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21 条记录 (耗时 0.011 秒)

    Phosphorus esters of 1-cyanoethyl-1,2,4-triazol-3-ols
    1.
    发明授权
    Phosphorus esters of 1-cyanoethyl-1,2,4-triazol-3-ols 失效
    1-氰基乙基-1,2,4-三唑-3-醇的磷酸酯

    公开(公告)号：US4172080A

    公开(公告)日：1979-10-23

    申请号：US527330

    申请日：1974-11-26

    申请人： Dag Dawes ,  Beat Bohner ,  Willy Meyer

    发明人： Dag Dawes ,  Beat Bohner ,  Willy Meyer

    IPC分类号： A01N57/16 ,  A01N57/08 ,  A01N57/24 ,  C07F9/6518 ,  C07F9/65

    CPC分类号： A01N57/08 ,  C07F9/65183

    摘要： New 1,2,4-triazoles, their manufacture and use as active ingredient on pest control is disclosed. The triazoles correspond to the formula ##STR1## wherein R.sub.1 represents C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy or C.sub.1 -C.sub.6 -alkylthio,R.sub.2 represents C.sub.1 -C.sub.6 -alkyl,R.sub.3 represents hydrogen, chlorine, bromine, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkylthio, C.sub.3 -C.sub.5 -alkenylthio or C.sub.3 -C.sub.5 -alkynylthio, andX represents oxygen or sulphur.

    摘要翻译： 新的1,2,4-三唑，其制造和用作有害生物控制的有效成分。 三唑对应于下式：其中R1代表C1-C6-烷基，C1-C6-烷氧基或C1-C6-烷硫基，R2代表C1-C6-烷基，R3代表氢，氯，溴，C1-C6- 烷基，C 1 -C 6 - 烷硫基，C 3 -C 5 - 烯硫基或C 3 -C 5 - 炔硫基，X表示氧或硫。

    Process for preparing 1,2,4-triazole derivatives
    2.
    发明授权
    Process for preparing 1,2,4-triazole derivatives 失效
    制备1,2,4-三唑衍生物的方法

    公开(公告)号：US4123437A

    公开(公告)日：1978-10-31

    申请号：US773026

    申请日：1977-02-28

    申请人： Beat Bohner ,  Dag Dawes ,  Willy Meyer

    发明人： Beat Bohner ,  Dag Dawes ,  Willy Meyer

    IPC分类号： C07D249/12 ,  C07F9/6518 ,  C07F9/65

    CPC分类号： C07F9/65183 ,  C07D249/12

    摘要： 1,2,4-TRIAZOLE DERIVATIVES WHICH HAVE PARTICULAR IMPORTANCE AS INTERMEDIATES FOR, E.G., THE PREPARATION OF ACTIVE SUBSTANCES FOR PEST CONTROL, CORRESPONDING TO THE FORMULA ##STR1## wherein R.sup.1 represents an unsubstituted or substituted alkyl, alkenyl, or alkynyl, naphthyl, benzyl, phenylethyl, ##STR2## or phenylpropyl radical, or a mono or polycyclic cycloalkyl radical which can be bound by way of an alkylene bridge member, or a substituted phenyl radical,And new processes for the preparation of compounds of the formula ##STR3## wherein R represents hydrogen, an optionally substituted alkyl, alkenyl or alkynyl radical, an optionally substituted phenyl, naphthyl, benzyl, phenylethyl or phenylpropyl radical, a mono- or polycyclic cycloalkyl radical which can be bound by way of an alkylene bridge member and/or be substituted by alkyl, or a partially hydrogenated naphthyl radical, which processes are performed by addition to a hydrazine of the formulaR -- NH--NH.sub.2or to a hydrazone of the formula ##STR4## wherein R has the above given meaning, R.sub.1 represents hydrogen or lower alkyl and R.sub.2 represents lower alkyl, of an alkoxy-carbonyl-isothiocyanate of the formulaalkyl--O--CO--NCSand subsequent closure of the triazole ring in the resulting thiosemicarbazide of the formula ##STR5## by the splitting-off of an alkanol (alkyl--OH), are disclosed.

