公开(公告)号：US20100249321A1

公开(公告)日：2010-09-30

申请号：US12801447

申请日：2010-06-09

Applicant: Richard J. Harrison ,  Bruce C. Gilbert ,  Andrew F. Parsons ,  Derek J. Irvine

Inventor： Richard J. Harrison ,  Bruce C. Gilbert ,  Andrew F. Parsons ,  Derek J. Irvine

IPC: C08F251/00 ,  C08F14/00 ,  C08F24/00 ,  C08F26/06 ,  C08F26/10 ,  C08L75/00

CPC classification number: C08F4/50

Abstract: Ethylenically unsaturated, particularly acrylic, monomers are polymerised using a catalyst system including a manganese carbonyl initiator, an organic halogen reactive substrate and an allylic halide chain termination agent. Desirably the manganese carbonyl initiator is a dimanganese compound, particularly dimanganese decacarbonyl (Mn2(CO)10). The catalysis mechanism appears to involve initiator homolysis, abstraction of halogen from the reactive substrate forming an organic free radical which acts as a chain initiator for polymerisation and eventual reaction of the propagating chain radical with the chain terminating agent. The speed or extent of reaction may be modified by the inclusion of Lewis acids in the reaction mixture. The resulting polymers are telechelic and may have different end groups. The polymers can be reacted further to functionalise them and/or to form block copolymers.

Abstract translation: 使用包括羰基羰基引发剂，有机卤素反应性底物和烯丙基卤化物链终止剂的催化剂体系来聚合乙烯基不饱和的，特别是丙烯酸的单体。 期望的羰基羰基引发剂是二甘氨酸化合物，特别是二甘氨酸的十羧基（Mn 2（CO）10））。 催化机理似乎涉及引发剂均聚，从反应性底物中提取卤素，形成有机自由基，其起到用于聚合的链引发剂和增链链基团与链终止剂的最终反应。 可以通过在反应混合物中加入路易斯酸来改变反应的速度或程度。 所得聚合物是遥爪的并且可以具有不同的端基。 聚合物可进一步反应以使其功能化和/或形成嵌段共聚物。

公开(公告)号：US20080221002A1

公开(公告)日：2008-09-11

申请号：US11791077

申请日：2005-11-07

Applicant: Andrew S Oldfield ,  Derek J. Irvine

Inventor： Andrew S Oldfield ,  Derek J. Irvine

IPC: C10M129/95 ,  C10M133/54 ,  C10M129/00 ,  C10M129/02

CPC classification number: C10M129/93 ,  C08G63/06 ,  C08G63/6852 ,  C10L1/238 ,  C10L10/06 ,  C10L10/08 ,  C10L10/18 ,  C10M129/90 ,  C10M133/54 ,  C10M141/02 ,  C10M141/06 ,  C10M161/00 ,  C10M2207/283 ,  C10M2207/286 ,  C10M2207/289 ,  C10M2207/30 ,  C10M2209/102 ,  C10M2209/108 ,  C10M2209/11 ,  C10M2211/022 ,  C10M2215/08 ,  C10M2215/082 ,  C10M2215/086 ,  C10M2215/12 ,  C10M2215/28 ,  C10M2217/044 ,  C10M2217/06 ,  C10N2230/02 ,  C10N2230/04 ,  C10N2230/06 ,  C10N2230/36 ,  C10N2240/10 ,  C10N2260/09

Abstract: A novel ashless polymeric dispersant is claimed which is suitable for use in an automotive lubricant composition. The ashless polymeric dispersant has a number average molecular weight of between 200 and 15,000 and derived from the reaction of a polar head group, which comprises a polar moiety having more than one amine, alcohol, acid or halogen functionality with two or more polar tail groups where each polar tail group comprises a polymeric backbone of 2 to 30 monomeric repeat units, each repeat unit comprising a hydrocarbon chain functionalised by the presence of at least one electronegative element or moiety. The dispersant has good dispersancy properties, when used as a sole dispersant or in combination with other dispersants. It provides enhanced seal resistance and has good oxidative stability in automotive applications as compared to current commercial products. Furthermore the low temperature viscosity of an automotive lubricant composition containing the dispersant is superior to that of a composition with current commercial dispersants.

