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公开(公告)号：US08043575B2
公开(公告)日：2011-10-25
申请号：US10815276
申请日：2004-04-01
申请人： Paul Michael McAllister , Alouisius Nicolaas Renee Bos , Michael Alan Richard , Dominicus Maria Rekers
发明人： Paul Michael McAllister , Alouisius Nicolaas Renee Bos , Michael Alan Richard , Dominicus Maria Rekers
CPC分类号： B01J35/026 , B01J8/067 , B01J19/30 , B01J23/50 , B01J23/66 , B01J23/688 , B01J2219/30223 , B01J2219/30416 , B01J2219/30475 , B01J2219/312 , C07D301/10
摘要： A reactor system for the oxidation of ethylene to ethylene oxide. The reactor system includes a reactor tube that contains a packed bed of shaped support material that can include a catalytic component. The shaped support material has a hollow cylinder geometric configuration. The reactor system has specific combinations of reactor tube and catalyst system geometries.
摘要翻译： 用于将乙烯氧化成环氧乙烷的反应器系统。 反应器系统包括反应器管，其包含可包括催化组分的成形载体材料的填充床。 成形的支撑材料具有中空圆筒几何构型。 反应器系统具有反应器管和催化剂体系几何形状的特定组合。
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公开(公告)号：US20090187055A1
公开(公告)日：2009-07-23
申请号：US12331867
申请日：2008-12-10
IPC分类号： C07C1/20
CPC分类号： C07C1/24 , C07C2521/04 , C07C15/46
摘要： The invention relates to a process for the preparation of styrene and/or a substituted styrene from a feed containing 1-phenylethanol and 2-phenylethanol and/or a substituted 1-phenylethanol and a substituted 2-phenylethanol, comprising a gas phase dehydration of the feed at elevated temperature in the presence of a catalyst comprising particles of alumina having a multimodal pore size distribution.
摘要翻译： 本发明涉及一种由含有1-苯基乙醇和2-苯基乙醇和/或取代的1-苯基乙醇和取代的2-苯基乙醇的原料制备苯乙烯和/或取代的苯乙烯的方法，该方法包括 在包含具有多峰孔径分布的氧化铝颗粒的催化剂的存在下在高温下进料。
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3.发明申请Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process 审中-公开在反应器中安装环氧化催化剂的方法，制备环氧化催化剂的方法，环氧化催化剂，制备烯烃氧化物的方法或可从烯烃氧化物衍生的化学品的方法，以及适用于这种方法的反应器公开(公告)号：US20080154052A1
公开(公告)日：2008-06-26
申请号：US11613763
申请日：2006-12-20
申请人： Jeroen Willem Bolk , Alouisius Nicolaas Renee Bos , Wayne Errol Evans , John Robert Lockemeyer , Paul Michael McAllister , Bernardus Franciscus Josef Marie Ramakers , Dominicus Maria Rekers , Mathias Jozef Paul Slapak
发明人： Jeroen Willem Bolk , Alouisius Nicolaas Renee Bos , Wayne Errol Evans , John Robert Lockemeyer , Paul Michael McAllister , Bernardus Franciscus Josef Marie Ramakers , Dominicus Maria Rekers , Mathias Jozef Paul Slapak
IPC分类号： C07D301/06 , C07D301/10
CPC分类号： C07D301/06 , C07D301/10
摘要： The present invention relates to an improved epoxidation process and an improved epoxidation reactor. The present invention makes use of a reactor which comprises a plurality of microchannels. Such process microchannels may be adapted such that the epoxidation and optionally other processes can take place in the microchannels and that they are in a heat exchange relation with channels adapted to contain a heat exchange fluid. A reactor comprising such process microchannels is referred to as a “microchannel reactor”. The invention also provides a method of installing an epoxidation catalyst in a microchannel reactor. The invention also provides a method of preparing an epoxidation catalyst. The invention also provides an epoxidation catalyst. The invention also provides a certain process for the epoxidation of an olefin and a process for the preparation of a chemical derivable from an olefin oxide. The invention also provides a microchannel reactor.
