公开(公告)号：US20140189960A1

公开(公告)日：2014-07-10

申请号：US14131706

申请日：2012-07-07

申请人： Johannes Himmrich ,  Barbara Duecker ,  Joachim Erbes ,  Stefan Riegelbeck

发明人： Johannes Himmrich ,  Barbara Duecker ,  Joachim Erbes ,  Stefan Riegelbeck

IPC分类号： C11D3/34

CPC分类号： C11D3/3463 ,  C11D1/143 ,  C11D3/38618

摘要： An improvement for boosting the cleaning capacity of liquid washing compositions provides for the use of a combination of one or more secondary paraffinsulfonates having 8 to 22 carbon atoms and amylase for increasing the cleaning capacity of the liquid washing compositions with respect to starch-containing stains on textiles. In accordance with the invention, it is possible to lower the amount of liquid washing composition with comparable cleaning performance, which brings environmental advantages. Moreover, it is possible to clean at low temperatures, which can reduce energy consumption.

摘要翻译： 用于提高液体洗涤组合物的清洁能力的改进提供使用一种或多种具有8至22个碳原子的仲烷烃磺酸盐和淀粉酶的组合来增加液体洗涤组合物相对于含淀粉污渍的清洁能力 纺织品。 根据本发明，可以以相当的清洁性能降低液体洗涤组合物的量，这带来环境优点。 此外，可以在低温下清洁，这可以降低能量消耗。

公开(公告)号：US08148530B2

公开(公告)日：2012-04-03

申请号：US11921884

申请日：2006-06-10

申请人： Michael Wessling ,  Barbara Duecker ,  Nicole Nitschke

发明人： Michael Wessling ,  Barbara Duecker ,  Nicole Nitschke

IPC分类号： C07D471/04

CPC分类号： C07D471/08

摘要： The present invention relates to a process for the preparation of 3,7-diazabicyclo[3.3.1]nonane compounds. According to the invention, in a first step, a dicarboxylic acid ester is reacted with a pyridine aldehyde and a primary amine. The piperidone which forms is reacted in a second stage with formaldehyde and a further primary amine. It is essential to the invention that, in the first reaction stage, a C2-C4-alcohol is used as solvent and, in the second reaction stage, a C3-C4-alcohol is used as solvent.

摘要翻译： 本发明涉及制备3,7-二氮杂双环[3.3.1]壬烷化合物的方法。 根据本发明，在第一步中，二羧酸酯与吡啶醛和伯胺反应。 形成的哌啶酮在第二阶段与甲醛和另外的伯胺反应。 本发明必须在第一反应阶段使用C 2 -C 4醇作为溶剂，在第二反应阶段使用C 3 -C 4醇作为溶剂。

公开(公告)号：US08871702B2

公开(公告)日：2014-10-28

申请号：US13512248

申请日：2010-11-24

申请人： Roman Morschhaeuser ,  Barbara Duecker ,  Hans Juergen Scholz

发明人： Roman Morschhaeuser ,  Barbara Duecker ,  Hans Juergen Scholz

IPC分类号： B08B3/04 ,  C08G63/672 ,  C08G63/688 ,  C11D3/00 ,  C11D3/37

CPC分类号： C08G63/6886 ,  C08G63/672 ,  C11D3/0036 ,  C11D3/3715

摘要： The invention relates to polyesters, obtainable by means of polymerization of the components including (a) one or more sulfo group-free aromatic dicarboxylic acids and/or salts thereof and/or anhydrides thereof and/or esters thereof, b) optionally one or more sulfo group-containing dicarboxylic acids, salts thereof and/or anhydrides thereof and/or esters thereof, c) 1,2-propylene glycol, d) ethylene glycol, e) one or more compounds of the formula (1) R1O(CHR2CHR3O)nH (1), where R1 is a linear or branched, saturated or unsaturated alkyl group having from 1 to 22 C atoms, R2 and R3, independently of one another, are hydrogen or an alkyl group having from 1 to 4 carbon atoms, and N is an integer of from 1 to 50, f) optionally one or more compounds of the formula (2) H—(OCH2CH2)m—SO3X (2), in which m is an integer from 1 to 10 and X is hydrogen or an alkali metal ion, and g); optionally one or more crosslinking polyfunctional compounds, provided that at least one of the components b) or f) is present, and provided further that the molar ratio of the components c) 1,2-propylene glycol to d) ethylene glycol is greater than or equal to 1.70.