    摘要翻译： 具有特异性重要性的1,2,4-三唑衍生物作为EG的中间体，用于制备用于病虫害控制的活性物质，对应于本发明的化合物，其中R 1表示未取代或取代的烷基，烯基或炔基，萘基， 苄基，苯基乙基，苯丙基或可以通过亚烷基桥基或取代的苯基结合的单环或多环环烷基，以及用于制备化合物的新方法 其中R表示氢，任选取代的烷基，烯基或炔基，任选取代的苯基，萘基，苄基，苯基乙基或苯基丙基，可以通过亚烷基桥连接体和/或 被烷基或部分氢化的萘基取代，该方法通过加入式R-NH-NH 2的肼或加成式的腙进行 其中R具有上述给定含义，R 1表示氢或低级烷基，R 2表示低级烷基，式ALKYL-O-CO-NCS的烷氧羰基 - 异硫氰酸酯，随后在三 公开了通过分解链烷醇（烷基-OH）得到的式“IMAGE”的氨基硫脲。

    O,S-dialkyl- and O-alkyl-S-alkoxyalkyl-S-1,2,4-oxa-diazolyl-3-methylene dithiophosphates
    3.
    发明授权
    O,S-dialkyl- and O-alkyl-S-alkoxyalkyl-S-1,2,4-oxa-diazolyl-3-methylene dithiophosphates 失效
    O，S-二烷基 - 和O-烷基-S-烷氧基烷基-S-1,2,4-氧杂 - 二唑基-3-亚甲基二硫代磷酸酯

    公开(公告)号：US4028377A

    公开(公告)日：1977-06-07

    申请号：US517359

    申请日：1974-10-23

    申请人： Willy Meyer ,  Beat Bohner ,  Dag Dawes ,  Kurt Rufenacht

    发明人： Willy Meyer ,  Beat Bohner ,  Dag Dawes ,  Kurt Rufenacht

    IPC分类号： A01N57/16 ,  C07F9/653 ,  C07F9/165

    CPC分类号： A01N57/16 ,  C07F9/65318

    摘要： 1,2,4-Oxadiazoles, their manufacture and use as active ingredients in pesticides especially insecticides and acaricides. The compounds correspond to the formula ##STR1## wherein R.sub.1 represents hydrogen, unsubstituted alkyl, benzyl or phenyl, R.sub.2 represents methyl or ethyl, and R.sub.3 represents unsubstituted C.sub.1 -C.sub.7 alkyl optionally interrupted by oxygen or represents C.sub.3 -C.sub.4 alkenyl.

    摘要翻译： 1,2,4-恶二唑，其制造和用作农药，特别是杀虫剂和杀螨剂中的有效成分。 该化合物对应于下式：其中R 1表示氢，未取代的烷基，苄基或苯基，R 2表示甲基或乙基，R 3表示任选被氧中断或表示C 3 -C 4烯基的未取代的C 1 -C 7烷基。

    1,2,4-Triazolyl-phosphoric and -phosphonic acid esters
    4.
    发明授权
    1,2,4-Triazolyl-phosphoric and -phosphonic acid esters 失效
    1,2,4-三唑基 - 磷酸和膦酸酯

    公开(公告)号：US3992399A

    公开(公告)日：1976-11-16

    申请号：US422038

    申请日：1973-12-05

    申请人： Beat Bohner ,  Dag Dawes ,  Willy Meyer

    发明人： Beat Bohner ,  Dag Dawes ,  Willy Meyer

    IPC分类号： A01N57/08 ,  C07D249/08 ,  C07D249/12 ,  C07F9/6518 ,  C07F9/65

    CPC分类号： C07F9/65185 ,  C07D249/08 ,  C07D249/12

    摘要： 1,2,4-Triazolylphosphoric and 1,2,4-triazolylphosphonic acid esters of the formula ##SPC1##Wherein R.sub.1 represents hydrogen, alkyl, cycloalkyl, phenyl, benzyl, or phenethyl, R.sub.2 represents substituted phenyl, benzyl, phenethyl, or unsubstituted diphenylmethyl, .beta.-naphthyl, or ##SPC2##R.sub.3 represents alkyl, alkoxy, alkylthio, amino, monoalkylamino or dialkylamino, R.sub.4 represents alkyl, and X represents oxygen or sulphur, a process for their manufacture and their use in pest control.

