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    Process for reducing chloride in hydrocarbon products using an ionic liquid catalyst
    2.
    发明授权
    Process for reducing chloride in hydrocarbon products using an ionic liquid catalyst 有权
    使用离子液体催化剂还原烃产物中的氯化物的方法

    公开(公告)号：US08969645B2

    公开(公告)日：2015-03-03

    申请号：US13715873

    申请日：2012-12-14

    申请人： Bi-Zeng Zhan ,  Hye Kyung Cho Timken ,  Michael Sean Driver

    发明人： Bi-Zeng Zhan ,  Hye Kyung Cho Timken ,  Michael Sean Driver

    IPC分类号： C07C7/10 ,  B01J31/26

    CPC分类号： C07C7/10 ,  B01D3/009 ,  B01J31/0284 ,  B01J31/0288 ,  B01J31/0289 ,  B01J31/26 ,  B01J2231/64 ,  C10G29/16

    摘要： We provide a process comprising: a. feeding a chlorinated-hydrocarbon and an ionic liquid catalyst to a treatment unit; b. operating the treatment unit at an elevated temperature to produce dechlorinated-hydrocarbon and HCl; and c. collecting the dechlorinated-hydrocarbon, wherein at least 90 wt % of the chlorides are removed. A second process comprises: a. creating an ionic liquid catalyst-rich zone in a distillation unit; b. passing chlorinated-hydrocarbon to the distillation unit; c. operating the unit under conditions causing removal of alkyl chloride to produce dechlorinated-hydrocarbon having a final boiling point close to a first final boiling point. A third process comprises: a. feeding alkylate gasoline blending component and ionic liquid catalyst to a treatment unit; b. operating the treatment unit; and c. collecting a dechlorinated-hydrocarbon, wherein at least 90 wt % of the chlorides have been removed and the dechlorinated-hydrocarbon has a second RON that is close to a first RON.

    摘要翻译： 我们提供一个过程，包括：a。 将氯代烃和离子液体催化剂供给到处理单元; b。 在升高的温度下操作处理单元以产生脱氯烃和HCl; 和c。 收集脱氯烃，其中除去至少90重量％的氯化物。 第二个过程包括：a。 在蒸馏单元中产生离子液体催化剂富集区; b。 将氯化烃通入蒸馏单元; C。 在引起去除烷基氯的条件下操作该单元以产生具有接近第一最终沸点的最终沸点的脱氯烃。 第三个过程包括：a。 将烷基化汽油调和组分和离子液体催化剂加入到处理单元中; b。 操作治疗单元; 和c。 收集脱氯烃，其中已除去至少90重量％的氯化物，脱氯烃具有接近第一RON的第二RON。

    Integration of hydro-dechlorination and hydro-regeneration
    3.
    发明授权
    Integration of hydro-dechlorination and hydro-regeneration 有权
    加氢脱氯和加氢再生的整合

    公开(公告)号：US08884091B2

    公开(公告)日：2014-11-11

    申请号：US13829620

    申请日：2013-03-14

    申请人： Bi-Zeng Zhan ,  Thomas Van Harris ,  Hye Kyung Cho Timken

    发明人： Bi-Zeng Zhan ,  Thomas Van Harris ,  Hye Kyung Cho Timken

    IPC分类号： C07C2/60 ,  C07C2/62 ,  C07C2/58

    CPC分类号： C07C2/58 ,  C10G29/205 ,  C10G45/02 ,  C10G45/10 ,  C10G69/123 ,  C10G2300/202 ,  C10G2400/02

    摘要： We provide an integrated process to produce alkylate gasoline, comprising: a. alkylating a mixture of hydrocarbons using a chloride-containing ionic liquid catalyst in an alkylation reactor to produce an alkylate gasoline comprising a chloride contaminant; b. hydro-regenerating the chloride-containing ionic liquid catalyst in a hydrogenation reactor; c. hydro-dechlorinating the alkylate gasoline comprising the chloride contaminant in a dechlorination reactor at a dechlorination pressure from 0 to 1000 psig of a hydrogenation pressure used in the hydrogenation reactor, to produce a dechlorinated alkylate gasoline; and d. feeding an off-gas, comprising 70 to 99.9 vol % hydrogen, from the dechlorination reactor to the hydrogenation reactor. We also provide an integrated alkylation process unit for conducting this process.