摘要翻译： 本发明涉及通过组分的聚合可获得的聚酯，所述组分包括（a）一种或多种不含磺基的芳族二羧酸和/或其盐和/或其酸酐和/或其酯，b）任选的一种或多种 含有磺基的二羧酸，其盐和/或其酸酐和/或其酯，c）1,2-丙二醇，d）乙二醇，e）一种或多种式（1）化合物：R 1 O（CHR 2 CHR 3 O） nH（1）其中R 1是具有1至22个C原子的直链或支链饱和或不饱和的烷基，R 2和R 3彼此独立地是氢或具有1至4个碳原子的烷基，以及 N是1至50的整数，f）任选一种或多种式（2）H（OCH 2 CH 2）m -SO 3 X（2）的化合物，其中m是1至10的整数，X是氢或 碱金属离子，和g）; 任选地一种或多种交联多官能化合物，条件是存在组分b）或f）中的至少一种，并且进一步提供组分c）1,2-丙二醇与d）乙二醇的摩尔比大于 或等于1.70。

公开(公告)号：US08536334B2

公开(公告)日：2013-09-17

申请号：US13140589

申请日：2009-12-12

申请人： Melanie Sajitz ,  Barbara Duecker ,  Michael Wessling

发明人： Melanie Sajitz ,  Barbara Duecker ,  Michael Wessling

IPC分类号： C07F15/02 ,  C07F15/00

CPC分类号： C07F15/025

摘要： The invention relates to a method for producing 3,7-diaza-bicyclo[3.3.1]nonane metal complexes, wherein the ligand, a 3,7-diaza-bicyclo[3.3.1]nonane compound, is reacted with an aqueous metal(II)salt solution in one step. According to the invention, the reaction stage is carried out with water as solvent.

摘要翻译： 本发明涉及制备3,7-二氮杂双环[3.3.1]壬烷金属络合物的方法，其中配体，3,7-二氮杂 - 双环[3.3.1]壬烷化合物与含水金属 （II）盐溶液。 根据本发明，反应阶段用水作为溶剂进行。

公开(公告)号：US20110263857A1

公开(公告)日：2011-10-27

申请号：US13140589

申请日：2009-12-12

申请人： Melanie Sajitz ,  Barbara Duecker ,  Michael Wessling

发明人： Melanie Sajitz ,  Barbara Duecker ,  Michael Wessling

IPC分类号： C07F15/02

CPC分类号： C07F15/025

摘要： The invention relates to a method for producing 3,7-diaza-bicyclo[3.3.1]nonane metal complexes, wherein the ligand, a 3,7-diaza-bicyclo[3.3.1] nonane compound, is reacted with an aqueous metal(II)salt solution in one step. According to the invention, the reaction stage is carried out with water as solvent.

摘要翻译： 本发明涉及制备3,7-二氮杂双环[3.3.1]壬烷金属络合物的方法，其中配体，3,7-二氮杂 - 双环[3.3.1]壬烷化合物与含水金属 （II）盐溶液。 根据本发明，反应阶段用水作为溶剂进行。

公开(公告)号：US07977487B2

公开(公告)日：2011-07-12

申请号：US11921551

申请日：2006-05-26

申请人： Michael Wessling ,  Barbara Duecker ,  Nicole Nitschke

发明人： Michael Wessling ,  Barbara Duecker ,  Nicole Nitschke

IPC分类号： C07D401/14 ,  C07F15/02

CPC分类号： C07D213/38

摘要： The invention relates to a method for producing the compositions cited in the title. According to this method: dipyridyl ketone is reacted with hydroxylamine; the oxime obtained thereby is reduced without intermediate isolation to form 1,1-di-(2-pyridyl)-methylamine, and; this amine is firstly reacted with 1 to 1.5 molar equivalent of picolyl chloride and then with another 1 to 1.5 molar equivalent of picolyl chloride to form the amine of formula (1). This amine is purified via the tetrafluoroborate salt and subsequently alkylated with an alkyl iodide. This method represents an improvement with regard to prior art methods for producing these compounds.