Abstract translation: 要求一种适用于汽车润滑剂组合物的新型无灰聚合物分散剂。 无灰聚合物分散剂的数均分子量为200至15,000，衍生自极性基团的反应，极性基团包含具有多于一个胺的极性部分，醇，酸或卤素官能团与两个或多个极性尾基 其中每个极性尾组包含2至30个单体重复单元的聚合物主链，每个重复单元包含通过存在至少一个电负性元素或部分官能化的烃链。 当用作单独的分散剂或与其它分散剂组合时，分散剂具有良好的分散性。 与目前的商业产品相比，它在汽车应用中提供了更强的密封性，并且具有良好的氧化稳定性。 此外，含有分散剂的汽车润滑剂组合物的低温粘度优于目前商用分散剂的组合物的低温粘度。

公开(公告)号：US07759443B2

公开(公告)日：2010-07-20

申请号：US10549856

申请日：2004-03-24

Applicant: Richard J Harrison ,  Bruce C Gilbert ,  Andrew F Parsons ,  Derek J Irvine

Inventor： Richard J Harrison ,  Bruce C Gilbert ,  Andrew F Parsons ,  Derek J Irvine

IPC: C08F20/06 ,  B01J31/20

CPC classification number: C08F4/50

Abstract: Ethylenically unsaturated, particularly acrylic, monomers are polymerized using a catalyst system including a manganese carbonyl initiator, an organic halogen reactive substrate and an allylic halide chain termination agent. Desirably the manganese carbonyl initiator is a dimanganese compound, particularly dimanganese decacarbonyl (Mn2(CO)10). The catalysis mechanism appears to involve initiator homolysis, abstraction of halogen from the reactive substrate forming an organic free radical which acts as a chain initiator for polymerization and eventual reaction of the propagating chain radical with the chain terminating agent. The speed or extent of reaction may be modified by the inclusion of Lewis acids in the reaction mixture. The resulting polymers are telechelic and may have different end groups. The polymers can be reacted further to functionalize them and/or to form block copolymers.

Abstract translation: 使用包括羰基羰基引发剂，有机卤素反应性底物和烯丙基卤化物链终止剂的催化剂体系，使烯键式不饱和的，特别是丙烯酸的单体聚合。 期望的羰基羰基引发剂是二甘氨酸化合物，特别是二甘氨酸的十羧基（Mn 2（CO）10））。 催化机理似乎涉及引发剂均聚，从反应性底物中提取卤素，形成有机自由基，其作为引发链的引发剂，并且传播链基与链终止剂的最终反应。 可以通过在反应混合物中加入路易斯酸来改变反应的速度或程度。 所得聚合物是遥爪的并且可以具有不同的端基。 聚合物可进一步反应以使其官能化和/或形成嵌段共聚物。

公开(公告)号：US20080214726A1

公开(公告)日：2008-09-04

申请号：US11667495

申请日：2005-11-02

Applicant: David J. Freeman ,  Derek J. Irvine ,  Jane Kitching ,  Stephen C. Rogers

Inventor： David J. Freeman ,  Derek J. Irvine ,  Jane Kitching ,  Stephen C. Rogers

IPC: C08F220/60 ,  C08F226/06

CPC classification number: C09K8/52 ,  C08F220/34 ,  C08F220/60 ,  C09K2208/22 ,  C10L3/00

Abstract: Copolymers, desirably having a molecular weight of from 500 to 20000, of aminoesters or aminoamides of (meth)acrylic acid and (meth)acrylamides at a molar ratio of from 10:1 to 60:1, particularly from 12:1 to 50:1 and especially about 20:1, can act as gas hydrate inhibitors in water containing hydrocarbon gas streams. Desirably the aminoesters or aminoamides are N-alkyl-amino(esters or amides) in particular of the formula (I): H2C═CR1 C(O)XR2NR3R4 (I) where R1, R2, R3, R4 and X have defined meanings and the (meth)acrylamides are of the formula (II): H2C═CR6C(O)NR7R8 (II) where R6, R7 and R8 have defined meanings. Methods of treating gas water mixtures using the copolymers to inhibit gas hydrate formation are described.

Abstract translation: 摩尔比为10：1至60：1，特别是12：1至50：1的（甲基）丙烯酸和（甲基）丙烯酰胺的分子量为500至20000的氨基酯或氨基酰胺的共聚物， 1，特别是约20：1，可以在含烃气流的水中充当气体水合物抑制剂。 理想地，氨基酯或氨基酰胺特别是式（I）的N-烷基 - 氨基（酯或酰胺）：H 2 C-CR 1 C（O）XR 其中R 1，R 2，R 2，R 2，R 3，R 4， R 3，R 4和X具有定义的含义，（甲基）丙烯酰胺具有式（II）：H 2 C-CR C（O）NR 7 R 8（II）其中R 6，R 7， / SUP>和R 8具有定义的含义。 描述了使用共聚物处理气体水混合物以抑制气体水合物形成的方法。