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    Method for post-treating polyol esters
    3.
    发明授权
    Method for post-treating polyol esters 有权
    后处理多元醇酯的方法

    公开(公告)号：US09580378B2

    公开(公告)日：2017-02-28

    申请号：US14915448

    申请日：2014-08-29

    申请人： Oxea GmbH

    发明人： Jens Kubitschke ,  Thorsten Kreickmann ,  Jörg Arnold ,  Matthias Kramer ,  Heinz Strutz

    IPC分类号： C07C67/60 ,  C07C67/08 ,  C07C67/56

    CPC分类号： C07C67/60 ,  C07C67/08 ,  C07C67/56 ,  C07C69/28

    摘要： A batchwise process for aftertreatment of polyol esters prepared by reacting polyols of the general formula (II) H—(—O—[—CR1R2—]m—)o—OH  (II) in which R1 and R2 are each independently hydrogen, an alkyl radical having 1 to 5 carbon atoms, preferably methyl, ethyl or propyl, or a hydroxyalkyl radical having 1 to 5 carbon atoms, preferably the hydroxymethyl radical, m is an integer from 1 to 10, preferably 1 to 8 and especially 1, 2, 3 or 4, o is an integer from 2 to 15, preferably 2 to 8 and especially 2, 3, 4 or 5, with excess linear or branched aliphatic monocarboxylic acids having 3 to 20 carbon atoms and having a lower boiling point than the polyols used. The process is carried out in the presence of a Lewis acid and in the presence of an adsorbent, while removing the water formed, characterized in that the excess monocarboxylic acid is removed by distillation and water is added to the crude ester obtained at a temperature below the boiling point of water at the particular pressure and the crude ester with added water is aftertreated with avoidance of basic compounds, and the sparingly soluble conversion products and the adsorbent present in the esterification reaction are filtered off.

    摘要翻译： 用于后处理多元醇酯的分批方法，其通过使通式（II）的多元醇H - （ - O - [ - CR 1 R 2 - ] m - ）o-OH（II）反应制备，其中R 1和R 2各自独立地为氢， 具有1至5个碳原子的烷基，优选甲基，乙基或丙基，或具有1至5个碳原子的羟烷基，优选羟甲基，m为1至10，优选1至8，特别是1,2 ，3或4，o是2至15，优选2至8，特别是2，4或5的整数，其中具有3至20个碳原子并具有比其低的沸点的过量的直链或支链脂肪族单羧酸 使用多元醇 该方法在路易斯酸存在下并且在吸附剂存在下进行，同时除去形成的水，其特征在于通过蒸馏除去过量的单羧酸，并将水加入到在低于 在特定压力下的水的沸点和加入水的粗酯进行后处理，避免碱性化合物，并且滤出酯化反应中存在的微溶的转化产物和吸附剂。

    Method for Post-Treating Polyol Esters
    4.
    发明申请
    Method for Post-Treating Polyol Esters 有权
    后处理多元醇酯的方法

    公开(公告)号：US20160207871A1

    公开(公告)日：2016-07-21

    申请号：US14915448

    申请日：2014-08-29

    申请人： OXEA GMBH

    发明人： Jens KUBITSCHKE ,  Thorsten KREICKMANN ,  Jörg ARNOLD ,  Matthias KRAMER ,  Heinz STRUTZ

    IPC分类号： C07C67/60

    CPC分类号： C07C67/60 ,  C07C67/08 ,  C07C67/56 ,  C07C69/28

    摘要： A batchwise process for aftertreatment of polyol esters prepared by reacting polyols of the general formula (II) H—(—O—[—CR1R2—]m—)o—OH   (II) in which R1 and R2 are each independently hydrogen, an alkyl radical having 1 to 5 carbon atoms, preferably methyl, ethyl or propyl, or a hydroxyalkyl radical having 1 to 5 carbon atoms, preferably the hydroxymethyl radical, m is an integer from 1 to 10, preferably 1 to 8 and especially 1, 2, 3 or 4, o is an integer from 2 to 15, preferably 2 to 8 and especially 2, 3, 4 or 5, with excess linear or branched aliphatic monocarboxylic acids having 3 to 20 carbon atoms and having a lower boiling point than the polyols used. The process is carried out in the presence of a Lewis acid and in the presence of an adsorbent, while removing the water formed, characterized in that the excess monocarboxylic acid is removed by distillation and water is added to the crude ester obtained at a temperature below the boiling point of water at the particular pressure and the crude ester with added water is aftertreated with avoidance of basic compounds, and the sparingly soluble conversion products and the adsorbent present in the esterification reaction are filtered off.

    摘要翻译： 用于后处理多元醇酯的分批方法，其通过使通式（II）的多元醇H - （ - O - [ - CR 1 R 2 - ] m - ）o-OH（II）反应制备，其中R 1和R 2各自独立地为氢， 具有1至5个碳原子的烷基，优选甲基，乙基或丙基，或具有1至5个碳原子的羟烷基，优选羟甲基，m为1至10，优选1至8，特别是1,2 ，3或4，o是2至15，优选2至8，特别是2，4或5的整数，其中具有3至20个碳原子并具有比其低的沸点的过量的直链或支链脂肪族单羧酸 使用多元醇 该方法在路易斯酸存在下并且在吸附剂存在下进行，同时除去形成的水，其特征在于通过蒸馏除去过量的单羧酸，并将水加入到在低于 在特定压力下的水的沸点和加入水的粗酯进行后处理，避免碱性化合物，并且滤出酯化反应中存在的微溶的转化产物和吸附剂。

    Method of recovering (meth) acrylic acid ester
    7.
    发明授权
    Method of recovering (meth) acrylic acid ester 有权
    回收（甲基）丙烯酸酯的方法

