公开(公告)号：US5077412A

公开(公告)日：1991-12-31

申请号：US414998

申请日：1989-09-29

Applicant: Josef Ehrenfreund ,  Manfred Boger ,  Odd Kristiansen ,  Jozef Drabek ,  Haukur Kristinsson

Inventor： Josef Ehrenfreund ,  Manfred Boger ,  Odd Kristiansen ,  Jozef Drabek ,  Haukur Kristinsson

IPC: A01N47/30 ,  A01N47/32 ,  A01N47/40 ,  A01N47/42 ,  C07D207/34 ,  C07D209/32 ,  C07D231/20 ,  C07D233/70 ,  C07D235/26 ,  C07D249/12 ,  C07D257/04 ,  C07D263/38 ,  C07D263/58 ,  C07D271/10 ,  C07D271/113 ,  C07D277/20 ,  C07D277/34 ,  C07D277/68 ,  C07D285/08 ,  C07D285/12 ,  C07D285/13 ,  C07D307/58 ,  C07D333/32 ,  C07D333/34

CPC classification number: C07D271/113 ,  A01N47/30 ,  A01N47/32 ,  A01N47/40 ,  A01N47/42 ,  C07D233/70 ,  C07D249/12 ,  C07D277/34 ,  C07D277/68 ,  C07D285/08 ,  C07D285/13

Abstract: The invention relates to novel substituted phenylthioureas, phenylisothioureas and phenylcarbodiimides of formula I ##STR1## wherein Z is ##STR2## or --N.dbd.C.dbd.N--; R.sub.1 is C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.10 alkenyl, C.sub.3 -C.sub.10 alkynyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.1 -C.sub.3 alkyl substituted by 1 or 2 C.sub.3 -C.sub.6 cycloalkyl radicals, or is alkoxyalkyl containing a total of 3 to 10 carbon atoms, halogen-substituted C.sub.1 -C.sub.12 alkyl, polycyclic C.sub.7 -C.sub.10 cycloalkyl, or phenyl(C.sub.1 -C.sub.5)alkyl which may be substituted in the phenyl moiety by 1 or 2 identical or different members selected from the group consisting of halogen, methoxy, ethoxy and C.sub.1 -C.sub.5 alkyl,R.sub.2 is hydrogen or C.sub.1 -C.sub.5 alkyl,R.sub.3 is C.sub.1 -C.sub.5 alkyl or C.sub.3 -C.sub.6 cycloalkyl,R.sub.4 is hydrogen or C.sub.1 -C.sub.4 alkyl,R.sub.5 is a 5-membered heterocyclic radical containing 1 to 4 hetero atoms selected from the group consisting of N, O and S, which radical may be substituted at the carbon or nitrogen atoms by 1 to 3 of the substituents R.sub.6, R.sub.7 and R.sub.8, or is a 5-membered heterocyclic radical which may be fused with benzene nuclei and which contains 1 or 2 hetero atoms selected from the group consisting of N, O and S and can be substituted at the carbon or nitrogen atoms by 1 to 3 of the substituents R.sub.6, R.sub.7 and R.sub.8,R.sub.6 and R.sub.7 are each independently of the other hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, halogen-substituted C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy; halogen-substituted C.sub.1 -C.sub.4 alkoxy, phenyl, or C.sub.1 -C.sub.4 alkylthio,R.sub.8 is hydrogen or C.sub.1 -C.sub.4 alkyl, andR.sub.9 is C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, C.sub.3 -C.sub.4 alkynyl, alkoxyalkyl containing a total of 10 carbon atoms, or alkylthioalkyl containing a total of 10 carbon atomsand to the salts thereof with acids and bases. The invention further relates to the preparation of these compounds and to the use thereof in pest control, and to novel intermediates.

