公开(公告)号：US06423865B1

公开(公告)日：2002-07-23

申请号：US09516511

申请日：2000-03-01

申请人： Peter Strohriegl ,  Katja Strelzyk ,  Andreas Stohr ,  Petra Grundig ,  Michael Gailberger ,  Fritz Dannenhauer ,  Anne Barth

发明人： Peter Strohriegl ,  Katja Strelzyk ,  Andreas Stohr ,  Petra Grundig ,  Michael Gailberger ,  Fritz Dannenhauer ,  Anne Barth

IPC分类号： C07C6976

CPC分类号： C07D493/04 ,  C07C69/54 ,  C07C69/92 ,  C07J9/00 ,  C09K19/126 ,  C09K19/2007 ,  C09K19/2021 ,  C09K19/36 ,  C09K2019/0448

摘要： The invention relates to compounds with the general formula Y1—A1—M1—A2—Y2 wherein Y1 and Y2 are different from each other and Y1 is an acrylate or methacrylate residue and Y2 is a vinyl ether, epoxy, or azide residue, A1 and A2 are identical or different residues with the general formula CnH2n in which n is a whole number from 0 to 20 and one or more methylene groups can be replaced by oxygen atoms, and M1 has the general formula —R1—X1—R2—X2—R3—X3—R4— wherein R1, R2, R3, and R4 are identical or different doubly bonded residues from the group —O—, —COO—, —CONH—, —CO—, —S—, —C≡C—, —CH═CH—, —CH═N—, —CH2—, —N═N—, and —N═N(O)—, and R2—X2—R3 can also be a C—C bond, and X1, X2, and X3 are identical or different residues from the group 1,4-phenylene, 1,4-cyclohexylene; arylalkane or heteroarylalkane with 1 to 10 carbon atoms which contains one to three heteroatoms from the group O, N, and S, substituted with B1, B2, and/or B3; and cycloalkylene with 1 to 10 carbon atoms and substituted with B1, B2, and/or B3, wherein B1, B2, and B3 can be identical or different substituents from the group —H, C1-C20-alkyl, C1-C20-alkoxy, C1-C20- alkylthio, C1-C20-alkylcarbonyl, C1-C20-alkoxycarbonyl, C1-C20-alkylthiocarbonyl, —OH, halogen (fluorine, chlorine, bromine, iodine), —CN, —NO2, cycloalkyl, formyl, acetyl, and alkyl, alkoxy, or alkylthio residues with 1-20 carbon atoms interrupted by ether oxygen, thioether sulfur, or ester groups.

摘要翻译： 本发明涉及具有通式Y1-A1-M1-A2-Y2的化合物，其中Y1和Y2彼此不同，Y1是丙烯酸酯或甲基丙烯酸酯残基，Y2是乙烯基醚，环氧基或叠氮化物残基A1和A2 是具有通式C n H 2n的相同或不同的残基，其中n是0至20的整数，一个或多个亚甲基可被氧原子替代，并且M 1具有通式-R 1 -X 1 -R 2 -X 2 -R 3 - X 3 -R 4 - ，其中R 1，R 2，R 3和R 4是与-O - ， - COO - ， - CONH - ， - CO - ， - S - ， - C = = CH-，-CH = N-，-CH 2 - ， - N = N-，-N = N（O） - ，R2-X2-R3也可以是CC键，X 1，X 2和X 3 与1,4-亚苯基，1,4-亚环己基基团相同或不同的残基; 具有1至10个碳原子的芳基烷烃或杂芳基烷烃，其含有1至3个被B1，B2和/或B3取代的O，N和S的杂原子; 和具有1至10个碳原子并被B1，B2和/或B3取代的亚环烷基，其中B1，B2和B3可以是相同或不同的取代基，基团-H，C1-C20-烷基，C1-C20-烷氧基 ，C 1 -C 20烷硫基，C 1 -C 20烷基羰基，C 1 -C 20烷氧基羰基，C 1 -C 20烷硫基羰基，-OH，卤素（氟，氯，溴，碘），-CN，-NO 2，环烷基，甲酰基， 和具有1-20个碳原子的烷基，烷氧基或烷硫基残基被醚氧，硫醚硫或酯基间隔开。

