公开(公告)号：US06534606B2

公开(公告)日：2003-03-18

申请号：US09801045

申请日：2001-03-08

Applicant: Katrin Köhler ,  Eike Poetsch ,  Herbert Schumann ,  Sebastian Dechert ,  Walter Kaminsky ,  Andre Laban ,  Manfred Arnold ,  Jana Knorr ,  Birgit Corinna Wassermann

Inventor： Katrin Köhler ,  Eike Poetsch ,  Herbert Schumann ,  Sebastian Dechert ,  Walter Kaminsky ,  Andre Laban ,  Manfred Arnold ,  Jana Knorr ,  Birgit Corinna Wassermann

IPC: C08F442

CPC classification number: C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F4/6555 ,  C08F4/6425 ,  C08F4/6543 ,  C08F4/6423 ,  C08F4/642 ,  C08F2500/17 ,  C08F2500/01 ,  C08F2500/15 ,  C08F2500/04

Abstract: Described are catalyst systems having aluminium alkyl complexes of the formula (I) described herein applied to magnesium chloride, SiO2 or SiO2 in combination with MgCl2 as support in the presence of titanium halides or vanadium halides and internal and, if desired, external donors act both as cocatalysts and as stereoselectivity promoters in heterogeneous polymerizations of &agr;-olefins. Also described are polymerization methods using these catalyst systems.

公开(公告)号：US07351678B2

公开(公告)日：2008-04-01

申请号：US10491917

申请日：2002-09-11

Applicant: Kartin Köhler ,  Herbert Schumann ,  Birgit Corinna Wassermann ,  Wilfried Wassermann ,  Katharina Lange ,  Sebastian Dechert ,  Markus Hummert ,  Stefan Schutte ,  Walter Kaminsky ,  Andrea Eisenhardt ,  Björn Heuer ,  Andre Laban

Inventor： Kartin Köhler ,  Herbert Schumann ,  Birgit Corinna Wassermann ,  Wilfried Wassermann ,  Katharina Lange ,  Sebastian Dechert ,  Markus Hummert ,  Stefan Schutte ,  Walter Kaminsky ,  Andrea Eisenhardt ,  Björn Heuer ,  Andre Laban

IPC: B01J31/14 ,  B01J31/00 ,  B01J31/18 ,  C07F5/00 ,  C07F5/06 ,  C08F4/52 ,  C08F4/658 ,  C08F10/00 ,  C08F10/06

CPC classification number: C07F5/066

Abstract: The invention relates to the use of nitrogenous aluminium organyl complexes of general formula (I) as co-catalysts in heterogeneous polymerisation reactions of propene. In said formula: R, R′, R1 and R1′ independently of one another represent branched or unbranched C1-C7 alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl or alkynyl; R2 represents unsubstituted, monoalkylated or polyalkylated and/or monofluorinated or polyfluorinated aromatic hydrocarbons from group (II); R3 and R4 independently of one another represent CH2, CF2 oder C(R1)2; m stands for 0, 1 or 2; n stands for 0, 1 or 2; o stands for 0 or 1, all independently of one another. Said systems exhibit improved characteristics in terms of activity and stereoselectivity in comparison to conventional co-catalysts such as AlEt3 and can act simultaneously as co-catalysts and stereoselectivity promoters

Abstract translation: 本发明涉及在丙烯的非均相聚合反应中使用通式（I）的含氮有机络合物作为助催化剂。 在所述式中：R 1，R 2，R 1和R 1彼此独立地表示支链或非支链C 1 -C 3 烷基，环烷基，烯基，环烯基，芳基或炔基; R 2表示来自（II）组的未取代的单烷基化或多烷基化和/或单氟化或多氟化芳族烃; R 3和R 4彼此独立地表示CH 2，CF 2，C（R 0） 2＆lt; 2＆gt;; m代表0,1或2; n代表0,1或2; o代表0或1，彼此独立。 与常规助催化剂如AlE 3 3 3相比，所述体系在活性和立体选择性方面表现出改善的特性，并且可以同时作为助催化剂和立体选择性促进剂