Cellulose derivatives having gel-like rheological properties and process for the preparation thereof
    1.
    发明授权
    Cellulose derivatives having gel-like rheological properties and process for the preparation thereof 有权
    具有凝胶状流变性的纤维素衍生物及其制备方法

    公开(公告)号:US06958393B2

    公开(公告)日:2005-10-25

    申请号:US10626338

    申请日:2003-07-23

    CPC classification number: C08B11/193 C08B11/00 C08B11/02 C08B15/00 C08B15/005

    Abstract: A description is given of cellulose derivatives having gel-like rheological properties in aqueous solution characterized in that: a) cellulose is alkalized with aqueous alkali metal hydroxide solution in the presence of a suspension medium, b) the alkalized cellulose is reacted with one or more alkylene oxides, c) then reacted with an alkyl halide present in the suspension medium d) subsequently or simultaneously the alkalized cellulose is reacted with a crosslinking agent in an amount of 0.0001 to 0.05 eq, where the unit “eq” represents the molar ratio of crosslinking agent relative to the anhydroglucose unit (AGU) of the cellulose used, and e) after, if appropriate, further addition of alkali metal hydroxide and/or alkylating agent, the resultant irreversibly crosslinked cellulose derivative is separated off from the reaction mixture, if appropriate purified and dried.

    Abstract translation: 给出了在水溶液中具有凝胶状流变性的纤维素衍生物的描述,其特征在于:a)在悬浮介质存在下,纤维素用碱金属氢氧化物水溶液碱化,b)碱化的纤维素与一种或多种 环氧烷,c)然后与存在于悬浮介质中的烷基卤反应d)随后或同时使碱化的纤维素与0.0001至0.05当量的交联剂反应,其中单位“eq”表示 交联剂相对于所使用的纤维素的脱水葡萄糖单元(AGU),以及e)如果适当,进一步加入碱金属氢氧化物和/或烷基化剂后,得到的不可逆交联的纤维素衍生物与反应混合物分离,如果 适当纯化并干燥。

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