摘要翻译： 本发明涉及改进的环氧化方法和改进的环氧化反应器。 本发明利用包括多个微通道的反应器。 这种工艺微通道可以适于使得环氧化和任选的其它方法可以在微通道中发生，并且它们与适于容纳热交换流体的通道处于热交换关系。 将包含这种工艺微通道的反应器称为“微通道反应器”。 本发明还提供了一种在微通道反应器中安装环氧化催化剂的方法。 本发明还提供了制备环氧化催化剂的方法。 本发明还提供一种环氧化催化剂。 本发明还提供了烯烃环氧化的一定方法以及制备可衍生自烯烃氧化物的化学品的方法。 本发明还提供一种微通道反应器。
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4.发明申请Reverse flow reactor with integrated separation and process for the employing this reactor 失效具有集成分离的反流反应器和使用该反应器的方法公开(公告)号：US20090101584A1
公开(公告)日：2009-04-23
申请号：US11666074
申请日：2005-10-24
CPC分类号： B01D51/10 , B01D53/02 , B01D2253/10 , B01D2253/202 , B01D2257/204 , B01D2257/30 , B01D2257/80 , B01J8/0446 , B01J2208/00106 , B01J2208/00699 , B01J2208/00707 , B01J2208/025
摘要： The present invention pertains to a reverse-flow reactor comprising at least one catalyst bed which is preceded and followed by at least one bed containing selectively adsorbing material, and its application for in a process for the removal of contaminants from a process stream.
摘要翻译： 本发明涉及一种反流反应器，其包含至少一个催化剂床，其前面和后面是至少一个含有选择性吸附材料的床，以及其在从工艺流中除去污染物的方法中的应用。
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公开(公告)号：US20080154051A1
公开(公告)日：2008-06-26
申请号：US11613741
申请日：2006-12-20
申请人： Jeroen Willem Bolk , Alouisius Nicolaas Renee Bos , Wayne Errol Evans , John Robert Lockemeyer , Paul Michael Mcallister , Bernardus Franciscus Josef Marie Ramakers , Dominicus Maria Rekers , Mathias Jozef Paul Slapak
发明人： Jeroen Willem Bolk , Alouisius Nicolaas Renee Bos , Wayne Errol Evans , John Robert Lockemeyer , Paul Michael Mcallister , Bernardus Franciscus Josef Marie Ramakers , Dominicus Maria Rekers , Mathias Jozef Paul Slapak
IPC分类号： C07D301/06 , C07D301/10
CPC分类号： C07D301/10 , C07D301/06
摘要： The present invention relates to an improved epoxidation process and an improved epoxidation reactor. The present invention makes use of a reactor which comprises a plurality of microchannels. Such process microchannels may be adapted such that the epoxidation and optionally other processes can take place in the microchannels and that they are in a heat exchange relation with channels adapted to contain a heat exchange fluid. A reactor comprising such process microchannels is referred to as a “microchannel reactor”. The invention also provides a method of installing an epoxidation catalyst in a microchannel reactor. The invention also provides a method of preparing an epoxidation catalyst. The invention also provides an epoxidation catalyst. The invention also provides a certain process for the epoxidation of an olefin and a process for the preparation of a chemical derivable from an olefin oxide. The invention also provides a microchannel reactor.
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6.发明授权公开(公告)号：US07547795B2
公开(公告)日：2009-06-16
申请号：US11775100
申请日：2007-07-09
申请人： Marek Matusz , Michael Alan Richard , John Robert Lockemeyer , Alouisius Nicolaas Renee Bos , Dominicus Maria Rekers , Donald Reinalda , Randall Clayton Yeates , Paul Michael McAllister
发明人： Marek Matusz , Michael Alan Richard , John Robert Lockemeyer , Alouisius Nicolaas Renee Bos , Dominicus Maria Rekers , Donald Reinalda , Randall Clayton Yeates , Paul Michael McAllister
IPC分类号： C07D303/00 , C07D301/10 , C07D301/03 , B01J23/50
CPC分类号： B01J23/58 , B01J23/50 , B01J23/63 , B01J23/683 , B01J23/688 , B01J35/02 , B01J35/026 , B01J35/1009 , B01J35/1014 , B01J37/0203 , B01J37/0213 , C07D301/10
摘要： A high activity and high selectivity silver catalyst comprising silver and, optionally, one or more promoters supported on a suitable support material having the form of a shaped agglomerate. The structure of the shaped agglomerate is that of a hollow cylinder having a relatively small inside (bore) diameter. The catalyst is made by providing the shaped material of a particular geometry and incorporating the catalytic components therein. The catalyst is useful in the epoxidation of ethylene.
