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公开(公告)号:US12211998B2
公开(公告)日:2025-01-28
申请号:US17947771
申请日:2022-09-19
Applicant: Enevate Corporation
Inventor: Sanjaya Perera , Liwen Ji , Jeremy Chang , Benjamin Yong Park
IPC: H01M4/525 , H01M4/131 , H01M4/134 , H01M4/38 , H01M4/46 , H01M4/62 , H01M10/052 , H01M10/0525 , H01M10/054 , H01M4/02 , H01M10/058
Abstract: Systems and methods for aromatic macrocyclic compounds (Phthalocyanines) as cathode additives for inhibition of transition metal dissolution and stable solid electrolyte interphase formation may include an anode, an electrolyte, and a cathode, where the cathode comprises an active material and a phthalocyanine additive, the additive being coordinated with different metal cationic center and functional groups. The active material may comprise one or more of: nickel cobalt aluminum oxide, nickel cobalt manganese oxide, lithium iron phosphate, lithium cobalt oxide, and lithium manganese oxide, Ni-rich layered oxides LiNi1-xMxO2 where M=Co, Mn, or Al, Li-rich xLi2MnO3(1-x)LiNiaCobMncO2, Li-rich layered oxides LiNi1+xM1−xO2 where M=Co, Mn, or Ni, and spinel oxides LiNi0.5Mn1.5O4. The phthalocyanine additive may include one or more of: cobalt hexadecafluoro phthalocyanine (Co-Pc-F), dilithium phthalocyanine (Li-Pc), cobalt(II) phthalocyanine, nickel(II) phthalocyanine-tetrasulfonic acid tetrasodium salt, titanium(IV) phthalocyanine dichloride, manganese(II) phthalocyanine, zinc phthalocyanine, aluminum phthalocyanine chloride, Iron(II) phthalocyanine, and silicon phthalocyanine dichloride.
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公开(公告)号:US20250023015A1
公开(公告)日:2025-01-16
申请号:US18772771
申请日:2024-07-15
Applicant: Enevate Corporation
Inventor: Giulia Canton , Benjamin Park , Fred Bonhomme , David J. Lee , Ian Browne
IPC: H01M4/134 , H01M4/04 , H01M4/1395 , H01M4/66 , H01M4/74 , H01M10/0525
Abstract: Systems and methods are provided for managing anisotropic expansion of silicon-dominant anodes. An example battery may include a cathode, an electrolyte, and an anode, with the anode including a current collector and an active material on a surface of the current collector. One or more characteristics of the current collector may ensure meeting particular expansion criteria. The expansion criteria may include expanding less in one of x-y directions and z-direction while expanding more in other one of the x-y directions and the z-direction, the x-y directions being parallel to the surface of the current collector and perpendicular to a thickness of the active material. The one or more characteristics include at least material of the current collector.
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公开(公告)号:US20250006892A1
公开(公告)日:2025-01-02
申请号:US18760907
申请日:2024-07-01
Applicant: Enevate Corporation
Inventor: Benjamin Yong Park , Jill R. Pestana , Heidi Leighette Anderson , Sung Won Choi
IPC: H01M4/1395 , H01M4/04 , H01M4/134 , H01M4/36 , H01M10/0525
Abstract: Methods of forming electrochemical cells are described. An electrochemical cell may be provided, with the electrochemical cell including a first electrode and a second electrode, wherein at least the first electrode includes up to about 99% by weight of silicon, a separator between the first electrode and the second electrode, and an electrolyte in contact with the first electrode, the second electrode, and the separator. During a formation process, a formation charge current may be at a first rate of constant current and at a second rate of constant current to the electrochemical cell. The first rate is less than the second rate. The providing may include providing the formation charge current at the first rate of constant current until a rate switching condition is met; and providing the formation charge current at the second rate of constant current after the rate switching condition is met.
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公开(公告)号:US12183918B2
公开(公告)日:2024-12-31
申请号:US16584574
申请日:2019-09-26
Applicant: Enevate Corporation
Inventor: Benjamin Park , Ian Browne , Sung Won Choi , Fred Bonhomme
Abstract: Systems and methods for silicon dominant lithium-ion cells with controlled lithiation of silicon may include a cathode, an electrolyte, and an anode. The anode may include silicon lithiated at a level after discharge that is configured to be above a minimum threshold level, where the minimum threshold lithiation is 3% silicon lithiation. The lithiation level of the silicon after charging the battery may range between 30% and 95% silicon lithiation, between 30% and 75% silicon lithiation, between 30% and 65% silicon lithiation, or between 30% and 50% silicon lithiation. The lithiation level of the silicon after discharging the battery may range between 3% and 50% silicon lithiation, between 3% and 30% silicon lithiation, or between 3% and 10% silicon lithiation. The minimum threshold level may be a lithiation level below which a cycle life of the battery degrades. The electrolyte may include a liquid, solid, or gel.
