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    Polymerization Catalyst Comprising Amidine Ligand
    1.
    发明申请
    Polymerization Catalyst Comprising Amidine Ligand 有权
    包含脒配体的聚合催化剂

    公开(公告)号：US20090012246A1

    公开(公告)日：2009-01-08

    申请号：US10592861

    申请日：2005-03-14

    申请人： Edwin Ijpeij ,  Henricus Arts ,  Gerardus van Doremaele ,  Peter Windmuller ,  Francis Van der Burgt ,  Martin Alexander Zuideveld

    发明人： Edwin Ijpeij ,  Henricus Arts ,  Gerardus van Doremaele ,  Peter Windmuller ,  Francis Van der Burgt ,  Martin Alexander Zuideveld

    IPC分类号： B01J31/12 ,  C08F4/76 ,  C07F7/28 ,  C07D209/14 ,  C08F110/02

    CPC分类号： C08F10/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F210/18 ,  C08F236/20 ,  C08F2420/04 ,  C08F4/6592 ,  C08F210/06 ,  C08F2500/25 ,  C08F2500/03 ,  C08F2500/17

    摘要： The invention relates to a process for the preparation of a polymer comprising at least one aliphatic or aromatic hydrocarbyl C2-20 olefin in the presence of an ionic catalyst comprising an organometallic compound and an activator, and optionally a scavenger, characterized in that the organometallic compound is a compound according to formula (1): where: M is a metal of group 3, 4, 5, 6 or 7, or the lanthanide series, and p is the valency of the metal M, A represents a neutral or anionic spectator ligand whose valency v is 0, 1 or 2, and q is an integer denoting the number of spectator ligands A, Z is an optional bridging moiety, n is the integer number of parallel bridging moieties Z, Y is an amidine-containing spectator ligand represented by formula (2): wherein the amidine-containing ligand is covalently bonded to the metal M via the imine nitrogen atom, Sub1 is a substituent, which comprises a group 14 atom through which Sub1 is bonded to the imine carbon atom. Sub2 is a substituent, which comprises a heteroatom of group 15-16, through which Sub2 is bonded to the imine carbon atom, r is an integer >0, L is an optional neutral Lewis basic ligand, j is an integer denoting the number of neutral ligands L, and X is an anionic ligand. The invention further relates to a organometallic compound according to formula (1) and a process for the preparation of this compound as well as to a UHMWPE having a weight average molecular weight of at least 4.000 kg/mol and a molecular weight distribution Mw/Mn of less than 2.6.

    摘要翻译： 本发明涉及在包含有机金属化合物和活化剂的离子催化剂和任选的清除剂的存在下，制备包含至少一种脂族或芳族烃基C 2-20烯烃的聚合物的方法，其特征在于有机金属化合物 是根据式（1）的化合物：其中：M是第3,4,5,6或7族的金属或镧系，p是金属M的化合价，A代表中性或阴离子观察者 配位体的化合价v为0,1或2，q为表示配体A的数的整数，Z为任选的桥连部分，n为平行桥连部分Z的整数，Y为含脒的观察配体 由式（2）表示：其中含脒配体通过亚胺氮原子与金属M共价结合，Sub1为取代基，其包含与亚氨基碳原子键合的14族原子。 Sub2是一个取代基，它包含15-16的杂原子，Sub2与亚氨基碳原子键合，r是大于0的整数，L是任选的中性路易斯碱性配体，j是一个整数， 中性配体L和X是阴离子配体。 本发明还涉及式（1）的有机金属化合物和该化合物的制备方法以及重均分子量至少为4.000kg / mol，分子量分布Mw / Mn的UHMWPE 小于2.6。

    Process For The Preparation Of A Metal-Organic Compound Comprising At Least One Imine Ligand
    2.
    发明申请
    Process For The Preparation Of A Metal-Organic Compound Comprising At Least One Imine Ligand 有权
    制备包含至少一种亚胺配体的金属有机化合物的方法