公开(公告)号：US4629802A

公开(公告)日：1986-12-16

申请号：US707358

申请日：1985-03-01

Applicant: Haukur Kristinsson ,  Werner Topfl

Inventor： Haukur Kristinsson ,  Werner Topfl

IPC: C07D251/46 ,  A01N47/36 ,  A01N47/42 ,  C07C67/00 ,  C07C301/00 ,  C07C303/38 ,  C07C303/40 ,  C07C311/63 ,  C07D239/42 ,  C07D239/47 ,  C07D251/16 ,  C07D521/00 ,  C07C119/20

CPC classification number: C07D521/00

Abstract: A novel process for producing sulfonylureas of the formula I having a herbicidal action and an action regulating plant growth ##STR1## wherein A is an unsubstituted or substituted phenyl, naphthyl, furan, thiophene or pyridine group, E is a nitrogen atom or the methine group, R.sub.a is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -haloalkyl, C.sub.1 -C.sub.5 -alkoxy, C.sub.1 -C.sub.5 -haloalkoxy, C.sub.1 -C.sub.5 -alkylthio or C.sub.2 -C.sub.10 -alkoxyalkoxy, and R.sub.b is the same as R.sub.a or is an unsubstituted or substituted amino group, and salts thereof, which process comprises firstly condensing an imidocarbonic acid ester with a sulfonyl chloride of the formula II to the sulfonylimidocarbonic acid diester of the formula IV ##STR2## wherein R is an alkyl group, and reacting this in an ethereal solvent in the presence of sodium hydride or potassium tertbutylate with a 2-aminopyrimidine or 2-amino-1,3,5-triazine of the formula V, and finally reacting the formed sulfonylisourea of the formula VI in an organic solvent with hydrochloric acid to obtain the sulfonylurea of the formula I, and isolating this as such or as a salt; ##STR3## The sulfonylimidocarbonic acid diesters of the formula IV and certain sulfonylisoureas of the formula VI, required as intermediates, are novel compounds. The process has the advantage that no sulfonamides are needed as intermediates.

Abstract translation: 一种制备具有除草作用和调节植物生长作用的式I的磺酰脲的新方法，其中A是未取代或取代的苯基，萘基，呋喃，噻吩或吡啶基，E是氮原子或 次甲基，R a为氢，卤素，C 1 -C 5 - 烷基，C 1 -C 5 - 卤代烷基，C 1 -C 5 - 烷氧基，C 1 -C 5 - 卤代烷氧基，C 1 -C 5 - 烷硫基或C 2 -C 10 - 烷氧基烷氧基，Rb为 与R a相同或为未取代或取代的氨基及其盐，该方法包括首先将亚氨基碳酸酯与式II的磺酰氯缩合成式IV的磺酰亚胺基碳酸二酯其中R是烷基 并将其在惰性溶剂中，在氢化钠或叔丁醇钾存在下与式V的2-氨基嘧啶或2-氨基-1,3,5-三嗪反应，最后使形成的式VI的磺酰基异脲 在有盐酸的有机溶剂中 在式I的磺酰脲中，并将其分离为盐或盐; 作为中间体，式IV的磺酰亚胺基碳酸二酯和式VI的某些磺酰基异脲是新化合物。 该方法的优点是不需要磺酰胺作为中间体。

公开(公告)号：US5783704A

公开(公告)日：1998-07-21

申请号：US669452

申请日：1996-06-28

Applicant: Henry Szczepanski ,  Haukur Kristinsson ,  Peter Maienfisch ,  Josef Ehrenfreund

Inventor： Henry Szczepanski ,  Haukur Kristinsson ,  Peter Maienfisch ,  Josef Ehrenfreund

IPC: A01C20060101 ,  A01N20060101 ,  A01N43/40 ,  A01N43/50 ,  A01N43/54 ,  A01N43/653 ,  A01N43/707 ,  A01N43/76 ,  A01N43/78 ,  A01N43/824 ,  A01N43/88 ,  C07D20060101 ,  C07D253/06 ,  C07D285/12 ,  C07D285/13 ,  C07D401/12 ,  C07D413/12 ,  C07D417/12

CPC classification number: C07D253/06 ,  A01N43/40 ,  A01N43/50 ,  A01N43/653 ,  C07D285/13 ,  C07D401/12

Abstract: Compounds of formu (I) wherein n and Z are as defined in claim 1, and, where appropriate, tautomers thereof, in each case in free form, or in salt form, can be used as agrochemical active ingredients and can be prepared in a manner known per se.

