摘要:
In some embodiments, a method of monitoring a resin-producing polymerization reaction in a fluid bed reactor system to generate reaction parameter data in on-line fashion, determining an indicator of at least one of entropy and complexity (for example, Kolmogorov or Shannon entropy) of each of at least two subsets of the reaction parameter data, and optionally also determining from at least one value of the indicator (for example, from a time series of Kolmogorov or Shannon entropy values) an indication of at least one of degree of resin stickiness, an approach to or imminence of resin stickiness, and an approach to or imminence of an unsafe or undesired reactor operating condition (e.g., that can result in sheeting or chunking). Optionally also, the reaction is controlled in response to at least one value of the indicator, for example, in an effort to prevent the occurrence of sheeting or another discontinuity event or to maintain the reactor in a stable, non-sticking condition.
摘要:
Embodiments of the present invention relate to measuring and controlling static in a gas phase reactor polymerization. In particular, embodiments relate to monitoring carryover static in an entrainment zone during gas phase polymerization to determine the onset of reactor discontinuity events such as chunking and sheeting. Embodiments also relate to monitoring carryover static to determine the need for effective additions of continuity additives that minimize reactor static activity and thereby preventing discontinuity events.
摘要:
The present invention relates to a catalyst composition and a method for making the catalyst composition of a polymerization catalyst and a static charge modifier. The invention is also directed to the use of the catalyst composition in the polymerization of olefin(s). In particular, the polymerization catalyst system is supported on a carrier. More particularly, the polymerization catalyst comprises a bulky ligand metallocene-type catalyst system.
摘要:
Embodiments of the present invention relate to operating a gas-phase reactor at or near maximum production rates and to measuring and controlling polymer stickiness in a gas phase reactor polymerization. In particular, embodiments relate to monitoring acoustic emissions in a reactor during gas phase polymerization to determine the onset of reactor stickiness and possibly discontinuity events such as chunking and sheeting resulting from that stickiness. Embodiments also relate to monitoring acoustic emissions to determine the need for effective control of parameters that minimize reactor stickiness and thereby preventing discontinuity events. The emissions are processed by arithmetic averaging.
摘要:
Processes for transitioning among polymerization catalyst systems, preferably catalyst systems that are incompatible with each other. In particular, the processes relate to transitioning from olefin polymerizations utilizing metallocene catalyst systems to olefin polymerizations utilizing traditional Ziegler-Natta catalyst systems.
摘要:
The present invention relates to a catalyst composition and a method for making the catalyst composition of a polymerization catalyst and a static charge modifier. The invention is also directed to the use of the catalyst composition in the polymerization of olefin(s). In particular, the polymerization catalyst system is supported on a carrier. More particularly, the polymerization catalyst comprises a bulky ligand metallocene-type catalyst system.
摘要:
The present invention is directed to various methods and systems for detecting at least one impurity in a bulk fluid. In certain embodiments, the methods are performed in conjunction with a polymerization reactor system such as a gas-phase reactor system.