公开(公告)号：US20050158000A1

公开(公告)日：2005-07-21

申请号：US10662516

申请日：2003-09-16

申请人： David Szum ,  Chander Chawla ,  James Petisce ,  John Vandeberg ,  George Pasternack ,  Timothy Bishop ,  Paul Snowwhite ,  Edward Zahora ,  Stephen Lapin

发明人： David Szum ,  Chander Chawla ,  James Petisce ,  John Vandeberg ,  George Pasternack ,  Timothy Bishop ,  Paul Snowwhite ,  Edward Zahora ,  Stephen Lapin

IPC分类号： G02B6/44 ,  C03C25/10 ,  C03C25/24 ,  C08F2/46 ,  C08F2/48 ,  C08F2/50 ,  G02B6/22

CPC分类号： C03C25/1065

摘要： Optical fiber coatings are disclosed having excellent ribbon stripping and adhesion behavior. The coatings are radiation-curable. The excellent stripping and adhesion behavior can be achieved by several means which include by use of additives, by use of radiation-curable oligomers having higher molecular weight, or by use of coatings having certain thermal properties. Combination of means can be employed. Stripping behavior can be measured by crack propagation and fiber friction measurements.

摘要翻译： 公开了具有优异的带剥离和粘合行为的光纤涂层。 涂层是可辐射固化的。 通过使用添加剂，通过使用具有较高分子量的可辐射固化的低聚物，或通过使用具有某些热性质的涂层，可以通过几种方式实现优异的剥离和粘合行为。 可以组合手段。 剥离行为可以通过裂纹扩展和纤维摩擦测量来测量。

公开(公告)号：US20060024010A1

公开(公告)日：2006-02-02

申请号：US11240397

申请日：2005-10-03

申请人： Jan van Eekelen ,  Joanna Nagelvoort ,  Duurt Alkema ,  Paul Buijsen ,  Huimin Cao ,  Robert Johnson ,  David Szum

发明人： Jan van Eekelen ,  Joanna Nagelvoort ,  Duurt Alkema ,  Paul Buijsen ,  Huimin Cao ,  Robert Johnson ,  David Szum

IPC分类号： G02B6/02 ,  G02B6/00 ,  G02B6/036

CPC分类号： C09J175/16 ,  C03C25/1065 ,  C08G18/4854 ,  C08G18/672 ,  C09D175/16 ,  G02B6/02395 ,  Y10S525/932 ,  C08G18/40 ,  C08G18/48

摘要： A coated optical fiber can have a primary coating and a secondary coating, where the primary coating can have good microbending resistance and is obtained by curing a composition having a high cure speed. In one example, a coated optical fiber can include as optical fiber, a primary coating and a secondary coating. The optical fiber can have an attenuation increase of less than 0.650 dB/km at 1550 nm, with the primary coating having a modulus retention ratio of at least 0.5, a glass transition temperature of −35° C., and where the primary coating is obtained by curing a primary coating composition having a cure dose to attain 95% of the maximum attainable modulus of less than 0.65 J/cm2.

摘要翻译： 涂覆光纤可以具有初级涂层和二次涂层，其中初级涂层可以具有良好的抗微弯曲性，并且通过固化具有高固化速度的组合物获得。 在一个示例中，涂覆的光纤可以包括作为光纤，初级涂层和二次涂层。 光纤可以在1550nm处具有小于0.650dB / km的衰减增加，其中初级涂层的模量保持率至少为0.5，玻璃化转变温度为-35℃，其中初级涂层为 其通过固化具有固化剂量的初级涂料组合物获得小于0.65J / cm 2的最大可获得模量的95％。

公开(公告)号：US06240230B1

公开(公告)日：2001-05-29

申请号：US08812569

申请日：1997-03-06

申请人： David Szum

发明人： David Szum

IPC分类号： C08L7508

CPC分类号： C03C25/106 ,  C03C25/1065 ,  Y10T428/2938

摘要： Radiation-curable compositions are disclosed which, after cure, are substantially non-yellowing. The compositions are particularly tailored for coating and bundling of optical fibers. A first preferred composition is based on a polyether-type of oligomer diluted with reactive diluents. Isocyanurate structures are included in the composition to raise Tg. A second preferred composition is based on fatty oil comprising (meth)acrylate groups and bisphenol A derivatives comprising (meth)acrylate groups. Photoinitiators can be included to increase cure speed. The formulations do not include material amounts of ingredients which tend to cause yellowing or, in theory, extended conjugation in the cured compositions.

摘要翻译： 公开了可固化的组合物，其在固化后基本上不变黄。 该组合物特别适用于光纤的涂布和捆扎。 第一优选的组合物是基于用活性稀释剂稀释的聚醚型低聚物。 组合物中包含异氰酸酯结构以提高Tg。 第二优选组合物是基于包含（甲基）丙烯酸酯基团的脂肪油和包含（甲基）丙烯酸酯基团的双酚A衍生物。 可以加入光引发剂以提高固化速度。 制剂不包括倾向于引起变黄的成分的物质量，或理论上在固化的组合物中延长的缀合。

公开(公告)号：US20060076534A1

公开(公告)日：2006-04-13

申请号：US11284306

申请日：2005-11-21

申请人： David Szum ,  Robert Johnson

发明人： David Szum ,  Robert Johnson

IPC分类号： C09K3/00

CPC分类号： C08F290/141 ,  C03C25/1065 ,  C08F222/1006 ,  C08F290/06 ,  C08F290/061 ,  C08F290/14 ,  C08F2222/1086 ,  C09D4/00 ,  C08F220/00 ,  C08F2220/302 ,  C08F2220/1891 ,  C08F2222/102 ,  C08F226/06 ,  C08F2222/1013 ,  C08F2222/1026

摘要： Inner and outer primary and matrix material compositions which, after curing, exhibit a high degree of uniformity after curing even when the coating is applied onto optical fibers at relatively high shear rates, e.g., such as those experienced at high optical fiber coating line speeds. These compositions are provided in significant part by the selective incorporation of at least one radiation-curable oligomer into the compositions. In particular, and with respect to inner primary coatings, the oligomer should be selected so that the value m of an uncured radiation-curable inner primary coating composition in the equation τ = K ⁢   ⁢ λ ⁢   ⁢ γ 1 + ( λ ⁢   ⁢ γ ) m ( I ) is advantageously equal to or greater than about 0.90.

摘要翻译： 固化后的固化后的内外原料和基体材料组合物即使在以较高的剪切速率将涂料施加到光纤上（例如在高光纤涂布线速度下经历的那些）下也能在固化后表现出高度的均匀性。 这些组合物在很大程度上通过将至少一种可辐射固化的低聚物选择性掺入组合物来提供。 特别地，对于内部主要涂层，应该选择低聚物，使得在等式