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1.发明授权Catalyzed synthesis of aryl-substituted fatty acids and fatty esters and compositions related thereto 失效芳基取代的脂肪酸和脂肪酯的催化合成及其相关的组合物
公开(公告)号：US5840942A
公开(公告)日：1998-11-24
申请号：US375217
申请日：1995-01-19
IPC分类号： C07C51/347 , C07C51/353 , C07C57/30 , C07C67/347 , C11C3/00
CPC分类号： C07C51/347 , C07C51/353 , C07C57/30 , C07C67/347
摘要： A novel method for preparing an aryl-substituted fatty acid or fatty ester is disclosed. According to the method, an olefinic composition selected from among mono-unsaturated fatty acids, mono-unsaturated fatty esters and mixtures thereof is introduced to a reaction zone comprising a liquid aromatic hydrocarbon and a catalytic amount of a clay catalyst to produce a reaction that is allowed to proceed for a time and at a temperature sufficient to produce a reaction product comprising a desired yield of aryl-substituted fatty acid or fatty ester. Preferably, the introduction of the olefinic composition is conducted slowly, such as over a period of one to four, more preferably, two to four, hours. Related methods and compositions, including xylylstearic acid, are also disclosed.
摘要翻译： 公开了一种制备芳基取代脂肪酸或脂肪酯的新方法。 根据该方法，将选自单不饱和脂肪酸，单不饱和脂肪酸酯及其混合物的烯烃组合物引入到包含液体芳族烃和催化量的粘土催化剂的反应区中，以产生 允许进行一段时间并在足以产生包含所需产率的芳基取代的脂肪酸或脂肪酯的反应产物的温度下进行。 优选地，缓慢地进行烯烃组合物的引入，例如在1-4的时间内，更优选的是2-4小时。 还公开了相关方法和组合物，包括二甲苯基硬脂酸。
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公开(公告)号：US5785895A
公开(公告)日：1998-07-28
申请号：US569372
申请日：1995-12-06
IPC分类号： C08L101/16 , C09K8/54 , C23F11/10 , C23F11/14 , C23F11/16 , C23F11/167 , C23F11/12
CPC分类号： C23F11/149 , C09K8/54 , C23F11/10
摘要： A method for inhibiting corrosion in an aqueous medium is disclosed. The method comprises incorporating into the medium an amount of a water-soluble corrosion inhibitor sufficient to inhibit corrosion. The corrosion inhibitor comprises an N-ethoxy, 2-substituted imidazoline, the N-ethoxy substituent having from one to about thirty ethoxy units and the 2-substituent being an unsaturated or polyunsaturated fatty chain of from about six to about thirty carbons. If the medium is sweet, the inhibitor further comprises a phosphate ester derived from a water-soluble oxyethylated, straight chain alcohol of from about two to about thirty carbons. Corrosion inhibitor compositions useful in such method are also disclosed.
摘要翻译： 公开了一种在水性介质中抑制腐蚀的方法。 该方法包括向培养基中加入一定量的足以抑制腐蚀的水溶性腐蚀抑制剂。 腐蚀抑制剂包括N-乙氧基，2-取代的咪唑啉，N-乙氧基取代基具有一至三十个乙氧基单元，2-取代基是约六至约三十个碳的不饱和或多不饱和脂肪链。 如果介质是甜的，则抑制剂还包含衍生自约2-约30个碳原子的水溶性乙氧基化的直链醇的磷酸酯。 还公开了可用于这种方法的腐蚀抑制剂组合物。
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公开(公告)号：US4757147A
公开(公告)日：1988-07-12
申请号：US772972
申请日：1985-09-05
IPC分类号： C07D211/72 , C07D211/02
CPC分类号： C07D211/72
摘要： This invention relates to novel highly branched amines and to a process of preparing same which comprises:(1) the preparation of a vinylimine from branched aldehydes and ammonia;(2) the dimerization and intermolecular condensation of such vinylimines to cyclic diamines; and(3) hydrolysis of such cyclic diamines to other diamines.