摘要翻译： 本发明涉及标题中引用的组合物的制备方法。 根据该方法：联吡啶酮与羟胺反应; 由此获得的肟在没有中间分离的情况下减少以形成1,1-二 - （2-吡啶基） - 甲胺， 该胺首先与1至1.5摩尔当量的吡啶甲基氯反应，然后与另外1至1.5摩尔当量的吡啶甲基氯反应以形成式（1）的胺。 该胺通过四氟硼酸盐纯化，随后用烷基碘烷基化。 该方法代表了用于生产这些化合物的现有技术方法的改进。

公开(公告)号：US08871703B2

公开(公告)日：2014-10-28

申请号：US13512260

申请日：2010-11-24

申请人： Roman Morschhaeuser ,  Barbara Duecker ,  Frank-Peter Lang ,  Georg Borchers ,  Peter Naumann

发明人： Roman Morschhaeuser ,  Barbara Duecker ,  Frank-Peter Lang ,  Georg Borchers ,  Peter Naumann

IPC分类号： B08B3/04 ,  C08G63/672 ,  C08G63/688 ,  C11D3/00 ,  C11D3/37

CPC分类号： C11D3/0036 ,  C08G63/672 ,  C08G63/6886 ,  C11D3/3715

摘要： The invention relates to an aqueous polyester concentrate having a proportion by weight of polyesters of 12 to 60%, wherein the polyesters are obtainable by means of polymerization of the components selected from a) one or more sulfo group-free aromatic dicarboxylic acids and/or salts thereof and/or anhydrides thereof and/or esters thereof, b) optionally one or more sulfo group-containing dicarboxylic acids, salts thereof and/or anhydrides thereof and/or esters thereof, c) 1,2-propylene glycol, d) ethylene glycol, e) one or more compounds of the formula (1) R1O(CHR2CHR3O)nH (1), where R1 is a linear or branched, saturated or unsaturated alkyl group having from 1 to 22 C atoms, R2 and R3, independently of one another, are hydrogen or an alkyl group having from 1 to 4 carbon atoms, and n is an integer of from 1 to 50, f) optionally one or more compounds of the formula (2) H—(OCH2CH2)m—SO3X (2), where m is an integer of from 1 to 10 and X is hydrogen or an alkali metal ion, and g) optionally one or more cross-linking polyfunctional compounds, provided that at least one of the components b) or f) is present, and provided further that the molar ratio of the components c) 1,2-propylene glycol to d) ethylene glycol is greater than or equal to 1.60.

摘要翻译： 本发明涉及一种聚酯重量百分比为12至60％的聚酯水性聚酯浓缩物，其中聚酯可通过选自以下成分的聚合获得：a）一种或多种不含无磺基的芳族二羧酸和/或 其盐和/或其酸酐和/或其酯，b）任选的一种或多种含磺基的二羧酸，其盐和/或其酸酐和/或其酯，c）1,2-丙二醇，d） 乙二醇，e）一种或多种式（1）化合物R 1 O（CHR 2 CHR 3 O）n H（1），其中R 1是具有1至22个C原子的直链或支链饱和或不饱和的烷基，R2和R3独立地 是氢或具有1至4个碳原子的烷基，n是1至50的整数，f）任选的一种或多种式（2）的化合物，H（OCH 2 CH 2）m -SO 3 X （2）中，m为1〜10的整数，X为氢或碱金属离子，g）选择 条件是存在至少一种组分b）或f）的一种或多种交联多官能化合物，并进一步提供组分c）1,2-丙二醇与d）乙二醇的摩尔比为 大于或等于1.60。

公开(公告)号：US20090221831A1

公开(公告)日：2009-09-03

申请号：US11921551

申请日：2006-05-26

申请人： Michael Wessling ,  Barbara Duecker ,  Nicole Nitschke

发明人： Michael Wessling ,  Barbara Duecker ,  Nicole Nitschke

IPC分类号： C07D401/14

CPC分类号： C07D213/38

摘要： The invention relates to a method for producing the compositions cited in the title. According to this method: dipyridyl ketone is reacted with hydroxylamine; the oxime obtained thereby is reduced without intermediate isolation to form 1,1-di-(2-pyridyl)-methylamine, and; this amine is firstly reacted with 1 to 1.5 molar equivalent of picolyl chloride and then with another 1 to 1.5 molar equivalent of picolyl chloride to form the amine of formula (1). This amine is purified via the tetrafluoroborate salt and subsequently alkylated with an alkyl iodide. This method represents an improvement with regard to prior art methods for producing these compounds.