公开(公告)号：US06313326B1

公开(公告)日：2001-11-06

申请号：US09526756

申请日：2000-03-16

申请人： Peter Strohriegl ,  Katja Strelzyk ,  Andreas Stohr ,  Petra Grundig ,  Michael Gailberger ,  Fritz Dannenhauer ,  Anne Barth

发明人： Peter Strohriegl ,  Katja Strelzyk ,  Andreas Stohr ,  Petra Grundig ,  Michael Gailberger ,  Fritz Dannenhauer ,  Anne Barth

IPC分类号： C07D30316

CPC分类号： C07D493/04 ,  C07C69/54 ,  C07C69/92 ,  C07J9/00 ,  C09K19/126 ,  C09K19/2007 ,  C09K19/2021 ,  C09K19/36 ,  C09K2019/0448

摘要： The invention relates to compounds with the general formula Y1—A1—M1—A2—Y2 wherein Y1 and Y2 are different from each other and Y1 is an acrylate or methacrylate residue and Y2 is a vinyl ether, epoxy, or azide residue, A1 and A2 are identical or different residues with the general formula CnH2n in which n is a whole number from 0 to 20 and one or more methylene groups can be replaced by oxygen atoms, and M1 has the general formula —R1—X1—R2—X2—R3—X3—R4— wherein R1, R2, R3, and R4 are identical or different doubly bonded residues from the group —O—, —COO—, —CONH—, —CO—, —S—, —C≡C—, —CH═CH—, —CH═N—, —CH2—, —N═N—, and —N═N(O)—, and R2—X2—R3 can also be a C—C bond, and X1, X2, and X3 are identical or different residues from the group 1,4-phenylene, 1,4-cyclohexylene; arylalkane or heteroarylalkane with 1 to 10 carbon atoms which contains one to three heteroatoms from the group O, N, and S, substituted with B1, B2, and/or B3; and cycloalkylene with 1 to 10 carbon atoms and substituted with B1, B2, and/or B3, wherein B1, B2, and B3 can be identical or different substituents from the group —H, C1-C20-alkyl, C1-C20-alkoxy, C1-C20-alkylthio, C1-C20-alkylcarbonyl, C1-C20-alkoxycarbonyl, C1-C20-alkylthiocarbonyl, —OH, halogen(fluorine, chlorine, bromine, iodine), —CN, —NO2, cycloalkyl, formyl, acetyl, and alkyl, alkoxy, or alkylthio residues with 1-20 carbon atoms interrupted by ether oxygen, thioether sulfur, or ester groups.

摘要翻译： 本发明涉及具有通式Y1-A1-M1-A2-Y2的化合物，其中Y1和Y2彼此不同，Y1是丙烯酸酯或甲基丙烯酸酯残基，Y2是乙烯基醚，环氧基或叠氮化物残基A1和A2 是具有通式C n H 2n的相同或不同的残基，其中n是0至20的整数，一个或多个亚甲基可被氧原子替代，并且M 1具有通式-R 1 -X 1 -R 2 -X 2 -R 3 - X 3 -R 4 - ，其中R 1，R 2，R 3和R 4是与-O - ， - COO - ， - CONH - ， - CO - ， - S - ， - C = = CH-，-CH = N-，-CH 2 - ， - N = N-，-N = N（O） - ，R2-X2-R3也可以是CC键，X 1，X 2和X 3 与1,4-亚苯基，1,4-亚环己基基团相同或不同的残基; 具有1至10个碳原子的芳基烷烃或杂芳基烷烃，其含有1至3个被B1，B2和/或B3取代的O，N和S的杂原子; 和具有1至10个碳原子并被B1，B2和/或B3取代的亚环烷基，其中B1，B2和B3可以是相同或不同的取代基，基团-H，C1-C20-烷基，C1-C20-烷氧基 ，C 1 -C 20烷硫基，C 1 -C 20烷基羰基，C 1 -C 20烷氧基羰基，C 1 -C 20烷硫基羰基，-OH，卤素（氟，氯，溴，碘），-CN，-NO 2，环烷基，甲酰基， 和具有1-20个碳原子的烷基，烷氧基或烷硫基残基被醚氧，硫醚硫或酯基间隔开。