    摘要翻译： 1,2,4-三唑基磷酸和式+ q，10的1,2,4-三唑基膦酸酯，其中R1表示氢，烷基，环烷基，苯基，苄基或苯乙基，R2表示取代的苯基，苄基，苯乙基或 未取代的二苯基甲基，β-萘基或+ q，11 R 3表示烷基，烷氧基，烷硫基，氨基，单烷基氨基或二烷基氨基，R 4表示烷基，X表示氧或硫，其制备方法及其在害虫防治中的应用。

    Process for the production of 3-hydroxy-1,2,4-triazole derivatives
    6.
    发明授权
    Process for the production of 3-hydroxy-1,2,4-triazole derivatives 失效
    3-羟基-1,2,4-三唑衍生物的制备方法

    公开(公告)号：US4055572A

    公开(公告)日：1977-10-25

    申请号：US707148

    申请日：1976-07-20

    申请人： Dag Dawes ,  Rudolph C. Thummel

    发明人： Dag Dawes ,  Rudolph C. Thummel

    IPC分类号： C07D249/12

    CPC分类号： C07D249/12

    摘要： A process for the production of 3-hydroxy-1,2,4-triazole derivatives of formula I ##STR1## wherein R.sub.1 and R.sub.2 each represent a straight-chain or branched-chain alkyl group having 1 to 6 carbon atoms, or a cycloalkyl group having 3 to 6 carbon atoms, andX represents oxygen or sulphur,Which process comprises adding to a 1-alkyl-1-cyanohydrazine of formula II ##STR2## wherein R.sub.1 has the meaning given under formula I, a compound of formula IIIr.sub.2 -- xh (iii)wherein R.sub.2 and X have the meanings given under formula I;and subsequently cyclising the addition product by reaction with a compound of formula IV ##STR3## wherein R.sub.3 and R.sub.4 independently of one another represent chlorine or an alkoxy group having 1 to 4 carbon atoms.The 3-hydroxy-1,2,4-triazole derivatives are valuable intermediates for producing phosphoric acid esters which can be used as pesticidal agents, particularly as insecticides and nematicides.

    摘要翻译： 制备式I（I）的3-羟基-1,2,4-三唑衍生物的方法其中R 1和R 2各自表示具有1至6个碳原子的直链或支链烷基， 或具有3至6个碳原子的环烷基，X表示氧或硫。该方法包括加入式II（II）的1-烷基-1-氰基喹啉其中R 1具有式I给出的含义， 式III的化合物R2-XH（III）其中R2和X具有式I给出的含义; 然后通过与式IV（IV）化合物反应使加成产物环化，其中R 3和R 4彼此独立地表示氯或具有1至4个碳原子的烷氧基。

    Pesticidal 2-phenyl-1,2,3-triazolyl-(4) and-triazox-(1)-yl-(4) phosphate and thiosphosphate esters
    7.
    发明授权
    Pesticidal 2-phenyl-1,2,3-triazolyl-(4) and-triazox-(1)-yl-(4) phosphate and thiosphosphate esters 失效
    农药2-苯基-1,2,3-三唑基 - （4）和 - 三唑氧 - （1） - 基 - （4）磷酸酯和硫代磷酸酯

    公开(公告)号：US4035487A

    公开(公告)日：1977-07-12

    申请号：US555009

    申请日：1975-03-03

    申请人： Beat Boehner ,  Dag Dawes ,  Haukur Kristinsson ,  Willy Meyer

    发明人： Beat Boehner ,  Dag Dawes ,  Haukur Kristinsson ,  Willy Meyer

    IPC分类号： C07F9/6518 ,  C07D249/06 ,  A01N9/36

    CPC分类号： C07F9/65183

    摘要： 1,2,3-Triazolyl phosphorus compounds, their manufacture and use as active ingredients for controlling insects, representatives of the order acarina and phytopathogenic nematodes. The compounds correspond to the formula ##STR1## wherein R.sub.1 represents alkyl, alkoxy, alkylthio, alkoxyalkylthio, amino, monoalkylamino or dialkylamino,R.sub.2 represents alkoxy, alkylthio, amino, monoalkylamino or dialkylamino,R.sub.3 represents unsubstituted or substituted phenyl,Y represents hydrogen, chlorine or bromine,n represents the numbers 0 or 1, andX represents oxygen or sulphur.

