摘要:
The present invention provides a method and apparatus for separating unreacted monomer from a polymerization process effluent stream, wherein the effluent stream comprises unreacted monomer and polymer particles. The method comprises passing the effluent stream of a fluidized-bed reactor into at least one container, feeding a high-pressure olefin through an ejector, and vacuuming at least a portion of the effluent stream from the at least one container through the ejector. The apparatus comprises a fluidized-bed reactor having a first conduit connected to a first tank, an ejector having a second conduit connected to the first tank, and a third conduit connected to the fluidized-bed reactor.
摘要:
The present invention relates to a continuous gas phase process comprising passing a recycle stream through a fluidized bed in a gas phase fluidized bed reactor, wherein the recycle stream comprises a low molecular weight dew point increasing component and a high molecular weight component, polymerizing an alpha-olefin monomer in the presence of a catalyst, and controlling an amount of the low molecular weight dew point increasing component in the recycle stream such that a dew point approach temperature of the recycle stream is less than the dew point approach temperature when operating with the higher molecular weight dew point increasing component alone.
摘要:
The present invention provides a method and apparatus for separating unreacted monomer from a polymerization process effluent stream, wherein the effluent stream comprises unreacted monomer and polymer particles. The method comprises passing the effluent stream of a fluidized-bed reactor into at least one container, feeding a high-pressure olefin through an ejector, and vacuuming at least a portion of the effluent stream from the at least one container through the ejector. The apparatus comprises a fluidized-bed reactor having a first conduit connected to a first tank, an ejector having a second conduit connected to the first tank, and a third conduit connected to the fluidized-bed reactor.
摘要:
A continuous gas fluidized bed polymerization process for the production of a polymer from a monomer including continuously passing a gaseous stream comprising the monomer through a fluidized bed reactor in the presence of a catalyst under reactive conditions; withdrawing a polymeric product and a stream comprising unreacted monomer gases; cooling said stream comprising unreacted monomer gases to form a mixture comprising a gas phase and a liquid phase and reintroducing said mixture into said reactor with sufficient additional monomer to replace that monomer polymerized and withdrawn as the product, wherein said liquid phase is vaporized, and wherein the stream comprises at least two inert condensing agents selected from the group consisting of alkanes, cycloalkanes, and mixtures thereof, each of the inert condensing agents having a normal boiling point less than 40° C.
摘要:
The present invention relates to a continuous gas phase process comprising passing a recycle stream through a fluidized bed in a gas phase fluidized bed reactor, wherein the recycle stream comprises a low molecular weight dew point increasing component and a high molecular weight component, polymerizing an alpha-olefin monomer in the presence of a catalyst, and controlling an amount of the low molecular weight dew point increasing component in the recycle stream such that a dew point approach temperature of the recycle stream is less than the dew point approach temperature when operating with the higher molecular weight dew point increasing component alone.