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    Process for preparing a transition metal compound and it's use as a component in an olefin polymerization catalyst
    1.
    发明授权
    Process for preparing a transition metal compound and it's use as a component in an olefin polymerization catalyst 失效
    制备过渡金属化合物的方法及其作为烯烃聚合催化剂中的组分使用

    公开(公告)号：US4111834A

    公开(公告)日：1978-09-05

    申请号：US688545

    申请日：1976-05-21

    申请人： Anthony David Caunt ,  Ian Gabriel Williams

    发明人： Anthony David Caunt ,  Ian Gabriel Williams

    IPC分类号： C08F4/00 ,  B01J31/00 ,  C07F7/28 ,  C07F11/00 ,  C08F4/60 ,  C08F4/62 ,  C08F4/64 ,  C08F10/00 ,  B01J31/02

    CPC分类号： C08F10/00

    摘要： A solid compound of a transition metal is ground in the presence of aluminium chloride, titanium tetrachloride and at least one organo-Lewis Base compound. The transition metal compound is typically titanium trichloride. The Lewis Base compound is an organo-phosphorus compound, preferably one which also contains nitrogen, such as 2-dimethylamino-1,3-dimethyl-1,3,2-diazaphospholidine-2-oxide or an organo-sulphur compound such as diphenyl sulphone. The solid compound of the transition metal may include aluminium chloride and if the amount of this aluminium chloride is at least 50% molar, there is no need to make a separate addition of aluminium chloride to the mixture which is ground. The ground product can be used as a component of an olefine polymerization catalyst.

    摘要翻译： 在氯化铝，四氯化钛和至少一种有机 - 路易斯碱化合物的存在下研磨过渡金属的固体化合物。 过渡金属化合物通常是三氯化钛。 路易斯碱化合物是有机磷化合物，优选含有氮的有机磷化合物，例如2-二甲基氨基-1,3-二甲基-1,3,2-二氮杂磷杂环丁烷-2-氧化物或有机硫化合物如二苯基 sulphone 过渡金属的固体化合物可以包括氯化铝，并且如果该氯化铝的量为至少50摩尔％，则不需要对被研磨的混合物单独加入氯化铝。 研磨产物可用作烯烃聚合催化剂的组分。

    Olefine polymerization catalyst
    2.
    发明授权
    Olefine polymerization catalyst 失效
    Olefine聚合催化剂

    公开(公告)号：US3940345A

    公开(公告)日：1976-02-24

    申请号：US367002

    申请日：1973-06-04

    申请人： Anthony David Caunt

    发明人： Anthony David Caunt

    IPC分类号： C07F9/572 ,  C07F9/6509 ,  C07F9/6584 ,  C08F4/62 ,  C08F110/00 ,  B01J27/14 ,  B01J27/16 ,  B01J31/12 ,  B01J31/14

    CPC分类号： C07F9/65848 ,  C07F9/5721 ,  C07F9/650958 ,  C08F110/00

    摘要： An olefine polymerisation catalyst includes a solid compound of a transition metal, e.g. titanium trichloride, an organo-compound of a non-transition metal, e.g. aluminium triethyl or diethyl aluminium chloride and a pentavalent phosphorus compound of the typeR.sub.3.sub.-n P(Q)(E--Z--G),e.g.[(CH.sub.3).sub.2 N].sub.2 P(O)N(CH.sub.3)CH.sub.2 CH.sub.2 N(CH.sub.3).sub.2and(CH.sub.3).sub.2 NP(O)[OCH.sub.2 CH.sub.2 N(CH.sub.3).sub.2 ].sub.2The transition metal compound can be ball-milled in the presence of a further compound which can be the specified phosphorus compound or an electron donor compound, e.g., triphenylphosphine oxide. Using catalysts of this type, a combination of high activity and high stereospecificity can be obtained when polymerising an olefine monomer.