    摘要翻译： 1,2,3-三唑基磷化合物，其制造和用途作为控制昆虫的有效成分，螨类和植物病原性线虫的代表。 化合物对应于下式：其中R 1表示烷基，烷氧基，烷硫基，烷氧基烷硫基，氨基，单烷基氨基或二烷基氨基，R 2表示烷氧基，烷硫基，氨基，单烷基氨基或二烷基氨基，R 3表示未取代或取代的苯基，Y表示氢， 或溴，N表示数字0或1，X表示氧或硫。

    Insecticidal and acaricidal 1-phenyl-1-P-propargyloxyphenyl-2-nitroethanes
    8.
    发明授权
    Insecticidal and acaricidal 1-phenyl-1-P-propargyloxyphenyl-2-nitroethanes 失效
    杀虫剂和杀螨剂的1-苯基-1-P - 炔丙氧基苯基-2-硝基乙胺

    公开(公告)号：US4000316A

    公开(公告)日：1976-12-28

    申请号：US645124

    申请日：1975-12-29

    申请人： Beat Bohner ,  Dag Dawes ,  Willy Meyer

    发明人： Beat Bohner ,  Dag Dawes ,  Willy Meyer

    IPC分类号： A01N9/24

    摘要： 1-Phenyl-1-p-propargyloxyphenyl-2-nitro-ethane derivatives of the formula ##STR1## wherein Z represents the radical ##STR2## and of the symbolsX and Y one represents hydrogen, fluorine, chlorine, bromine, C.sub.1 -C.sub.3 -alkyl, C.sub. 1 -C.sub.3 -alkoxy, propargyloxy or C.sub.1 -C.sub.3 -alkylthio, and the other represents propargyloxy,Process for their preparation and their use in pest control.

    摘要翻译： 其中Z代表基团，符号X和Y表示氢，氟，氯，溴，C 1 -C 3的1-苯基-1-对 - 炔丙氧基苯基-2-硝基 - 乙烷衍生物 - 烷基，C 1 -C 3 - 烷氧基，炔丙氧基或C 1 -C 3 - 烷硫基，另一个表示炔丙氧基，其制备方法及其在病虫害控制中的用途。

    Insecticidal and acaricidal composition and method with triazolyl phosphoric esters acid
    9.
    发明授权
    Insecticidal and acaricidal composition and method with triazolyl phosphoric esters acid 失效
    杀虫和杀螨组合物和方法用三唑基磷酸酯酸

    公开(公告)号：US3973010A

    公开(公告)日：1976-08-03

    申请号：US539143

    申请日：1975-01-07

    申请人： Dag Dawes ,  Beat Bohner

    发明人： Dag Dawes ,  Beat Bohner

    IPC分类号： A01N57/16 ,  C07F9/6518 ,  A01N9/36

    CPC分类号： C07F9/65185 ,  A01N57/16

    摘要： Insecticidal and acaricidal composition and method utilizing triazolyl phosphoric acid esters of the formula ##EQU1##wherein R.sub.1 represents a phenyl group susbstituted by one or more fluorine atoms or lower haloalkyl groups or by at least one chlorine atom and at least one fluorine atom or lower haloalkyl groups, R.sub.2 and R.sub.3 are each lower alkyl and X and Y are each oxygen or sulphur.

    摘要翻译： 杀虫剂和杀螨剂的组合物和利用式R 1 -N的NX的三唑基磷酸酯的方法：NX | PARALLEL PARALLEL OR2 CH COP ANGLE YR3 N其中R 1表示被一个或多个氟原子或低级卤代烷基取代的苯基或由 至少一个氯原子和至少一个氟原子或低级卤代烷基，R2和R3各自为低级烷基，X和Y各自为氧或硫。