Abstract translation: PCT No.PCT / EP94 / 04222 Sec。 371日期：1996年6月28日 102（e）日期1996年6月28日PCT 1994年12月19日PCT公布。 WO95 / 18123 PCT出版物 日期1995年7月6日，其中n和Z如权利要求1中所定义的formu（I）化合物，并且在适当的情况下，其互变异构体以游离形式或盐形式，可用作农业化学活性成分， 可以以本身已知的方式制备。

公开(公告)号：US5561230A

公开(公告)日：1996-10-01

申请号：US460342

申请日：1995-06-02

Applicant: Ernst Beriger ,  Haukur Kristinsson

Inventor： Ernst Beriger ,  Haukur Kristinsson

IPC: C07D253/06 ,  C07D271/10 ,  C07D271/113 ,  C07D401/12 ,  C07D413/06

CPC classification number: C07D253/06 ,  C07D271/113 ,  C07D401/12 ,  C07D413/06

Abstract: The invention relates to a process for the preparation of a compound of formula ##STR1## useful as intermediate for the preparation of pesticides, wherein R is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.1 -C.sub.4 alkyl substituted by from 1 to 10 halogen atoms or by from 1 to 3 radicals selected from the group consisting of C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 alkylthio and phenyl, phenyl or phenyl substituted by from 1 to 3 radicals selected from the group consisting of halogen, methyl, ethyl, methoxy, methylthio and nitro, which comprises reacting with hydrazine hydrate a compound of formula ##STR2## wherein R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.1 -C.sub.4 alkyl substituted by from 1 to 9 chlorine atoms, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 alkylthio, C.sub.1 -C.sub.3 alkylsulfinyl, C.sub.1 -C.sub.3 alkylsulfonyl, phenyl, phenyl substituted by from 1 to 3 radicals selected from the group consisting of halogen, methyl, ethyl, methoxy, methylthio and nitro, or pyridyl, and subjecting to hydrolysis the resulting compound of formula ##STR3##

Abstract translation: 本发明涉及制备式（I）化合物的方法，其可用作制备农药的中间体，其中R是氢，C 1 -C 6烷基，C 3 -C 6环烷基，被1至 10个卤素原子或1至3个选自C 1 -C 3烷氧基，C 1 -C 3烷硫基和苯基的基团，苯基或被1至3个选自卤素，甲基，乙基，甲氧基， 甲硫基和硝基，其包括与水合肼反应其中R 1是氢，C 1 -C 4烷基，C 3 -C 6环烷基，被1至9个氯原子取代的C 1 -C 4烷基，C 1 -C 3烷氧基，C 1 C 3烷硫基，C 1 -C 3烷基亚磺酰基，C 1 -C 3烷基磺酰基，苯基，被1至3个选自卤素，甲基，乙基，甲氧基，甲硫基和硝基或吡啶基的基取代的苯基，并将所得化合物 公式（III）

公开(公告)号：US4388464A

公开(公告)日：1983-06-14

申请号：US232752

申请日：1981-02-09

Applicant: Haukur Kristinsson ,  Beat Muller ,  Johannes P. Pachlatko

Inventor： Haukur Kristinsson ,  Beat Muller ,  Johannes P. Pachlatko

IPC: A01N25/32 ,  A01N43/824 ,  C07C251/32 ,  C07C259/10 ,  C07C311/16 ,  C07C317/32 ,  C07C317/44 ,  C07C317/46 ,  C07C317/48 ,  C07C323/47 ,  C07C327/20 ,  C07D213/53 ,  C07D213/61 ,  C07D213/64 ,  C07D213/65 ,  C07D213/69 ,  C07D213/70 ,  C07D213/79 ,  C07D215/32 ,  C07D215/34 ,  C07D233/26 ,  C07D233/86 ,  C07D235/14 ,  C07D235/16 ,  C07D249/06 ,  C07D263/56 ,  C07D263/58 ,  C07D277/64 ,  C07D285/12 ,  C07D285/125 ,  C07D285/13 ,  C07D307/20 ,  C07D307/52 ,  C07D309/20 ,  C07D309/32 ,  C07D311/58 ,  C07D317/58 ,  C07D335/06 ,  C07D339/06 ,  C07D339/08 ,  A01N43/82 ,  A01N47/40

