公开(公告)号：US07576228B2

公开(公告)日：2009-08-18

申请号：US10595174

申请日：2004-12-02

Applicant: Christoph Rüdinger ,  Ragnar Bogner ,  Hans-Jürgen Eberle ,  Johann Weis

Inventor： Christoph Rüdinger ,  Ragnar Bogner ,  Hans-Jürgen Eberle ,  Johann Weis

IPC: C07F7/04

CPC classification number: C07F7/1892

Abstract: A process for preparing isocyanoatoorganosilanes by thermolysis of carbamatoorganosilanes in the presence of microwave radiation, optionally employing homogeneous or heterogeneous catalysis, provides isocyanatoorganosilane product in higher yield than prior art thermolyses, and with fewer byproducts. A continuous process is thus possible.

Abstract translation: 在微波辐射的存在下，任选地使用均相或非均相催化的氨基甲酰硅氧烷热解制备异氰酰基有机硅烷的方法提供了比现有技术的热分解产物更高产率的异氰酸酯基有机硅烷产物，并且具有较少的副产物。 因此，连续的过程是可能的。

公开(公告)号：US07385069B2

公开(公告)日：2008-06-10

申请号：US10595173

申请日：2004-12-02

Applicant: Christoph Rüdinger ,  Hans-Jürgen Eberle

Inventor： Christoph Rüdinger ,  Hans-Jürgen Eberle

IPC: C07F7/02

CPC classification number: B01J8/1836 ,  B01J8/0055 ,  B01J2219/0004 ,  B01J2219/00083 ,  B01J2219/00141 ,  C07F7/1892

Abstract: Isocyanatosilanes are prepared by themolyzing carbamatosilanes in a fluidized bed reactor containing fluidized solid particles. The process substantially avoids the deposition of solid reaction by products in the reactor.

Abstract translation: 异氰蔗糖通过在含有流化固体颗粒的流化床反应器中溶解氨基甲酰硅烷来制备。 该方法基本上避免了产物在反应器中沉积固体反应。

公开(公告)号：US06695952B1

公开(公告)日：2004-02-24

申请号：US10030533

申请日：2002-01-09

Applicant: Christoph Rüdinger ,  Harald Herbert Voit ,  Michael Hallmann ,  Mehmet Günaltay ,  Barbara Geborene Neé Reil Wild ,  Hans Jürgen Eberle

Inventor： Christoph Rüdinger ,  Harald Herbert Voit ,  Michael Hallmann ,  Mehmet Günaltay ,  Barbara Geborene Neé Reil Wild ,  Hans Jürgen Eberle

IPC: B01D1100

CPC classification number: C07C51/44 ,  C07C51/46 ,  C07C51/48 ,  Y10S203/20 ,  C07C53/08 ,  C07C53/02

Abstract: A method for the separation and purification of an aqueous mixture of main components, namely acetic acid and formic acid and non-volatiles by extraction, uses a solvent in a circulatory system. A raffinate stream is mixed with the larger proportion of water from a solvent stripper column (11) for the removal of water. The extraction stream is introduced into a solvent distillation column (8), from which in a first step involving the use of a mixture (A) containing a larger proportion of the solvent is separated out via a header and a mixture (B) of formic acid, water and solvent is separated out via a side offtake and a mixture (C) of acetic acid and non-volatiles is also separated out. A mixture (B) is introduced into a formic acid distillation column (4) for further processing, and a mixture (C) is introduced into an acetic acid distillation column (5), and purified acetic acid is subsequently isolated in the acetic acid distillation column (5) from the header. Pure formic acid is isolated at the settling basin of the formic acid distillation column (4).

Abstract translation: 通过提取分离和纯化主要成分的水性混合物，即乙酸和甲酸和非挥发物的方法，在循环系统中使用溶剂。 将萃余液流与来自溶剂汽提塔（11）的较大比例的水混合以除去水。 将萃取物流引入溶剂蒸馏塔（8）中，在包含较大比例溶剂的混合物（A）的第一步骤中，通过头部和甲酸的混合物（B） 酸，水和溶剂通过侧面分离，乙酸和非挥发物的混合物（C）也被分离出来。 将混合物（B）引入甲酸蒸馏塔（4）中进一步处理，并将混合物（C）引入乙酸蒸馏塔（5）中，随后在乙酸蒸馏中分离纯化的乙酸 列（5）。 在甲酸蒸馏塔（4）的沉降池中分离出纯甲酸。

公开(公告)号：US06624114B1

公开(公告)日：2003-09-23

申请号：US09709832

申请日：2000-11-10

Applicant: Hans-Jürgen Eberle ,  Dirk Groke ,  Christoph Rüdinger ,  Ulrich Wecker

Inventor： Hans-Jürgen Eberle ,  Dirk Groke ,  Christoph Rüdinger ,  Ulrich Wecker

IPC: B01J3200

CPC classification number: C07C51/25 ,  B01J21/063 ,  B01J23/22 ,  B01J23/28 ,  B01J35/026 ,  C07C51/215 ,  C07C51/265 ,  Y02P20/582 ,  Y10S261/72 ,  C07C53/08 ,  C07C63/16

Abstract: The invention relates to supported catalysts consisting of an active material on an inert support in the shape of rings, wherein the rings have one or more notches in the upper and/or lower flat side of the ring.