摘要翻译： 本发明涉及新型高支化胺及其制备方法，其包括：（1）从支链醛和氨制备乙烯基亚胺; （2）这种乙烯基亚胺与环状二胺的二聚和分子间缩合; 和（3）将这种环状二胺水解成其它二胺。
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公开(公告)号：US4665180A
公开(公告)日：1987-05-12
申请号：US779752
申请日：1985-09-25
IPC分类号： C07D221/12 , C07D239/70
CPC分类号： C07D239/70 , C07D221/12
摘要： This invention relates to certain substituted tetrahydropyrimidines and derivatives thereof, including the preparation and uses thereof.
摘要翻译： 本发明涉及某些取代的四氢嘧啶及其衍生物，包括其制备和用途。
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公开(公告)号：US4539404A
公开(公告)日：1985-09-03
申请号：US444418
申请日：1982-11-24
IPC分类号： C07D233/20 , C09K8/54 , C23F11/16 , C23G1/06 , C07D239/02
CPC分类号： C07D233/20 , C09K8/54 , C23F11/16 , C23G1/065
摘要： This invention relates to the following:(1) An amino-containing composition characterized by polymercapto groups,(2) A polyamino-containing composition characterized by mercapto or polymercapto groups,(3) A composition characterized by the presence ofA. a mercapto or polymercapto groups, andB. nitrogen-containing group characterized by at least one of the following:1. an amido or a polyamido group,2. a cyclic amidine or a polycyclic amidine group,3. an epihalohydrin-derived amino-containing group.This invention also relates to the use of the above compositions as corrosion inhibitors.
摘要翻译： 本发明涉及以下：（1）以聚合物巯基为特征的含氨基组合物，（2）以巯基或聚合物巯基为特征的含聚氨基的组合物，（3）一种组合物，其特征在于存在A.巯基或 特征在于以下至少一个的B.含氮基团：1.酰胺基或聚酰胺基，环状脒或多环脒基团，3.表卤代醇衍生的含氨基的基团。 本发明还涉及上述组合物作为腐蚀抑制剂的用途。
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公开(公告)号：US4085105A
公开(公告)日：1978-04-18
申请号：US406544
申请日：1973-10-15
IPC分类号： C07D239/70 , C07D239/74
CPC分类号： C07D239/70
摘要： This invention relates to hexahydropyrimidines (HHP) and to the preparation of HHP by the reduction of tetrahydropyrimidines (THP). HHP is preferably prepared by reacting carbonyls, such as ketones and aldehydes, with ammonia in the presence of ammonium formate to form THP and then reducing THP to HHP. The preferred carbonyl is a cycloalkylene ketone such as cyclohexyl ketone or substituted cyclohexyl ketone.
摘要翻译： 本发明涉及六氢嘧啶（HHP）和通过还原四氢嘧啶（THP）制备HHP。 HHP优选通过在甲酸铵存在下使羰基（例如酮和醛）与氨反应制备，以形成THP，然后将THP还原成HHP。 优选的羰基是环亚烷基酮如环己基酮或取代的环己基酮。
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公开(公告)号：US4040799A
公开(公告)日：1977-08-09
申请号：US512424
申请日：1974-10-07
CPC分类号： C10L1/2222
摘要： This invention relates to the reductive amination of unsaturated cyclic ketones; to cyclic amines prepared thereby; and to uses thereof. For example, when isophorone is reductively aminated, trimethyl cyclohexylamines and cyclohexenamines are obtained. This invention also relates to uses thereof, for example, as fuel additives, particularly for stabilizing distillate fuels.