CPC classification number: C07D213/53 ,  C07D213/61 ,  C07D213/64 ,  C07D213/65 ,  C07D213/69 ,  C07D213/70 ,  C07D213/79 ,  C07D215/32 ,  C07D215/34 ,  C07D233/26 ,  C07D233/86 ,  C07D235/14 ,  C07D235/16 ,  C07D249/06 ,  C07D263/56 ,  C07D277/64 ,  C07D285/12 ,  C07D285/125 ,  C07D285/13 ,  C07D307/20 ,  C07D307/52 ,  C07D309/20 ,  C07D309/32 ,  C07D311/58 ,  C07D317/58 ,  C07D335/06 ,  C07D339/06 ,  C07D339/08 ,  Y10S47/03

Abstract: A process for protecting cultivated plants against aggressive agricultural chemicals is described in which oxime derivatives of the formula ##STR1## are used as antidotes. Either the cultivated area for the cultivated plants or the cultivated plants themselves or parts of the plant (seeds, tubers, stem parts and the like), as desired, can be treated with these oxime derivatives, which are used as a dressing.Ar is a phenyl radical of the formula ##STR2## or Ar is also a 5-membered to 10-membered heterocyclic radical which contains not more than three identical or different hetero-atoms N, O and/or S and which can be bonded via a C.sub.1 - to C.sub.3 -aliphatic chain to the remainder of the molecule and which is substituted by R.sub.1, R.sub.2 or R.sub.3 and can be substituted by oxo or thiono; X is hydrogen, CN, halogen, C.sub.1 -C.sub.10 -alkyl, lower alkanoyl, --COOH, a carboxylic acid ester of a carboxamide radical; and Q is hydrogen, lower alkyl, which can be interrupted by hetero-atoms or substituted by halogen or cyano, lower alkenyl or halogenoalkenyl, lower alkynyl, C.sub.3 -C.sub.7 cycloalkyl, which is unsubstituted or substituted by halogen, or a lower alkanecarboxylic acid ester group, a lower alkanecarboxylic acid thioester group, a lower alkanecarboxamide group, an aliphatic acyl radical, an araliphatic, cycloaliphatic or substituted or unsubstituted aromatic or heterocyclic acyl radical, an alkylsulfonyl radical, a sulfonamide radical, a metal salt, a quaternized ammonium salt or an aliphatic, araliphatic, cycloaliphatic or substituted or unsubstituted aromatic or heterocyclic carbonic acid, thiocarbonic acid or carbamoyl radical.

Abstract translation: 描述了用于保护栽培植物免受侵袭性农药的方法，其中使用式“IMAGE”的肟衍生物作为解毒剂。 根据需要，可以用这些用作敷料的肟衍生物来处理栽培植物或栽培植物本身或植物的部分（种子，块茎，茎部等）的栽培面积。 Ar是下式的苯基或Ar也是5元至10元杂环基，其含有不超过三个相同或不同的杂原子N，O和/或S，并且可以通过 与分子的其余部分存在的C 1 -C 3 - 脂族链，并被R 1，R 2或R 3取代并且可被氧代或硫代替代; X是氢，CN，卤素，C 1 -C 10 - 烷基，低级烷酰基，-COOH，羧酰胺基的羧酸酯; Q为氢原子，可被杂原子或被卤素或氰基取代的低级烷基，低级链烯基或卤代烯基，低级炔基，未被取代或被卤素取代的C3-C7环烷基或低级链烷羧酸酯 低级链烷羧酸硫酯基，低级链烷酰胺基，脂族酰基，芳脂族，脂环族或取代或未取代的芳族或杂环酰基，烷基磺酰基，磺酰胺基，金属盐，季铵化铵盐或 脂族，芳脂族，脂环族或取代或未取代的芳族或杂环碳酸，硫代碳酸或氨基甲酰基。

公开(公告)号：US4254133A

公开(公告)日：1981-03-03

申请号：US42822

申请日：1979-05-29

Applicant: Haukur Kristinsson ,  Walter Traber

Inventor： Haukur Kristinsson ,  Walter Traber

IPC: A01N43/50 ,  C07D233/24

CPC classification number: C07D233/24

Abstract: Compositions containing active substances of the formula ##STR1## wherein R.sub.1 and R.sub.2, each independently of the other, represent hydrogen or alkyl of 1 to 10 carbon atoms, R.sub.3 and R.sub.4, each independently of the other, represent alkyl of 1 to 5 carbon atoms or halogen, preferably chlorine, and R.sub.5 represents hydrogen, alkyl of 1 to 5 carbon atoms or halogen, or an acid addition salt thereof for combating ectoparasites.

