摘要:
The present invention relates to a continuous gas phase process comprising passing a recycle stream through a fluidized bed in a gas phase fluidized bed reactor, wherein the recycle stream comprises a low molecular weight dew point increasing component and a high molecular weight component, polymerizing an alpha-olefin monomer in the presence of a catalyst, and controlling an amount of the low molecular weight dew point increasing component in the recycle stream such that a dew point approach temperature of the recycle stream is less than the dew point approach temperature when operating with the higher molecular weight dew point increasing component alone.
摘要:
The present invention relates to a continuous gas phase process comprising polymerizing one or more hydrocarbon monomer(s) in a fluidized bed reactor in the presence of catalyst system or polymerization catalyst and a condensable fluid for a period of at least 12 hours where the bed temperature is less than the Critical Temperature and the dew point temperature of the gas composition in the reactor is within 25° C. of the bed temperature.
摘要:
The present invention relates to a continuous gas phase process comprising polymerizing one or more hydrocarbon monomer(s) in a fluidized bed reactor in the presence of catalyst system or polymerization catalyst and a condensable fluid for a period of at least 12 hours where the bed temperature is less than the Critical Temperature and the dew point temperature of the gas composition in the reactor is within 25° C. of the bed temperature.
摘要:
The present invention relates to a continuous gas phase process comprising polymerizing one or more hydrocarbon monomer(s) in a fluidized bed reactor in the presence of a Ziegler-Natta-type catalyst system and a condensable fluid for a period of at least 12 hours where the bed temperature is less than the Critical Temperature and the dew point temperature of the gas composition in the reactor is within 25° C. of the bed temperature.
摘要:
Methods for shutting down and restarting polymerization in a gas phase polymerization reactor are provided. The method can include introducing a polymerization neutralizer to the reactor in an amount sufficient to stop polymerization therein. The method can also include stopping recovery of a polymer product from the reactor and stopping introduction of a catalyst feed and a reactor feed to the reactor. The method can also include adjusting a pressure within the reactor from an operating pressure to an idling pressure. The method can also include adjusting a superficial velocity of a cycle fluid through the reactor from an operating superficial velocity to an idling superficial velocity. The method can also include maintaining the reactor in an idled state for a period of time.
摘要:
Generally, a method of monitoring a polymerization reaction in a fluid bed reactor to generate, in on-line fashion, data indicative of the imminent occurrence of a discontinuity event (for example, sheeting) and optionally also control the reaction to prevent the occurrence of the discontinuity event is provided. Typical embodiments include the steps of generating in on-line fashion at least one of bed static data indicative of static charge in the fluidized bed and carryover static data indicative of carryover static; and generating at least one of temperature data (in on-line fashion using at least one monitored reaction parameter) indicative of a first temperature and acoustic emission data indicative of resin stickiness in the reactor, where the first temperature is indicative of at least one of degree of resin stickiness in the reactor and a characteristic of melting behavior of polymer resin in the reactor in the presence of at least one diluent.
摘要:
Systems and methods for monitoring a polymerization reactor are provided. The method can include estimating an acoustic condition of a polymer produced in a reactor. The method can also include estimating a stickiness control parameter of the polymer produced in the reactor. The method can further include pairing the acoustic condition with the stickiness control parameter to provide a paired acoustic condition and stickiness control parameter.
摘要:
A method for cleaning a distributor plate in a fluidized bed polymerization reactor system according to one embodiment includes, in a first mode, operating with about a normal, baseline value of superficial gas velocity in a fluidized bed polymerization reactor system having a reactor vessel, a recycle line, and a distributor plate in the reactor vessel near an inlet of the reactor vessel. In a second mode, the superficial gas velocity is increased above the baseline value of the first mode to a level sufficient to raise the temperature of the cycle gas at the inlet above an average temperature of the cycle gas at the inlet in the first mode, and to a level sufficient to dislodge foulant from holes in the distributor plate.
摘要:
Methods for shutting down and restarting polymerization in a gas phase polymerization reactor are provided. The method can include introducing a polymerization neutralizer to the reactor in an amount sufficient to stop polymerization therein. The method can also include stopping recovery of a polymer product from the reactor and stopping introduction of a catalyst feed and a reactor feed to the reactor. The method can also include adjusting a pressure within the reactor from an operating pressure to an idling pressure. The method can also include adjusting a superficial velocity of a cycle fluid through the reactor from an operating superficial velocity to an idling superficial velocity. The method can also include maintaining the reactor in an idled state for a period of time.
摘要:
A method for preparing a reactor for performance of a polymerization reaction, the method including providing at least one seed bed into the reactor; wherein the at least one seed bed includes at least one organometallic compound and polymer particles.