Abstract translation: 本发明涉及由环形惰性载体上的活性材料组成的负载催化剂，其中环在环的上部和/或下部平坦侧具有一个或多个凹口。

公开(公告)号：US06884909B2

公开(公告)日：2005-04-26

申请号：US10285206

申请日：2002-10-31

Applicant: Christoph Rüdinger ,  Harald Herbert Voit ,  Hans-Jürgen Eberle

Inventor： Christoph Rüdinger ,  Harald Herbert Voit ,  Hans-Jürgen Eberle

IPC: C07B61/00 ,  C07C51/245 ,  C07C51/44 ,  C07C51/48 ,  C07C53/02 ,  C07C53/08 ,  C07B53/00

CPC classification number: C07C51/245 ,  C07C53/08 ,  C07C53/02

Abstract: A process for preparing saturated carboxylic acids having from one to four carbon atoms by gas-phase oxidation, includes reacting 2-butanone with oxygen over a coated catalyst which is an inert nonporous support body and a catalytically active mixed oxide composition comprising (a) one or more oxides selected from the group consisting of titanium dioxide, zirconium dioxide, tin dioxide and aluminum oxide, and (b) from 0.1% to 1.5% by weight, based on the weight of the component (a) and per m2/g of specific surface area of the component (a), of vanadium pentoxide, applied to the external surface of the support body.

Abstract translation: 通过气相氧化制备具有1-4个碳原子的饱和羧酸的方法包括使2-丁酮与氧反应在作为惰性无孔载体的涂覆催化剂和催化活性混合氧化物组合物上，该组合物包含（a）一种 或更多选自二氧化钛，二氧化锆，二氧化锡和氧化铝的氧化物，和（b）基于组分（a）和每摩尔重量的0.1重量％至1.5重量％ （a）的五氧化二钒的比表面积的2×2 / g，施加到支撑体的外表面。

公开(公告)号：US06793777B1

公开(公告)日：2004-09-21

申请号：US10009507

申请日：2001-12-05

Applicant: Christoph Rüdinger ,  Harald Herbert Voit ,  Michael Hallmann ,  Mehmet Günaltay ,  Barbara Reil ,  Hans-Jürgen Eberle

Inventor： Christoph Rüdinger ,  Harald Herbert Voit ,  Michael Hallmann ,  Mehmet Günaltay ,  Barbara Reil ,  Hans-Jürgen Eberle

IPC: B01D314

CPC classification number: C07C51/48 ,  C07C51/44 ,  Y10S203/08 ,  Y10S203/20 ,  C07C53/02 ,  C07C53/08

Abstract: The invention relates to a method for separating and purifying an aqueous mixture that mainly consists of acetic acid, formic acid and high-boiling substances by extraction with a solvent in a cyclic process. The inventive method is characterized in that the flow of raffinate is fed to a solvent stripping column (11) with the major part of the water in order to remove the water from the cycle. The flow of extract is fed to a solvent recovery distillation column (8). In a first step, a mixture (A) that consists of water and solvent, is separated by overhead distillation. A mixture (B) that consists of acetic acid, formic acid and high-boiling substances is separated via a sump. Once the formic acid is removed in a column (29), mixture (B) is separated in an acetic acid distillation column to give pure acetic acid and high-boiling substances. Mixture (A) is fed to a phase separator and the aqueous phase is returned to the solvent stripping column (11) together with any residual portions of the solvent while the organic phase is returned to the extractor (8).

Abstract translation: 本发明涉及一种通过在循环过程中用溶剂萃取来分离和纯化主要由乙酸，甲酸和高沸点物质组成的含水混合物的方法。 本发明的方法的特征在于，萃余液的流动与主要部分的水一起进料到溶剂汽提塔（11），以便从循环中除去水。 将萃取物流送入溶剂回收蒸馏塔（8）。 在第一步中，由水和溶剂组成的混合物（A）通过塔顶蒸馏分离。 由乙酸，甲酸和高沸点物质组成的混合物（B）通过贮槽分离。 一旦在柱（29）中除去甲酸后，将混合物（B）在乙酸蒸馏塔中分离，得到纯乙酸和高沸点物质。 将混合物（A）进料到相分离器中，并将水相与溶剂的任何残留部分一起返回到溶剂汽提塔（11），同时将有机相返回到萃取器（8）。