Abstract translation: 包含式IMA活性物质的组合物，其中R 1和R 2各自独立地表示氢或1至10个碳原子的烷基，R 3和R 4各自独立地表示1至5个碳原子的烷基 或卤素，优选氯，R5表示氢，1〜5个碳原子的烷基或卤素，或其酸加成盐，用于对抗外寄生物。

公开(公告)号：US6034083A

公开(公告)日：2000-03-07

申请号：US119285

申请日：1998-07-20

Applicant: Henry Szczepanski ,  Haukur Kristinsson ,  Peter Maienfisch ,  Josef Ehrenfreund

Inventor： Henry Szczepanski ,  Haukur Kristinsson ,  Peter Maienfisch ,  Josef Ehrenfreund

IPC: A01C20060101 ,  A01N20060101 ,  A01N43/40 ,  A01N43/50 ,  A01N43/54 ,  A01N43/653 ,  A01N43/707 ,  A01N43/76 ,  A01N43/78 ,  A01N43/824 ,  A01N43/88 ,  C07D20060101 ,  C07D253/06 ,  C07D285/12 ,  C07D285/13 ,  C07D401/12 ,  C07D413/12 ,  C07D417/12 ,  A61K31/53

CPC classification number: C07D253/06 ,  A01N43/40 ,  A01N43/50 ,  A01N43/653 ,  C07D285/13 ,  C07D401/12

Abstract: Compounds of formula ##STR1## wherein n and Z are as defined in claim 1, and, where appropriate, tautomers thereof, in each case in free form or in salt form, can be used as agrochemical active ingredients and can be prepared in a manner known per se.

Abstract translation: 其中n和Z如权利要求1所定义的化合物，并且在适当的情况下，其互变异构体在每种情况下以游离形式或盐形式可用作农业化学活性成分，并且可以以本身已知的方式制备 。

公开(公告)号：US5679623A

公开(公告)日：1997-10-21

申请号：US460473

申请日：1995-06-02

Applicant: Henry Szczepanski ,  Haukur Kristinsson

Inventor： Henry Szczepanski ,  Haukur Kristinsson

IPC: A01N43/50 ,  A01N47/16 ,  A01N47/38 ,  C07D233/70 ,  C07D233/88 ,  C07D401/12 ,  C07D403/12 ,  C07D413/12 ,  C07D417/12 ,  C07D213/36 ,  C07D233/36

CPC classification number: C07D401/12 ,  A01N43/50 ,  A01N47/16 ,  A01N47/38 ,  C07D233/70

Abstract: Compounds of the formula ##STR1## in which R.sub.l, R.sub.2, R.sub.3, R.sub.4, Y and Z are as defined in claim 1, and, if appropriate, the tautomers thereof, in each case in free form or in salt form, can be used as agrochemical active ingredients and can be prepared in a manner known per se.

Abstract translation: 其中R 1，R 2，R 3，R 4，Y和Z如权利要求1中所定义的式（Ⅰ）化合物，如果合适，其互变异构体在每种情况下为游离形式或盐形式， 可以用作农药活性成分，并且可以以本身已知的方式制备。