摘要翻译： 一种高活性和高选择性的银催化剂，其包含银和任选的一种或多种支持在具有成形附聚物形式的合适载体材料上的助催化剂。 成形附聚物的结构是具有相对较小的内径（孔）直径的中空圆柱体的结构。 催化剂通过提供具有特定几何形状的成形材料并将其中的催化组分并入而制成。 该催化剂可用于乙烯的环氧化。
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7.发明授权公开(公告)号：US07259129B2
公开(公告)日：2007-08-21
申请号：US10816543
申请日：2004-04-01
申请人： Marek Matusz , Michael Alan Richard , John Robert Lockemeyer , Alouisius Nicolaas Renee Bos , Dominicus Maria Rekers , Donald Reinalda , Randall Clayton Yeates
发明人： Marek Matusz , Michael Alan Richard , John Robert Lockemeyer , Alouisius Nicolaas Renee Bos , Dominicus Maria Rekers , Donald Reinalda , Randall Clayton Yeates
IPC分类号： B01J23/50
CPC分类号： B01J37/0213 , B01J23/50 , B01J23/58 , B01J23/63 , B01J23/683 , B01J23/688 , B01J35/026 , B01J35/10 , B01J35/1009 , B01J37/0203 , C07D301/08 , C07D301/10
摘要： A high activity and high selectivity silver catalyst comprising silver and, optionally, one or more promoters supported on a suitable support material having the form of a shaped agglomerate. The structure of the shaped agglomerate is that of a hollow cylinder having a relatively small inside (bore) diameter. The catalyst is made by providing the shaped material of a particular geometry and incorporating the catalytic components therein. The catalyst is useful in the epoxidation of ethylene.
摘要翻译： 一种高活性和高选择性的银催化剂，其包含银和任选的一种或多种支持在具有成形附聚物形式的合适载体材料上的助催化剂。 成形附聚物的结构是具有相对较小的内径（孔）直径的中空圆柱体的结构。 催化剂通过提供具有特定几何形状的成形材料并将其中的催化组分并入而制成。 该催化剂可用于乙烯的环氧化。
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公开(公告)号：US20090234144A1
公开(公告)日：2009-09-17
申请号：US11886800
申请日：2006-03-20
IPC分类号： C07D301/10 , B01J8/06
CPC分类号： C07D301/10 , B01J8/067 , B01J19/30 , B01J21/04 , B01J23/683 , B01J23/688 , B01J2219/30223 , B01J2219/30416 , B01J2219/30475 , Y02P20/52
摘要： A reactor system for the epoxidation of ethylene, which reactor system comprises an elongated tube having an internal tube diameter of more than 40 mm, wherein contained is a catalyst bed of catalyst particles comprising silver and a promoter component deposited on a carrier, which promoter component comprises an element selected from rhenium, tungsten, molybdenum and chromium; a process for the epoxidation of ethylene comprising reacting ethylene with oxygen in the presence of the catalyst bed contained in the reactor system; and a method of preparing ethylene glycol, an ethylene glycol ether or an ethanol amine comprising obtaining ethylene oxide by the process for the epoxidation of ethylene, and converting the ethylene oxide into ethylene glycol, the ethylene glycol ether, or the ethanol amine. Preferably, the internal tube diameter is at least 45 mm.
摘要翻译： 一种用于乙烯环氧化的反应器系统，该反应器系统包括内管直径大于40mm的细长管，其中包含催化剂床的催化剂床，所述催化剂颗粒包含银和沉积在载体上的助催化剂组分，该促进剂组分 包括选自铼，钨，钼和铬的元素; 一种乙烯环氧化方法，包括在反应器系统中包含的催化剂床存在下使乙烯与氧反应; 以及制备乙二醇，乙二醇醚或乙醇胺的方法，包括通过乙烯环氧化方法获得环氧乙烷，并将环氧乙烷转化为乙二醇，乙二醇醚或乙醇胺。 优选地，内管直径至少为45mm。
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