    公开(公告)号：US08772534B2

    公开(公告)日：2014-07-08

    申请号：US13055425

    申请日：2009-11-19

    申请人： Se-Won Baek ,  Hyun-Kyu Kim ,  Jun-Seok Ko ,  Kyoung-Su Ha ,  Sung-Koo Park ,  Dong-Hyun Woo

    发明人： Se-Won Baek ,  Hyun-Kyu Kim ,  Jun-Seok Ko ,  Kyoung-Su Ha ,  Sung-Koo Park ,  Dong-Hyun Woo

    IPC分类号： C07C69/54 ,  C07C67/48

    CPC分类号： C07C67/10 ,  C07C67/60 ,  C07C69/54

    摘要： The present invention provides a method of recovering a (meth)acrylic acid ester, which comprises the steps of: (a) carrying out an esterification reaction between an alcohol and (meth)acrylic acid in the presence of a catalyst to obtain a (meth)acrylic acid ester, wherein a byproduct is generated together with the (meth)acrylic acid ester; and (b) subjecting the byproduct generated in step (a) to a reaction with a catalyst and water in a reactor, wherein the water is fed into the reactor in order that water content exceeds 0 wt % but is 10 wt % or less in the reactor based on the total weight of reactants comprising the byproduct, the catalyst and the water, and thereby separating the (meth)acrylic acid, the alcohol and the (meth)acrylic acid ester contained in the byproduct from the byproduct to obtain the (meth)acrylic acid, the alcohol and the (meth)acrylic acid ester as a recovered product.

    摘要翻译： 本发明提供一种回收（甲基）丙烯酸酯的方法，其包括以下步骤：（a）在催化剂存在下，在醇和（甲基）丙烯酸之间进行酯化反应，得到（甲基） ）丙烯酸酯，其中与（甲基）丙烯酸酯一起产生副产物; 和（b）使在步骤（a）中产生的副产物与反应器中的催化剂和水反应，其中将水进料到反应器中，以使水含量超过0重量％，但为10重量％以下 反应器基于包含副产物，催化剂和水的反应物的总重量，从而将副产物中所含的（甲基）丙烯酸，醇和（甲基）丙烯酸酯从副产物中分离出来，得到（ 甲基）丙烯酸，醇和（甲基）丙烯酸酯作为回收产物。

    PRODUCTION AND PURIFICATION OF ESTERS OF POLYUNSATURATED FATTY ACIDS
    8.
    发明申请
    PRODUCTION AND PURIFICATION OF ESTERS OF POLYUNSATURATED FATTY ACIDS 有权
    聚氧乙烯脂肪酸酯的生产和纯化

    公开(公告)号：US20140128465A1

    公开(公告)日：2014-05-08

    申请号：US14154140

    申请日：2014-01-13

    申请人： DSM IP Assets B.V.

    发明人： Krishna Raman ,  Jung Lee ,  Neil Leininger ,  Chris Luigart

    IPC分类号： C07C67/60 ,  C07C69/587

    CPC分类号： C07C69/587 ,  A21D2/16 ,  A23K20/158 ,  A23L33/12 ,  C07C67/03 ,  C07C67/08 ,  C07C67/60 ,  C11C3/003 ,  C07C69/533

    摘要： The present invention includes methods for producing and purifying esters of polyunsaturated fatty acids that include reacting a composition having triglycerides with polyunsaturated fatty acid residues in the presence of an alcohol and a base to produce an ester of a polyunsaturated fatty acid from the triglycerides. The composition can be a polyunsaturated fatty acid-containing composition that has not been conventionally processed. The reacted composition can be further processed by distillation.

    摘要翻译： 本发明包括用于生产和纯化多不饱和脂肪酸酯的方法，其包括在醇和碱的存在下使具有甘油三酯的组合物与多不饱和脂肪酸残基反应以从甘油三酸酯生产多不饱和脂肪酸的酯。 组合物可以是未经常规加工的含多不饱和脂肪酸的组合物。 可以通过蒸馏进一步处理反应的组合物。

    Method for producing high purity terminal olefin compound
    10.
    发明授权
    Method for producing high purity terminal olefin compound 有权
    高纯度末端烯烃化合物的制备方法

    公开(公告)号：US08609886B2

    公开(公告)日：2013-12-17

    申请号：US13262372

    申请日：2010-01-08

    申请人： Kei Miyoshi ,  Goro Asanuma

    发明人： Kei Miyoshi ,  Goro Asanuma

    IPC分类号： C07C67/48

    CPC分类号： C07C45/85 ,  C07C7/005 ,  C07C7/04 ,  C07C45/82 ,  C07C67/60 ,  C07C253/34 ,  C07C11/02 ,  C07C47/21 ,  C07C69/533 ,  C07C255/07

    摘要： An industrially advantageous method for producing a high purity terminal olefin is disclosed, comprising the steps of (a) contacting a mixture comprising a terminal olefin represented by formula (1): and one or more corresponding internal olefins as impurities, with a brominating agent in the presence of water or an alcohol, to convert the internal olefin(s) to compound(s) having a higher boiling point than the terminal olefin; and (b) purifying the terminal olefin by distillation from the reaction mixture.

    摘要翻译： 公开了一种用于生产高纯度末端烯烃的工业上有利的方法，其包括以下步骤：（a）将包含由式（1）表示的末端烯烃与一种或多种相应的内部烯烃作为杂质的混合物与溴化剂 存在水或醇，将内烯烃转化成沸点高于末端烯烃的化合物; 和（b）通过蒸馏从反应混合物中纯化末端烯烃。