Method for polymerization reaction monitoring with determination of entropy of monitored data
    1.
    发明申请
    Method for polymerization reaction monitoring with determination of entropy of monitored data 有权
    测定监测数据熵的聚合反应监测方法

    公开(公告)号:US20070244271A1

    公开(公告)日:2007-10-18

    申请号:US11731853

    申请日:2007-03-30

    IPC分类号: C08F2/00 C08F2/01

    摘要: In some embodiments, a method of monitoring a resin-producing polymerization reaction in a fluid bed reactor system to generate reaction parameter data in on-line fashion, determining an indicator of at least one of entropy and complexity (for example, Kolmogorov or Shannon entropy) of each of at least two subsets of the reaction parameter data, and optionally also determining from at least one value of the indicator (for example, from a time series of Kolmogorov or Shannon entropy values) an indication of at least one of degree of resin stickiness, an approach to or imminence of resin stickiness, and an approach to or imminence of an unsafe or undesired reactor operating condition (e.g., that can result in sheeting or chunking). Optionally also, the reaction is controlled in response to at least one value of the indicator, for example, in an effort to prevent the occurrence of sheeting or another discontinuity event or to maintain the reactor in a stable, non-sticking condition.

    摘要翻译: 在一些实施方案中,一种监测流化床反应器系统中产生树脂的聚合反应以在线方式产生反应参数数据的方法,确定熵和复杂度中的至少一种的指标(例如,Kolmogorov或Shannon熵 )反应参数数据的至少两个子集中的每一个,并且可选地还根据指示符的至少一个值(例如,从Kolmogorov或Shannon熵值的时间序列)确定以下各项中的至少一个的指示: 树脂粘性,树脂粘性的方法或迫切性,以及不安全或不需要的反应器操作条件(例如,可能导致片材或分块)的方法或迫切性。 还可选地,响应于指示剂的至少一个值来控制反应,例如,为了防止片材的发生或另外的不连续事件或将反应器保持在稳定的不粘附状态。