selective performance of an adsorbent is disclosed. The adsorbent is selected from a list of metals and/or metal cations for use in removing contaminants as thiophene derivatives in hydrocarbon feed. The metals or metal cations are identified from a list having a positive value for Erel, wherein the metal or metal cation having the largest value for Erel is the most selective adsorbent.
Abstract:
A process for the production of lower alkyl alkoxyacetates, preferably methyl methoxyacetate, by reaction of a di-(lower alkoxy)methane, preferably dimethoxymethane, with the acid form of a medium-pore or large-pore zeolite catalyst, preferably the acid form of faujasite, ZSM-5, mordenite, or beta, in the gas phase at atmospheric or near-atmospheric pressures.