    摘要翻译： 我们提供生产烷基化汽油的综合方法，包括：a。 在烷基化反应器中使用含氯离子液体催化剂烷烃化烃类混合物以产生包含氯化物污染物的烷基化汽油; b。 在氢化反应器中对含氯离子液体催化剂进行加氢再生; C。 在脱氯反应器中，在氢化反应器中使用的氢化压力为0-1000psig的脱氯压力下，将包含氯化物污染物的烷基化汽油加氢脱氯，得到脱氯烷基化汽油; 和d。 将来自脱氯反应器的含有70至99.9体积％氢气的废气进料到氢化反应器。 我们还提供了一个整合的烷基化处理单元来进行这个过程。

    INTEGRATION OF HYDRO-DECHLORINATION AND HYDRO-REGENERATION
    4.
    发明申请
    INTEGRATION OF HYDRO-DECHLORINATION AND HYDRO-REGENERATION 有权
    氢化脱盐和水力再生的综合

    公开(公告)号：US20140275680A1

    公开(公告)日：2014-09-18

    申请号：US13829620

    申请日：2013-03-14

    申请人： Bi-Zeng Zhan ,  Thomas Van Harris ,  Hye Kyung Cho Timken

    发明人： Bi-Zeng Zhan ,  Thomas Van Harris ,  Hye Kyung Cho Timken

    IPC分类号： C07C2/58

    CPC分类号： C07C2/58 ,  C10G29/205 ,  C10G45/02 ,  C10G45/10 ,  C10G69/123 ,  C10G2300/202 ,  C10G2400/02

    摘要： We provide an integrated process to produce alkylate gasoline, comprising: a. alkylating a mixture of hydrocarbons using a chloride-containing ionic liquid catalyst in an alkylation reactor to produce an alkylate gasoline comprising a chloride contaminant; b. hydro-regenerating the chloride-containing ionic liquid catalyst in a hydrogenation reactor; c. hydro-dechlorinating the alkylate gasoline comprising the chloride contaminant in a dechlorination reactor at a dechlorination pressure from 0 to 1000 psig of a hydrogenation pressure used in the hydrogenation reactor, to produce a dechlorinated alkylate gasoline; and d. feeding an off-gas, comprising 70 to 99.9 vol % hydrogen, from the dechlorination reactor to the hydrogenation reactor. We also provide an integrated alkylation process unit for conducting this process.

    摘要翻译： 我们提供生产烷基化汽油的综合方法，包括：a。 在烷基化反应器中使用含氯离子液体催化剂烷烃化烃类混合物以产生包含氯化物污染物的烷基化汽油; b。 在氢化反应器中对含氯离子液体催化剂进行加氢再生; C。 在脱氯反应器中，在氢化反应器中使用的氢化压力为0-1000psig的脱氯压力下，将包含氯化物污染物的烷基化汽油加氢脱氯，得到脱氯烷基化汽油; 和d。 将来自脱氯反应器的含有70至99.9体积％氢气的废气进料到氢化反应器。 我们还提供了一个整合的烷基化处理单元来进行这个过程。

    Denitrification of a hydrocarbon feed
    5.
    发明授权
    Denitrification of a hydrocarbon feed 有权
    烃进料的脱氮

    公开(公告)号：US08540871B2

    公开(公告)日：2013-09-24

    申请号：US12847107

    申请日：2010-07-30

    申请人： Bi-Zeng Zhan ,  Akshay Verma ,  Zunqing He ,  Zhen Zhou ,  Marcus Dutra e Mello ,  Sheila Yeh

    发明人： Bi-Zeng Zhan ,  Akshay Verma ,  Zunqing He ,  Zhen Zhou ,  Marcus Dutra e Mello ,  Sheila Yeh

    IPC分类号： C10G25/12

    CPC分类号： C10G25/003 ,  C10G67/06 ,  C10G2300/1037 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2400/10

    摘要： A denitrification method is disclosed for removing nitrogen compounds from a hydrocarbon feed in which the feed is contacted with an adsorbent including an organic heterocyclic salt deposited on a porous support. Additionally, a method for hydrotreating a hydrocarbon feed which includes a hydroprocessing step is disclosed, wherein prior to hydroprocessing, the feed is contacted with an adsorbent including an organic heterocyclic salt deposited on a support. Additionally, a method for producing a lube oil which includes isomerization dewaxing of a base oil fraction is disclosed, wherein prior to the isomerization dewaxing step, the base oil fraction is contacted with an adsorbent including an organic heterocyclic salt deposited on a support.