摘要翻译： 本发明涉及标题中引用的组合物的制备方法。 根据该方法：联吡啶酮与羟胺反应; 由此获得的肟在没有中间分离的情况下减少以形成1,1-二 - （2-吡啶基） - 甲胺， 该胺首先与1至1.5摩尔当量的吡啶甲基氯反应，然后与另外1至1.5摩尔当量的吡啶甲基氯反应以形成式（1）的胺。 该胺通过四氟硼酸盐纯化，随后用烷基碘烷基化。 该方法代表了用于生产这些化合物的现有技术方法的改进。

公开(公告)号：US20140193887A1

公开(公告)日：2014-07-10

申请号：US14131696

申请日：2012-07-07

申请人： Johannes Himmrich ,  Barbara Duecker ,  Joachim Erbes ,  Stefan Riegelbeck

发明人： Johannes Himmrich ,  Barbara Duecker ,  Joachim Erbes ,  Stefan Riegelbeck

IPC分类号： C11D3/34 ,  C11D3/386

CPC分类号： C11D3/3454 ,  C11D1/143 ,  C11D3/386 ,  C11D3/38618 ,  C11D3/38627 ,  C11D3/38636

摘要： An improvement for boosting the cleaning capacity of one or more enzymes includes providing one or more secondary paraffin-sulfonates to a cleaning composition. The method is particularly effective for textiles at low washing temperatures.

摘要翻译： 提高一种或多种酶的清洁能力的改进包括向清洁组合物提供一种或多种次级链烷磺酸盐。 该方法对于低洗涤温度下的纺织品特别有效。

公开(公告)号：US20130200290A1

公开(公告)日：2013-08-08

申请号：US13512260

申请日：2010-11-24

申请人： Roman Morschhaeuser ,  Barbara Duecker ,  Frank-Peter Lang ,  Georg Borchers ,  Peter Naumann

发明人： Roman Morschhaeuser ,  Barbara Duecker ,  Frank-Peter Lang ,  Georg Borchers ,  Peter Naumann

IPC分类号： C11D3/00 ,  C11D3/37

CPC分类号： C11D3/0036 ,  C08G63/672 ,  C08G63/6886 ,  C11D3/3715

摘要： The invention relates to an aqueous polyester concentrate having a proportion by weight of polyesters of 12 to 60%, wherein the polyesters are obtainable by means of polymerisation of the components selected from a) one or more sulfo group-free aromatic dicarboxylic acids and/or salts thereof and/or anhydrides thereof and/or esters thereof, b) optionally one or more sulfo group-containing dicarboxylic acids, salts thereof and/or anhydrides thereof and/or esters thereof, c) 1,2-propylene glycol, d) ethylene glycol, e) one or more compounds of the formula (1) R1O(CHR2CHR3O)nH (1), where R1 is a linear or branched, saturated or unsaturated alkyl group having from 1 to 22 C atoms, R2 and R3, independently of one another, are hydrogen or an alkyl group having from 1 to 4 carbon atoms, and n is an integer of from 1 to 50, f) optionally one or more compounds of the formula (2) H—(OCH2CH2)m—SO3X (2), where m is an integer of from 1 to 10 and X is hydrogen or an alkali metal ion, and g) optionally one or more cross-linking polyfunctional compounds, provided that at least one of the components b) or f) is present, and provided further that the molar ratio of the components c) 1,2-propylene glycol to d) ethylene glycol is greater than or equal to 1.60.

摘要翻译： 本发明涉及一种聚酯重量百分比为12至60％的聚酯水性聚酯浓缩物，其中聚酯可通过选自以下成分的聚合获得：a）一种或多种不含磺基的芳族二羧酸和/或 其盐和/或其酸酐和/或其酯，b）任选的一种或多种含磺基的二羧酸，其盐和/或其酸酐和/或其酯，c）1,2-丙二醇，d） 乙二醇，e）一种或多种式（1）化合物R 1 O（CHR 2 CHR 3 O）n H（1），其中R 1是具有1至22个C原子的直链或支链饱和或不饱和的烷基，R2和R3独立地 是氢或具有1至4个碳原子的烷基，n是1至50的整数，f）任选的一种或多种式（2）的化合物，H（OCH 2 CH 2）m -SO 3 X （2）其中m为1〜10的整数，X为氢或碱金属离子，g）可选项 提供一种或多种交联多官能化合物，条件是存在组分b）或f）中的至少一种，并且进一步提供组分c）1,2-丙二醇与d）乙二醇的摩尔比为 大于或等于1.60。