公开(公告)号：US6049000A

公开(公告)日：2000-04-11

申请号：US953976

申请日：1997-10-20

申请人： Peter Strohriegl ,  Katja Strelzyk ,  Andreas Stohr ,  Petra Grundig ,  Michael Gailberger ,  Fritz Dannenhauer ,  Anne Barth

发明人： Peter Strohriegl ,  Katja Strelzyk ,  Andreas Stohr ,  Petra Grundig ,  Michael Gailberger ,  Fritz Dannenhauer ,  Anne Barth

IPC分类号： C07C69/54 ,  C07C69/92 ,  C07C233/65 ,  C07C245/02 ,  C07C251/02 ,  C07C255/54 ,  C07C291/08 ,  C07C323/10 ,  C07C323/50 ,  C07D493/04 ,  C07J9/00 ,  C08F2/48 ,  C08F4/32 ,  C08F220/10 ,  C08F290/12 ,  C08F299/00 ,  C08G81/02 ,  C09D133/04 ,  C09D155/00 ,  C09K19/12 ,  C09K19/20 ,  C09K19/36 ,  C09K19/38

CPC分类号： C07D493/04 ,  C07C69/54 ,  C07C69/92 ,  C07J9/00 ,  C09K19/126 ,  C09K19/2007 ,  C09K19/2021 ,  C09K19/36 ,  C09K2019/0448

摘要： The invention relates to compounds with the general formula Y.sup.1 --A.sup.1 --M.sup.1 --A.sup.2 --Y.sup.2 whereinY.sup.1 and Y.sup.2 are different from each other and Y.sup.1 is an acrylate or methacrylate residue and Y.sup.2 is a vinyl ether, epoxy, or azide residue,A.sup.1 and A.sup.2 are identical or different residues with the general formula C.sub.n H.sub.2n in which n is a whole number from 0 to 20 and one or more methylene groups can be replaced by oxygen atoms, andM.sup.1 has the general formula --R.sup.1 --X.sup.1 --R.sup.2 --X.sup.2 --R.sup.3 --X.sup.3 --R.sup.4 -- whereinR.sup.1, R.sup.2, R.sup.3, and R.sup.4 are identical or different doubly bonded residues from the group --O--, --COO--, --CONH--, --CO--, --S--, --C.tbd.C--, --CH.dbd.CH--, --CH.dbd.N--, --CH.sub.2 --, --N.dbd.N--, and --N.dbd.N(O)--, and R.sup.2 --X.sup.2 --R.sup.3 can also be a C--C bond, andX.sup.1, X.sup.2, and X.sup.3 are identical or different residues from the group 1,4-phenylene, 1,4-cyclohexylene; arylalkane or heteroarylalkane with 1 to 10 carbon atoms which contains one to three heteroatoms from the group O, N, and S, substituted with B.sup.1, B.sup.2, and/or B.sup.3 ; and cycloalkylene with 1 to 10 carbon atoms and substituted with B.sup.1, B.sup.2, and/or B.sup.3, wherein B.sup.1, B.sup.2, and B.sup.3 can be identical or different substituents from the group --H, C.sub.1 -C.sub.20 -alkyl, C.sub.1 -C.sub.20 -alkoxy, C.sub.1 -C.sub.20 -alkylthio, C.sub.1 -C.sub.20 -alkylcarbonyl, C.sub.1 -C.sub.20 -alkoxycarbonyl, C.sub.1 -C.sub.20 -alkylthiocarbonyl, --OH, halogen (fluorine, chlorine, bromine, iodine), --CN, --NO.sub.2, cycloalkyl, formyl, acetyl, and alkyl, alkoxy, or alkylthio residues with 1-20 carbon atoms interrupted by ether oxygen, thioether sulfur, or ester groups.