    摘要翻译： 公开了一种用于从烃进料中除去氮化合物的脱氮方法，其中进料与包含沉积在多孔载体上的有机杂环盐的吸附剂接触。 另外，公开了一种加氢处理烃进料的方法，其包括加氢处理步骤，其中在加氢处理之前，将进料与包含沉积在载体上的有机杂环盐的吸附剂接触。 另外，公开了一种包含基油馏分的异构化脱蜡的润滑油的制造方法，其中在异构化脱蜡工序之前，使基油馏分与沉积在载体上的有机杂环盐的吸附剂接触。

    PROCESSES FOR UPGRADING FISCHER-TROPSCH CONDENSATE BY OLEFIN ENRICHMENT AND ALKYLATION OF HYDROCRACKATE
    6.
    发明申请
    PROCESSES FOR UPGRADING FISCHER-TROPSCH CONDENSATE BY OLEFIN ENRICHMENT AND ALKYLATION OF HYDROCRACKATE 有权
    通过烯烃富集和氢化烷烃的烷基化来提升固化剂 - 载体冷凝液的方法

    公开(公告)号：US20130206643A1

    公开(公告)日：2013-08-15

    申请号：US13765036

    申请日：2013-02-12

    申请人： Sven Ivar Hommeltoft ,  Bi-Zeng Zhan

    发明人： Sven Ivar Hommeltoft ,  Bi-Zeng Zhan

    IPC分类号： C10G57/00

    CPC分类号： C10G57/00 ,  C10G29/205 ,  C10G50/00 ,  C10G65/14 ,  C10G2300/1022 ,  C10G2300/1088

    摘要： Processes for upgrading Fischer-Tropsch condensate olefins by alkylation of hydrocrackate involves providing an olefin enriched condensate stream and further providing a Fischer-Tropsch derived hydrocarbon stream comprising wax, hydrocracking the latter Fischer-Tropsch hydrocarbon stream to provide a distillate enriched hydrocracked product comprising isoparaffins, and alkylating the olefins with the isoparaffins in an alkylation zone to provide an alkylate product. The alkylate product is fed to a distillation unit together with the hydrocracked product, while a naphtha containing fraction from the distillation unit is fed to the alkylation zone together with the olefin enriched hydrocarbon stream.

    摘要翻译： 通过加氢裂化烷基化来提高费 - 托冷凝物烯烃的方法涉及提供富含烯烃的冷凝物流，并进一步提供包含蜡的费 - 托衍生烃流，加氢裂化后者费 - 托烃流，以提供富含馏出物的加氢裂化产物，其包含异链烷烃， 并在烷基化区中用异链烷烃烷基化烯烃以提供烷基化产物。 将烷基化产物与加氢裂化产物一起进料到蒸馏单元，同时将含有蒸馏单元的含石脑油馏分与富含烯烃的烃流一起进料至烷基化区。

    PROCESSES FOR UPGRADING FISCHER-TROPSCH CONDENSATE OLEFINS BY ALKYLATION OF HYDROCRACKATE
    7.
    发明申请
    PROCESSES FOR UPGRADING FISCHER-TROPSCH CONDENSATE OLEFINS BY ALKYLATION OF HYDROCRACKATE 有权
    通过氢氯酸盐碱化来提升固化剂冷冻油的方法

    公开(公告)号：US20120160739A1

    公开(公告)日：2012-06-28

    申请号：US12975752

    申请日：2010-12-22

    申请人： Sven Ivar Hommeltoft ,  Bi-Zeng Zhan

    发明人： Sven Ivar Hommeltoft ,  Bi-Zeng Zhan

    IPC分类号： C10G69/12

    CPC分类号： C10G57/00 ,  C10G29/205 ,  C10G50/00 ,  C10G65/14 ,  C10G2300/1022 ,  C10G2300/1088

    摘要： Processes for upgrading Fischer-Tropsch condensate olefins by alkylation of hydrocrackate may involve providing an olefin enriched condensate stream and further providing a Fischer-Tropsch derived hydrocarbon stream comprising wax, hydrocracking the latter Fischer-Tropsch hydrocarbon stream to provide a distillate enriched hydrocracked product comprising isoparaffins, and alkylating the olefins with the isoparaffins in an alkylation zone to provide an alkylate product. The alkylate product may be fed to a distillation unit together with the hydrocracked product, while a naphtha containing fraction from the distillation unit may be fed to the alkylation zone together with the olefin enriched hydrocarbon stream.

    摘要翻译： 通过加氢裂化烷基化来提高费 - 托冷凝物烯烃的方法可包括提供富含烯烃的冷凝物流，并进一步提供包含蜡的费 - 托衍生烃流，加氢裂化后者费 - 托烃流，以提供富含馏出物的加氢裂化产物，其包含异链烷烃 ，并在烷基化区中用异链烷烃烷基化烯烃以提供烷基化产物。 烷基化产物可以与加氢裂化产物一起进料到蒸馏单元，而含有来自蒸馏单元的含石脑油馏分可与富含烯烃的烃流一起进料至烷基化区。