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公开(公告)号:US20240429448A1
公开(公告)日:2024-12-26
申请号:US18744072
申请日:2024-06-14
Applicant: Enevate Corporation
Inventor: Liwen Ji , Benjamin Yong Park , Ian Browne , Tracy Ho , Sung Won Choi
IPC: H01M10/0567 , H01G11/30 , H01G11/32 , H01G11/58 , H01G11/64 , H01M4/134 , H01M4/36 , H01M4/38 , H01M4/587 , H01M4/62 , H01M10/0525
Abstract: Electrolytes and electrolyte additives for energy storage devices comprising a carboxylic ether, a carboxylic acid based salt, or an acrylate electrolyte are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte, and at least one electrolyte additive selected from carboxylic ethers, carboxylic acid based salts, and acrylates.
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公开(公告)号:US20240339661A1
公开(公告)日:2024-10-10
申请号:US18615829
申请日:2024-03-25
Applicant: Enevate Corporation
Inventor: Liwen Ji , Benjamin Park
IPC: H01M10/0567 , C07C317/28 , H01M4/38 , H01M10/0525 , H01M10/0569
CPC classification number: H01M10/0567 , C07C317/28 , H01M4/386 , H01M10/0525 , H01M10/0569 , H01M2300/0028
Abstract: Electrode or electrolyte additives for energy storage devices comprising symmetrical or asymmetrical alkylsulfonyl imide or cyclic alkylene sulfonylimide salts are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, and an electrolyte composition. Symmetrical or asymmetrical alkylsulfonyl imide or cyclic alkylene sulfonylimide salts may serve as additives to the electrodes or to the electrolyte composition, or both.
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公开(公告)号:US12113200B2
公开(公告)日:2024-10-08
申请号:US17332689
申请日:2021-05-27
Applicant: Enevate Corporation
Inventor: Younes Ansari , Liwen Ji , Benjamin Park
IPC: H01M4/133 , H01M4/02 , H01M4/04 , H01M4/134 , H01M10/0525
CPC classification number: H01M4/133 , H01M4/0404 , H01M4/0471 , H01M4/134 , H01M10/0525 , H01M2004/027
Abstract: Systems and methods for water soluble weak acidic resins as carbon precursors for silicon-dominant anodes may include an electrode coating layer on a current collector, where the electrode coating layer is formed from silicon and a primary resin carbon precursor; wherein the primary resin carbon precursor comprises a water-soluble acidic polyamide imide functionalized with acidic groups and one or more polymeric stabilizing additives. The electrode coating layer may also include a base and/or a surfactant. The electrode coating layer may be more than 70% silicon.
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公开(公告)号:US20240274886A1
公开(公告)日:2024-08-15
申请号:US18102621
申请日:2023-01-27
Applicant: Enevate Corporation
Inventor: Daniel Sylvinson Muthiah Ravinson , Vincent Giordani , Heidi Anderson , Benjamin Yong Park
IPC: H01M10/0569
CPC classification number: H01M10/0569 , H01M2300/0037
Abstract: New electrolyte compositions for lithium-ion energy storage devices with silicon-based electrode materials having improved stability. The electrolyte compositions may be used in an energy storage device comprising a first electrode and a second electrode, where at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, and the electrolyte composition.
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公开(公告)号:US20240204169A1
公开(公告)日:2024-06-20
申请号:US18441445
申请日:2024-02-14
Applicant: ENEVATE CORPORATION
Inventor: Fred Bonhomme , Benjamin Park , Todd Tatar , Ian Browne
IPC: H01M4/1393 , H01M4/133 , H01M10/0525
CPC classification number: H01M4/1393 , H01M4/133 , H01M10/0525
Abstract: Systems and methods are provided for control of thermal transfer during electrode pyrolysis based processing. An apparatus for processing battery electrodes may include a core configured for use in forming an electrode roll and a thermal rod. The core is configured to engage a sheet including electrode material applied on a current collector, specifically by rolling the sheet on the core to create concentric alternating layers of electrode material and current collector around an internal space formed by the core. The thermal rod is configured for engaging the electrode roll via the internal space of the core such that, once engaged, at least a portion of the thermal rod is disposed within the concentric alternating layers of electrode material and current collector. The thermal rod is configured to provide thermal transfer into the electrode roll via the core during processing of the electrode roll, with the processing including applying pyrolysis.
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公开(公告)号:US11978894B2
公开(公告)日:2024-05-07
申请号:US17398786
申请日:2021-08-10
Applicant: Enevate Corporation
Inventor: Liwen Ji , Younes Ansari , Sanjaya D. Perera , Benjamin Park
IPC: H01M4/36 , H01M4/04 , H01M4/38 , H01M4/62 , H01M10/0525
CPC classification number: H01M4/386 , H01M4/0404 , H01M4/622 , H01M10/0525
Abstract: Systems and methods for batteries comprising a cathode, an electrolyte, and an anode, wherein the anode is a Si-dominant anode that utilizes water-soluble maleic anhydride- and/or maleic acid-containing polymers/co-polymers, derivatives, and/or combinations (with or without additives) as binders.
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