公开(公告)号：US5446154A

公开(公告)日：1995-08-29

申请号：US221303

申请日：1994-03-31

Applicant: Ernst Beriger ,  Haukur Kristinsson

Inventor： Ernst Beriger ,  Haukur Kristinsson

IPC: C07D253/06 ,  C07D271/10 ,  C07D271/113 ,  C07D401/12 ,  C07D413/06

CPC classification number: C07D253/06 ,  C07D271/113 ,  C07D401/12 ,  C07D413/06

Abstract: The invention relates to a process for the preparation of a compound of formula ##STR1## useful as intermediate for the preparation of pesticides, wherein R is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.1 -C.sub.4 alkyl substituted by from 1 to 10 halogen atoms or by from 1 to 3 radicals selected from the group consisting of C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 alkylthio and phenyl, phenyl or phenyl substituted by from 1 to 3 radicals selected from the group consisting of halogen, methyl, ethyl, methoxy, methylthio and nitro, which comprises reacting with hydrazine hydrate a compound of formula ##STR2## wherein R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.1 -C.sub.4 alkyl substituted by from 1 to 9 chlorine atoms, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 alkylthio, C.sub.1 -C.sub.3 alkylsulfonyl, C.sub.1 -C.sub.3 alkylsulfonyl, phenyl, phenyl substituted by from 1 to 3 radicals selected from the group consisting of halogen, methyl, ethyl, methoxy, methylthio and nitro, or pyridyl, and subjecting to hydrolysis the resulting compound of formula ##STR3##

Abstract translation: 本发明涉及制备式（I）化合物的方法，其可用作制备农药的中间体，其中R是氢，C 1 -C 6烷基，C 3 -C 6环烷基，被1至 10个卤素原子或1至3个选自C 1 -C 3烷氧基，C 1 -C 3烷硫基和苯基的基团，苯基或被1至3个选自卤素，甲基，乙基，甲氧基， 甲硫基和硝基，其包括与水合肼反应其中R 1是氢，C 1 -C 4烷基，C 3 -C 6环烷基，被1至9个氯原子取代的C 1 -C 4烷基，C 1 -C 3烷氧基，C 1 C 3烷硫基，C 1 -C 3烷基磺酰基，C 1 -C 3烷基磺酰基，苯基，被1至3个选自卤素，甲基，乙基，甲氧基，甲硫基和硝基或吡啶基的基取代的苯基，并将所得化合物 公式（III）

公开(公告)号：US5179094A

公开(公告)日：1993-01-12

申请号：US672763

申请日：1991-03-19

Applicant: Odd Kristiansen ,  Manfred Boger ,  Haukur Kristinsson ,  Peter Maienfisch

Inventor： Odd Kristiansen ,  Manfred Boger ,  Haukur Kristinsson ,  Peter Maienfisch

IPC: A01N43/707 ,  C07D401/12

CPC classification number: C07D401/12 ,  A01N43/707

Abstract: There are disclosed novel substituted N-amino-1,2,4-triazinones of formula I ##STR1## wherein R.sub.1 is C.sub.1 -C.sub.12 alkyl or C.sub.3 -C.sub.7 cycloalkyl,R.sub.2 and R.sub.3 are each independently of the other hydrogen or C.sub.1 -C.sub.6 alkyl,R.sub.4, R.sub.5, R.sub.6 and R.sub.7 are each independently of one another hydrogen, halogen, C.sub.1 -C.sub.3 alkyl, ##STR2## C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 alkylthio, and n is 0 or 1, or a salt thereof, with the proviso that n is 1, if simultaneously the pyridine ring is attached via the 3-position to the methylidene group and R.sub.4, R.sub.5, R.sub.6 and R.sub.7 are each hydrogen; their use in pest control and pesticidal compositions which contain a compound of formula I as active component. The preferred utility is the control of pests of animals and plants.

Abstract translation: 公开了式I（I）的新的取代的N-氨基-1,2,4-三嗪酮，其中R 1是C 1 -C 12烷基或C 3 -C 7环烷基，R 2和R 3各自独立地是另一个氢或C 1 -C 6烷基 ，R 4，R 5，R 6和R 7各自独立地为氢，卤素，C 1 -C 3烷基，C 1 -C 3烷氧基或C 1 -C 3烷硫基，n为0或1，或其盐，条件是n 是1，如果同时吡啶环通过3-位连接到亚甲基上，并且R4，R5，R6和R7各自为氢; 它们在害虫控制中的用途和含有式I化合物作为活性成分的杀虫组合物。 优选的效用是控制动物和植物的害虫。