    公开(公告)号：US20070219376A1

    公开(公告)日：2007-09-20

    申请号：US10567156

    申请日：2004-08-03

    申请人： Edwin Ijpeij ,  Henricus Arts ,  Gerardus Van Doremaele ,  Felix Beijer ,  Francis Van Der Burgt ,  Martin Zuideveld

    发明人： Edwin Ijpeij ,  Henricus Arts ,  Gerardus Van Doremaele ,  Felix Beijer ,  Francis Van Der Burgt ,  Martin Zuideveld

    IPC分类号： C08F4/64 ,  C07F19/00 ,  C07F7/00 ,  C07F7/28 ,  C07F7/30 ,  C07F9/00 ,  C07F9/535

    CPC分类号： C08F10/00 ,  C07F7/00 ,  C07F7/28 ,  C07F7/30 ,  C07F9/00 ,  C07F9/5355 ,  C07F17/00 ,  C07F19/00 ,  C08F4/65908 ,  C08F4/6592 ,  C08F210/06 ,  C08F210/16 ,  C08F2420/04 ,  C08F2500/17

    摘要： The invention relates to a process for the preparation of a metal-organic compound, comprising at least one imine ligand, characterized in that an imine ligand according to formula I or the HA adduct thereof, wherein HA represents an acid, of which H represents its proton and A its conjugate base, is contacted with a metal-organic reagent of formula 2 In the presence of at least 1, respectively at least 2 equivalents of a base, with Y═N—R   as formula 1, wherein Y is selected from a substituted carbon, nitrogen, or phosphorous atom and R represents a substituent, and with MV(L1)k(L2)l(L3)m(L4)nX   as formula 2, wherein: M represents a group 4 or group 5 metal ion V represents the valency of the metal ion, being 3, 4 or 5 L1, L2, L3, and L4 represent a ligand or a group 17 halogen atom on M and may be equal or different X represents a group 17 halogen atom, k, l, m, n=0, 1, 2, 3, 4 with k+l+m+n+1=V. The invention further relates to a process for the preparation of a polyolefin in the presence of the compound prepared according to the process of the invention.

    摘要翻译： 本发明涉及制备包含至少一种亚胺配体的金属 - 有机化合物的方法，其特征在于，式I的亚胺配体或其HA加合物，其中HA代表酸，其中H代表其 质子和A的共轭碱与式2的金属有机试剂接触在至少1个分别至少2当量的碱存在下，其中<？在线公式描述=“在线式 “end =”lead“？> YNR为公式1，<？in-line-formula description =”In-line formula“end =”tail“？>其中Y选自取代的碳，氮或磷原子， R代表一个取代基，并且<？在线公式描述=“在线公式”end =“lead”？> M V（L 1 1） （L 3）（L 3）（L 3）（L 3） 其中：M代表基团4或g，其中：M代表基团4或g 5号金属离子V表示金属离子的化合价，为3,4或5个L 1，L 2，L 3 3和 L 4表示M上的配位体或17族卤素原子，可以相同或不同X表示17位卤原子，k，l，m，n = 0,1,2,3， 4，其中k + 1 + m + n + 1 = V。 本发明还涉及在根据本发明的方法制备的化合物存在下制备聚烯烃的方法。

    Process for the preparation of a metal-organic compound comprising at least one imine ligand
    4.
    发明授权
    Process for the preparation of a metal-organic compound comprising at least one imine ligand 有权
    制备包含至少一种亚胺配体的金属 - 有机化合物的方法

    公开(公告)号：US07737070B2

    公开(公告)日：2010-06-15

    申请号：US10567156

    申请日：2004-08-03

    申请人： Edwin Ijpeij ,  Henricus Arts ,  Gerardus van Doremaele ,  Felix Beijer ,  Francis Van Der Burgt ,  Martin Alexander Zuideveld

    发明人： Edwin Ijpeij ,  Henricus Arts ,  Gerardus van Doremaele ,  Felix Beijer ,  Francis Van Der Burgt ,  Martin Alexander Zuideveld

