Catalysis in halogen exchange reactions

    公开(公告)号:US5965781A

    公开(公告)日:1999-10-12

    申请号:US975924

    申请日:1997-11-21

    CPC classification number: C07F9/06 C07C17/208 C07F9/025

    Abstract: Impure tetra(dihydrocarbylamino)phosphonium halide is contacted with a liquid cyclic ether to dissolve the phosphonium halide and leave at least a portion of the impurities comprising at least quaternary ammonium halide or an amidophosphoxide remaining in the solid state. The solids and the liquid phase are separated from each other, an anhydrous non-solvent for the tetra(dihydrocarbylamino)phosphonium halide is mixed with the separated liquid phase to precipitate the tetra(dihydrocarbylamino)phosphonium halide, which is then separated from the liquid phase. The so-treated tetra(dihydrocarbylamino)phosphonium halide is more efficient as a catalyst for halogen exchange reactions than the original untreated tetra(dihydrocarbylamino)phosphonium halide.

    Halide reduction in dihydrocarbylmagnesium mixtures
    4.
    发明授权
    Halide reduction in dihydrocarbylmagnesium mixtures 有权
    二烃基镁混合物中的卤化物还原

    公开(公告)号:US07871547B2

    公开(公告)日:2011-01-18

    申请号:US11718380

    申请日:2004-11-12

    CPC classification number: C07F3/02

    Abstract: This invention provides a process for reducing the amount of soluble halide in a solution comprising a liquid organic medium, at least one viscosity reducing agent, at least one dihydrocarbylmagnesium compound, and an initial amount of soluble halide. The process comprises mixing at least one alkali metal with the solution at a mole ratio of alkali metal to magnesium of less than about 1:2.5, thereby forming precipitated soluble halides. Also provided by this invention is a process for reducing the amount of soluble halide in a slurry comprising a liquid organic medium, at least one viscosity reducing agent, at least one dihydrocarbylmagnesium compound, solids from the formation of said dihydrocarbylmagnesium compound, and an initial amount of soluble halide. This process comprises mixing at least one alkali metal with the slurry at a mole ratio of alkali metal to magnesium of less than about 1:1.25, thereby forming precipitated soluble halides.

    Abstract translation: 本发明提供一种减少包含液体有机介质,至少一种降粘剂,至少一种二烃基镁化合物和初始量的可溶性卤化物的溶液中的可溶性卤化物的量的方法。 该方法包括将碱金属与镁的摩尔比以小于约1:2.5的比例混合至少一种碱金属与溶液,由此形成沉淀的可溶性卤化物。 本发明还提供一种减少包含液体有机介质,至少一种粘度降低剂,至少一种二烃基镁化合物,形成所述二烃基镁化合物的固体和初始量的浆料中的可溶性卤化物的量的方法 的可溶性卤化物。 该方法包括将碱金属与镁的摩尔比以小于约1:1.25的比例混合至少一种碱金属,从而形成沉淀的可溶性卤化物。

    Process for production of organic disulfides
    6.
    发明授权
    Process for production of organic disulfides 失效
    有机二硫化物生产工艺

    公开(公告)号:US06235941B1

    公开(公告)日:2001-05-22

    申请号:US09619164

    申请日:1998-02-13

    CPC classification number: C07C319/24 C07C321/14

    Abstract: An aqueous solution of basic mercaptide salt and water-soluble peroxide are mixed together in a reaction zone and maintained under reaction conditions effective to produce a vapor phase comprising organic disulfide, and concurrently vapor phase is recovered from the reaction zone. The process is highly efficient and enables production of organic disulfides in high yield and purity. Not only is the process very easy and simple to carry out, but in addition the process (i) eliminates the need for forming an organic phase of liquid organic disulfide product and conducting a separation between such product and the total aqueous phase used in the reaction, (ii) enables efficient control of a highly exothermic reaction, and (iii) minimizes alkanesulfonic acid salt formation during the reaction.

    Abstract translation: 碱性硫醇盐和水溶性过氧化物的水溶液在反应区中混合在一起,保持在有效产生包含有机二硫化物的气相的反应条件下,同时从反应区回收气相。 该方法是高效的,能够以高产率和纯度生产有机二硫化物。 该方法不仅非常容易和简单地进行,而且该方法(i)不需要形成液体有机二硫化物产物的有机相并且在该反应产物和该反应中使用的总水相之间进行分离 ,(ii)能够有效控制高放热反应,和(iii)使反应期间烷烃磺酸盐形成最小化。

    Preventing undesired odor in and/or purifying alkanediols
    9.
    发明授权
    Preventing undesired odor in and/or purifying alkanediols 失效
    预防烷基二醇中和/或纯化不良气味

    公开(公告)号:US06528665B1

    公开(公告)日:2003-03-04

    申请号:US10116482

    申请日:2002-04-03

    Abstract: Epoxyalkanes are subjected to at least one of the following washing operations: (1) washing with aqueous inorganic base, and then with aqueous borohydride, or vice versa; or (2) washing with an aqueous solution of both inorganic base and borohydride. Undesirable odor is reduced or eliminated from alkanediol(s), if produced from the treated epoxyalkane(s) by hydrolysis. Use of such washing procedures in the production of alkanediols is also described.

    Abstract translation: 对环氧烷烃进行以下洗涤操作中的至少一种:(1)用无机碱水溶液洗涤,然后用硼氢化钠洗涤,反之亦然; 或(2)用无机碱和硼氢化钠的水溶液洗涤。 如果通过水解由经处理的环氧烷烃生产,则从链烷二醇中减少或消除不希望的气味。 还描述了在制备链烷二醇中使用这种洗涤方法。

    Epoxidation of olefins
    10.
    发明授权
    Epoxidation of olefins 失效
    烯烃环氧化

    公开(公告)号:US06525208B1

    公开(公告)日:2003-02-25

    申请号:US10116508

    申请日:2002-04-03

    CPC classification number: C07D301/12

    Abstract: Mixed together are (i) hydrogen peroxide; (ii) 1-alkene; (iii) quaternary ammonium salt wherein at least one of the substituents contains at least six carbon atoms; (iv) boric acid, or both a 1,2-diol and boric acid; and (v) a preformed catalyst solution formed from hydrogen peroxide, at least one aqueous inorganic acid, and at least one tungstate salt, while water is continuously removed, such that a 1,2-epoxide is formed. A new method for purifying 1,2-epoxyalkanes is also described.

    Abstract translation: 混合在一起是(i)过氧化氢; (ii)1-烯烃; (iii)季铵盐,其中至少一个取代基含有至少6个碳原子; (iv)硼酸,或1,2-二醇和硼酸; 和(v)由过氧化氢,至少一种含水无机酸和至少一种钨酸盐形成的预成型催化剂溶液,同时连续除去水,从而形成1,2-环氧化物。 还描述了用于纯化1,2-环氧烷烃的新方法。

Patent Agency Ranking