    摘要翻译： 烯烃聚合催化剂包括过渡金属的固体化合物，例如 三氯化钛，非过渡金属的有机化合物，例如， 三乙基铝或二乙基氯化铝和R3-nP（Q）（E-Z-G）类型的五价磷化合物，例如。

    Treatment of transition metal compound
    3.
    发明授权
    Treatment of transition metal compound 失效
    过渡金属化合物的处理

    公开(公告)号：US4108796A

    公开(公告)日：1978-08-22

    申请号：US627451

    申请日：1975-10-30

    申请人： Anthony David Caunt ,  Michael Stanley Fortuin ,  Ian Gabriel Williams

    发明人： Anthony David Caunt ,  Michael Stanley Fortuin ,  Ian Gabriel Williams

    IPC分类号： C08F4/00 ,  B01J31/14 ,  B01J31/18 ,  C01G23/02 ,  C08F2/00 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00 ,  B01J31/02

    CPC分类号： B01J31/1855 ,  B01J31/143 ,  B01J31/1845 ,  C08F10/00 ,  B01J2531/46 ,  Y10S526/906

    摘要： A titanium trihalide is ground with an organic Lewis Base compound which contains at least one phosphorus atom, and optionally at least one nitrogen atom, and a titanium tetrahalide, the Lewis Base and the titanium tetrahalide being used in amounts of 5 to 75, preferably 5 to 50%, molar and 1 to 50, preferably 5 to 30% molar respectively relative to the titanium trihalide. The materials are conveniently milled together and the milled product can be used as a component of an olefine polymerization catalyst and when such catalysts are used to polymerize propylene a high activity is achieved together with satisfactory stereospecificity.

    摘要翻译： 将三卤化钛用含有至少一个磷原子的有机路易斯碱化合物和任选的至少一个氮原子和四卤化钛研磨，路易斯碱和四卤化钛的用量为5至75，优选5 至50％，摩尔，1至50，优选5至30％摩尔。 将材料方便地研磨在一起，并且研磨的产物可以用作烯烃聚合催化剂的组分，并且当这种催化剂用于聚合丙烯时，可以获得高的活性和令人满意的立体定向性。

    Process for the production of olefin polymers using an organo-phosphorus catalyst compound
    4.
    发明授权
    Process for the production of olefin polymers using an organo-phosphorus catalyst compound 失效
    使用有机磷光催化剂化合物生产烯烃聚合物的方法

    公开(公告)号：US4098976A

    公开(公告)日：1978-07-04

    申请号：US670134

    申请日：1976-03-25

    申请人： Anthony David Caunt

    发明人： Anthony David Caunt

    IPC分类号： B01J31/26 ,  C08F4/646 ,  C08F10/00 ,  C08F110/00 ,  C08F4/66 ,  C08F10/06

    CPC分类号： B01J31/0259 ,  B01J31/0237 ,  B01J31/0262 ,  B01J31/0271 ,  B01J31/122 ,  B01J31/143 ,  B01J31/26 ,  B01J31/38 ,  C08F10/00 ,  C08F110/00 ,  B01J31/185 ,  B01J31/1855 ,  B01J31/186 ,  Y10S526/906

    摘要： A process for the production of olefin polymers which comprises contacting at least one olefin monomer with an olefin polymerization catalyst comprising:(1) a solid compound of titanium, vanadium or zirconium wherein the metal has a valency below its maximum,(2) a Grignard reagent which is substantially ether free,Mg[Al(C.sub.2 H.sub.5).sub.4 ].sub.2, Mg(C.sub.6 H.sub.5).sub.2,a lithium aluminium tetraalkyl, an aluminium hydrocarbyl halide, an aluminium hydrocarbyl sulphate, an aluminium hydrocarbyl oxyhydrocarbyl, an aluminium trihydrocarbyl or a dihydrocarbyl aluminium hydride, the improvement of adding to the polymerization system up to C.sub.a /f molecular proportions of a trivalent phosphorus compound of the formulaPR'.sub.3-n (X--A--Y).sub.nwhereinR' is halogen, a hydrocarbyl group, the group --NR.sub.2 or the group --OR;x is --O--, --S-- or --NR--;A is a bivalent hydrocarbyl radical such that X and Y are separated by not more than 3 carbon atoms;Y is --OR, --SR, --NR.sub.2, --PR.sub.2, a pyridyl radical, a quinolyl radical, an isoquinolyl radical, a furyl radical or a tetrahydrofuryl radical;R is a hydrocarbyl group;C.sub.a is the molecular proportion of component (2) of the catalyst;f is the number of functional groups in the phosphorus compound which contain O or N, there being at least one such functional group in the phosphorus compound, andn is 1, 2 or 3.

