摘要:
An apparatus, software, and method for segregating out background signals from a signal of interest comprising sampling a signal that includes the background signals over one or more periods of time, forming a matrix from results of the sampling, calculating a matrix of basis functions via a singular value decomposition of the matrix from the forming operation, and determining a set of basis functions to employ to segregate out background signals. Also a corresponding wavelength modulation spectroscopy apparatus, software, and method.
摘要:
A spectrometer and spectrometry method comprising modulating a light source with a carrier waveform multiplied by an envelope function, directing light from the light source through a sample region and to a photodetector, and demodulating current from the photodetector at a reference frequency. Also a method for computing a modulation waveform comprising specifying a target detection efficiency in a Fourier space, computing a response of a waveform that comprises a carrier wave multiplied by an envelope function, and modifying the envelope function using nonlinear optimization means to minimize a difference between the computed response and a predetermined target gain spectrum.
摘要:
A spectrographic apparatus and method comprising providing a spectrometer, digitizing a sample spectrum in a spectral range that includes at least one feature of an analyte, and comparing, via a linear least squares computation, the sample spectrum to a spectrum known to closely approximate the sample spectrum at a reference condition and to one or more derivatives of the known spectrum taken with respect to one or more parameters of the reference condition.
摘要:
A magnetometer and concomitant magnetometry method comprising emitting light from a light source, via a pulse generator pulsing light from the light source, directing the pulsed light to an atomic chamber, employing a field sensor in the atomic chamber, and via a signal processing module receiving a signal from the field sensor.
摘要:
An apparatus, software, and method for segregating out background signals from a signal of interest comprising sampling a signal that includes the background signals over one or more periods of time, forming a matrix from results of the sampling, calculating a matrix of basis functions via a singular value decomposition of the matrix from the forming operation, and determining a set of basis functions to employ to segregate out background signals. Also a corresponding wavelength modulation spectroscopy apparatus, software, and method.
摘要:
A tone burst spectrometer and spectrometry method comprising employing a narrow bandwidth light source, a tone burst modulation waveform generator, synchronization of a lock-in amplifier to a burst frequency of the generator, and one or more of the following: use of a semiconductor laser; setting the tone frequency of the generator to an integer multiple of the burst frequency; using a tone modulation waveform other than a sine wave; setting the tone frequency of the generator to less than a half width at half maximum of a targeted spectral transition; and producing a spectral feature with a high signal to noise ratio while synchronizing the lock-in amplifier to the tone frequency of the generator or an odd harmonic of the tone frequency and wherein the output of the lock-in amplifier is low pass filtered and negative feedback is employed to stabilize the operating wavelength at or near a center wavelength of a spectral feature of the sample.
摘要:
A spectrometer and spectrometry method comprising modulating a light source with a carrier waveform multiplied by an envelope function, directing light from the light source through a sample region and to a photodetector, and demodulating current from the photodetector at a reference frequency. Also a method for computing a modulation waveform comprising specifying a target detection efficiency in a Fourier space, computing a response of a waveform that comprises a carrier wave multiplied by an envelope function, and modifying the envelope function using nonlinear optimization means to minimize a difference between the computed response and a predetermined target detection efficiency.
摘要:
A process for improving moisture analyzers or hygrometers that use optical absorption techniques to measure water vapor. Water vapor in the optical path outside the sample region is treated to exchange the hydrogen atoms for deuterium, so that the adsorbed water vapor is converted to heavy water, D.sub.2 O, and isotopically mixed HDO, thus reducing or eliminating the interference in any optical absorption apparatus for measuring water vapor, provided the spectral resolution is sufficient to resolve normal water absorptions from heavy water absorptions.