摘要翻译： 本发明涉及具有通式Y1-A1-M1-A2-Y2的化合物，其中Y1和Y2彼此不同，Y1是丙烯酸酯或甲基丙烯酸酯残基，Y2是乙烯基醚，环氧基或叠氮化物残基，A1和 A2是具有通式C n H 2n的相同或不同的残基，其中n是0至20的整数，并且一个或多个亚甲基可以被氧原子替代，并且M1具有通式-R1-X1-R2-X2- R3-X3-R4-，其中R1，R2，R3和R4是与-O - ， - COO - ， - CONH - ， - CO - ， - S - ， - ，-CH = CH-，-CH = N-，-CH 2 - ， - N = N-，-N = N（O） - ，R2-X2-R3也可以是CC键，X1，X2 ，X3是与1,4-亚苯基，1,4-亚环己基， 具有1至10个碳原子的芳基烷烃或杂芳基烷烃，其含有1至3个被B1，B2和/或B3取代的O，N和S的杂原子; 和具有1至10个碳原子并被B1，B2和/或B3取代的亚环烷基，其中B1，B2和B3可以是相同或不同的取代基，基团-H，C1-C20-烷基，C1-C20-烷氧基 ，C 1 -C 20烷硫基，C 1 -C 20烷基羰基，C 1 -C 20烷氧基羰基，C 1 -C 20烷硫基羰基，-OH，卤素（氟，氯，溴，碘），-CN，-NO 2，环烷基，甲酰基， 和具有1-20个碳原子的烷基，烷氧基或烷硫基残基被醚氧，硫醚硫或酯基间隔开。

公开(公告)号：US5691053A

公开(公告)日：1997-11-25

申请号：US441686

申请日：1995-05-15

申请人： Michael Gailberger ,  Anne Barth ,  Hans Ruetger Kricheldorf ,  Volkmar Vill ,  Mihai Gurau ,  Matthias Berghahn

发明人： Michael Gailberger ,  Anne Barth ,  Hans Ruetger Kricheldorf ,  Volkmar Vill ,  Mihai Gurau ,  Matthias Berghahn

IPC分类号： B05D7/24 ,  B05D7/14 ,  C09D5/00 ,  C09D5/26 ,  C09D5/29 ,  C09D5/36 ,  C09D5/46 ,  C09D167/00 ,  C09K19/38 ,  B32B19/00

CPC分类号： C09D5/36 ,  Y10T428/29 ,  Y10T428/31786

摘要： A coating material and coating process for color coating articles, such as motor vehicle bodies, and coated articles produced therewith. The coating contains a paint vehicle composed of at least one curable liquid-crystal polymer (LCP), the colored appearance of the coating being determined by mesogens of the paint vehicle which exhibit an interference effect, the mesogens automatically aligning themselves substantially perpendicular to the surface of the article during application of the coating material and adopting a chiral-nematic configuration in which they form a helix having a pitch length which can be influenced by heat within a specified temperature range. The liquid-crystal polymers are such that they are not crosslinked by heat and also such that the temperature level at which the pitch length of the helix can be influenced is above the temperature at which the color coated article is used. By heating an applied but uncrosslinked coating to a temperature within the specified range, the color of the coating can be adjusted in situ to obtain a desired interference color effect after the coating has been applied to the article, and the heat-adjusted color effect can thereafter be stabilized by rapid cooling and/or by UV irradiation of the coat. The color-determining substance of the paint vehicle and the essential substance of the paint vehicle itself are identical and form a coherent homogeneous layer of a cured liquid-crystal polymer.

摘要翻译： 用于彩色涂布制品（例如机动车身体）和由其制造的涂覆制品的涂覆材料和涂覆方法。 涂料含有由至少一种可固化液晶聚合物（LCP）组成的涂料载体，涂料的着色外观由涂料载体的介晶确定，其表现出干扰效应，介晶自动将其本身基本垂直于表面 并且采用手征向列配置，其中它们形成具有在特定温度范围内受热影响的节距长度的螺旋。 液晶聚合物使得它们不会被热交联，并且也使得螺旋线的节距长度受到影响的温度水平高于使用彩色涂层制品的温度。 通过将施加但未交联的涂层加热到指定范围内的温度，可以在将涂层施加到制品上之后，原位调节涂层的颜色以获得期望的干涉色彩效果，并且热调色彩效果 然后通过快速冷却和/或通过UV涂覆来稳定。 油漆车辆的着色物质和油漆车辆本身的基本物质是相同的，并形成固化的液晶聚合物的粘合均匀层。