    Polymerization process
    5.
    发明授权
    Polymerization process 失效
    聚合过程

    公开(公告)号：US3972866A

    公开(公告)日：1976-08-03

    申请号：US416495

    申请日：1973-11-16

    申请人： Michael Stanley Fortuin ,  Anthony David Caunt

    发明人： Michael Stanley Fortuin ,  Anthony David Caunt

    IPC分类号： C07F9/572 ,  C07F9/6509 ,  C07F9/6584 ,  C08F10/00 ,  C08F4/66 ,  C08F10/06

    CPC分类号： C07F9/65848 ,  C07F9/5721 ,  C07F9/650958 ,  C08F10/00

    摘要： An olefine polymerization catalyst includes a complex compound of phosphorus having the general formula ##EQU1## where the various groups are defined. Typical phosphorus compounds include ##EQU2## Catalyst systems containing these phosphorus compounds give a high rate of polymerization together with a low proportion of soluble polymer. The phosphorus compound can be ball-milled with the titanium compound to give an improved effect and the catalyst system may also include an electron donor compound such as triphenylphosphine oxide and tris(dimethylamino)silicon monochloride or a cyclic polyene such as cycloheptatriene.

    摘要翻译： 烯烃聚合催化剂包括具有通式E R'P（Q）的定角化合物，其中定义了各种基团。 典型的磷化合物包括N（CH 3）CH 2（CH 3）2 N（O）ANGLE | N（CH 3）CH 2）。

    Treatment of transition metal compound
    7.
    发明授权
    Treatment of transition metal compound 失效
    过渡金属化合物的处理

    公开(公告)号：UST962007I4

    公开(公告)日：1977-09-06

    申请号：US733408

    申请日：1976-10-18

    申请人： Anthony David Caunt ,  Alan Branford Newton ,  Ian Gabriel Williams ,  Michael Stanley Fortuin

    发明人： Anthony David Caunt ,  Alan Branford Newton ,  Ian Gabriel Williams ,  Michael Stanley Fortuin