摘要翻译： 本发明涉及不饱和环酮的还原胺化; 由此制备的环胺; 并使用它们。 例如，当异佛尔酮被还原胺化时，得到三甲基环己胺和环己烯胺。 本发明还涉及其用途，例如作为燃料添加剂，特别是用于稳定馏出燃料。
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公开(公告)号：US3957925A
公开(公告)日：1976-05-18
申请号：US165336
申请日：1971-07-22
IPC分类号： C07D339/04 , C07F9/173 , C07F9/16
CPC分类号： C07D339/04 , C07F9/173
摘要： Thiophosphates of the formula ##EQU1## where X is O or S, R is a hydrocarbon or a substituted hydrocarbon group such as alkyl, aryl, cycloalkyl, alkaryl, aralkyl, etc., and R' is a 3-thione-propene-1 or a substituted 3-thione-propene-1 group; the preparation thereof by reacting a 1,2-dithiolium compound with a phosphite ester; the reversion to the original dithionium compound is effected by reacting the thiophosphate under acid conditions; and the uses of such thiophosphates as corrosion inhibitors in acid systems.
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公开(公告)号：US3935215A
公开(公告)日：1976-01-27
申请号：US374992
申请日：1973-06-29
IPC分类号： C07F9/173 , C07D339/04
CPC分类号： C07F9/173 , Y10S507/934 , Y10S507/939
摘要： Thiophosphates of the formula ##EQU1## where X is 0 or S, R is a hydrocarbon or a substituted hydrocarbon group such as alkyl, aryl, cycloalkyl, alkaryl, aralkyl, etc., and R' is a 3-thione-propene-1 or a substituted 3-thione-propene-1 group; the preparation thereof by reacting a 1,2-dithiolium compound with a phosphite ester; the reversion to the original dithionium compound is effected by reacting the thiophosphate under acid conditions; and the uses of such thiophosphates as corrosion inhibitors in acid systems.
摘要翻译： 式X的二硫代磷酸酯（RX）2P-SR'，其中X为0或S，R为烃或取代的烃基如烷基，芳基，环烷基，烷芳基，芳烷基等，R'为3 - 硫酮 - 丙烯-1或取代的3-硫酮 - 丙烯-1-基; 其通过1,2-二硫鎓鎓化合物与亚磷酸酯反应制备; 通过在酸性条件下使硫代磷酸酯反应来实现对原始的二硫化钛化合物的反转; 以及这些硫代磷酸盐在酸性体系中作为腐蚀抑制剂的用途。
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公开(公告)号：US5393464A
公开(公告)日：1995-02-28
申请号：US146900
申请日：1993-11-02
IPC分类号： C08L101/16 , C09K8/54 , C23F11/10 , C23F11/14 , C23F11/16 , C23F11/167
CPC分类号： C23F11/149 , C09K8/54 , C23F11/10
摘要： A method for inhibiting corrosion in an aqueous medium is disclosed. The method comprises incorporating into the medium an amount of a water-soluble corrosion inhibitor sufficient to inhibit corrosion. The corrosion inhibitor comprises an N-ethoxy,2-substituted imidazoline, the N-ethoxy substituent having from one to about thirty ethoxy units and the 2-substituent being an unsaturated or polyunsaturated fatty chain of from about six to about thirty carbons. If the medium is sweet, the inhibitor further comprises a phosphate ester derived from a water-soluble oxyethylated, straight chain alcohol of from about two to about thirty carbons. Corrosion inhibitor compositions useful in such method are also disclosed.
摘要翻译： 公开了一种在水性介质中抑制腐蚀的方法。 该方法包括向培养基中加入一定量的足以抑制腐蚀的水溶性腐蚀抑制剂。 腐蚀抑制剂包括N-乙氧基，2-取代的咪唑啉，N-乙氧基取代基具有一至三十个乙氧基单元，2-取代基是约六至约三十个碳的不饱和或多不饱和脂肪链。 如果介质是甜的，则抑制剂还包含衍生自约2-约30个碳原子的水溶性乙氧基化的直链醇的磷酸酯。 还公开了可用于这种方法的腐蚀抑制剂组合物。
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