    IPC分类号： C08F4/64 ,  C08F10/00

    CPC分类号： C08F10/00 ,  C08F4/657 ,  C08F4/653 ,  C08F4/651 ,  C08F4/655

    摘要： according to the present invention (1) a titanium trihalide is ground in the presence of from 5 up to 75% molar, relative to the titanium trihalide, of (2) a Lewis Base compound which is an organo-phosphorus compound of the formulaR.sub.1 R.sub.2 R.sub.3 P(O).sub.aand either (a) from 1 up to 50% molar, relative to the titanium trihalide, of a titanium tetrahalide and/or (b) from 0.2 up to 50% molar, relative to the titanium trihalide, of an oxidizing agent, wherein when a titanium tetrahalide is present, the molar quantity of the organo-phosphorus compound is at least equal to the molar quantity of the titanium tetrahalide.The titanium halides (1) and (a) are preferably the chlorides. Suitable forms of titanium trichloride are obtained by the reduction of titanium tetrachloride with hydrogen, titanium metal, aluminum metal or an organo-aluminium compound. It is preferred to use a material of the type, titanium trichloride/aluminium chloride, such as is obtainable by the reduction of titanium tetrachloride with aluminium metal.In the organo-phosphorus compound, R.sub.1 is conveniently an alkyl group containing 2 to 10 carbon atoms. The groups R.sub.2 and R.sub.3 can be alkyl, aryl, cycloalkyl, alkaryl or aralkyl groups. Preferably, R.sub.2 and R.sub.3 are both alkyl groups and preferably R.sub.1, R.sub.2 and R.sub.3 are all the same, for example, butyl as in tributylphosphine and tributylphosphine oxide.Suitable oxidizing agents include oxygen gas or halogen-containing materials such as chlorine gas, carbon tetrachloride, hexachlorocyclopentadiene, stannic chloride, phosphorus pentachloride and iodine.The product produced by grinding (1), (2) and either (a) and/or (b) above may be admixed with (A) to form an olefin polymerization catalyst, wherein(A) is at least one organo-metallic compound of aluminium or of a non-transition metal of Group IIA of the Periodic System, or a complex of an organo-metallic compound of a non-transition metal of Group IA or IIA of the Periodic System and an organo-aluminium compound. That polymerization catalyst may be modified by the addition of a Lewis Base which is effective to modify the stereospecificity of the catalyst and/or a substituted or unsubstituted polyene.

    Olefine polymerization catalyst incorporating an organo-phosphorus compound
    8.
    发明授权
    Olefine polymerization catalyst incorporating an organo-phosphorus compound 失效
    含有有机磷化合物的烯烃聚合催化剂

    公开(公告)号：US3969269A

    公开(公告)日：1976-07-13

    申请号：US475840

    申请日：1974-06-03

    申请人： Anthony David Caunt

    发明人： Anthony David Caunt

    IPC分类号： C08F4/60 ,  C08F110/00 ,  C08F4/52 ,  C08F4/64 ,  C08F4/68

    CPC分类号： C08F110/00

    摘要： An olefine polymerization catalyst comprising (1) a solid compound of a transition metal wherein the said metal has a valency below its maximum, (2) an organo-metallic compound of aluminium, or of a non-transition metal of Group II of the Periodic System, or a complex of an organo-metallic compound of a non-transition metal of Group I or II of the Periodic System and an organo-aluminium compound; and (3) a trivalent phosphorus compound of the formulaPR'.sub.3-n (X-A-Y).sub.nWhereinR' is halogen, a hydrocarbyl group or the group --NR.sub.2 or --OR;X is --O--, --S--, or --NR--;A is a bivalent organic radical such that X and Y are separated by not more than 3 carbon atoms;Y is --OR, --SR, --NR.sub.2, --PR.sub.2 or a heterocyclic ring system whereof the heteroatom is O, S, N or P; andn is 1, 2 or 3. The phosphorus compound can be ball-milled with the transition metal component of the catalyst. The catalyst may also include an electron donor compound of a known type such as isoquinoline, tetramethylene-diamine or triphenyl phosphone oxide. When used to polymerize olefine monomers such as propylene, the production of soluble polymer is decreased.

    摘要翻译： 一种烯烃聚合催化剂，其包含（1）过渡金属的固体化合物，其中所述金属的化合价低于其最大值，（2）铝的有机金属化合物或第二族的非过渡金属化合物 系统，或周期系I族或II族非过渡金属有机金属化合物与有机铝化合物的络合物; 和（3）式PR'3-n（X-A-Y）n WHEREIN R'是卤素，烃基或基团-NR2或-OR的三价磷化合物; X是-O - ， - S-或-NR-; A是二价有机基团，使得X和Y被不多于3个碳原子分开; Y是-OR，-SR，-NR2，-PR2或其杂原子是O，S，N或P的杂环体系; 磷化合物可以用催化剂的过渡金属组分球磨。 催化剂还可以包括已知类型的电子给体化合物，例如异喹啉，四亚甲基二胺或三苯基膦氧化物。 当用于聚合烯烃单体如丙烯时，可溶性聚合物的生产降低。