    IPC分类号： C08F4/44

    CPC分类号： C08F10/00 ,  C07F7/00 ,  C07F7/28 ,  C07F7/30 ,  C07F9/00 ,  C07F9/5355 ,  C07F17/00 ,  C07F19/00 ,  C08F4/65908 ,  C08F4/6592 ,  C08F210/06 ,  C08F210/16 ,  C08F2420/04 ,  C08F2500/17

    摘要： A process for the preparation of a metal-organic compound, comprising at least one imine ligand, characterized in that an imine ligand according to formula (1) or the HA adduct thereof, wherein HA represents an acid, of which H represents its proton and A its conjugate base, is contacted with a metal-organic reagent of formula (2) in the presence of at least 1, respectively at least 2 equivalents of a base, with Y═N—R as formula (1), wherein Y is selected from a substituted carbon, or nitrogen atom and R represents a substituent, and with Mv(L1)k(L2)l(L3)m(L4)nx as formula (2), wherein: M represents a group 4 or group 5 metal ion, V represents the valency of the metal ion, being 3, 4 or 5, L1, L2, L3, and L4 represent a ligand or a group 17 halogen atom on M and may be equal or different, X represents a group 17 halogen atom, k, l, m, n=0, 1, 2, 3, 4 with k+l+m+n+l=V. The invention further relates to a process for the preparation of a polyolefin by making a metal-organic compound according to the process of the invention, wherein the base is an olefin polymerisation compatible base, which metal-organic compound is activated anywhere in, or before a polymerisation reactor.

    摘要翻译： 一种制备包含至少一种亚胺配体的金属 - 有机化合物的方法，其特征在于根据式（1）的亚胺配体或其HA加合物，其中HA代表酸，其中H代表其质子， 将其共轭碱与式（2）的金属有机试剂在至少1份，至少2当量碱的存在下与Y = N-R（式（1））接触，其中Y为 选自取代的碳或氮原子，R表示取代基，Mv（L1）k（L2）l（L3）m（L4）nx为式（2），其中：M表示4族或5族 金属离子，V表示金属离子的化合价，为3,4或5，L1，L2，L3和L4表示M上的配位体或17族卤素原子，可以相同或不同，X表示第17族 卤素原子，k，l，m，n = 0,1,2,3,4，其中k + 1 + m + n + 1 = V。 本发明还涉及通过制备根据本发明方法的金属 - 有机化合物来制备聚烯烃的方法，其中所述碱是烯烃聚合相容性碱，所述金属 - 有机化合物在任何地方或之前被活化 聚合反应器。

    Process for the Preparation of an Metal-Organic Compound Comprising at Least One Imine Ligand
    6.
    发明申请
    Process for the Preparation of an Metal-Organic Compound Comprising at Least One Imine Ligand 有权
    制备包含至少一种亚胺配体的金属有机化合物的方法

    公开(公告)号：US20080027195A1

    公开(公告)日：2008-01-31

    申请号：US10566839

    申请日：2004-08-03

    申请人： Edwin Ijpeij ,  Henricus Arts ,  Gerardus Van Doremaele ,  Felix Beijer ,  Francis Van der Burgt ,  Martin Alexander Zuideveld

    发明人： Edwin Ijpeij ,  Henricus Arts ,  Gerardus Van Doremaele ,  Felix Beijer ,  Francis Van der Burgt ,  Martin Alexander Zuideveld

    IPC分类号： C08F4/72

    CPC分类号： C08F10/00 ,  C07F7/00 ,  C07F7/28 ,  C07F7/30 ,  C07F9/00 ,  C07F9/5355 ,  C07F17/00 ,  C07F19/00 ,  C08F4/65908 ,  C08F4/6592 ,  C08F210/06 ,  C08F210/16 ,  C08F2420/04 ,  C08F2500/17

    摘要： The invention relates to a process for the preparation of a metal-organic compound, comprising at least one phosphinimine ligand, characterized in that the HA adduct of a phosphinimine ligand according to formula (1) is contacted with a metal-organic reagent of formula (2) in the presence of 1, respectively 2 equivalents of a base, wherein HA represents an acid, of which H represents its proton and A its conjugate base, with Y=N−H as formula (1), and Mv(L1)k(L2)l(L3)m(L4)nX as formula (2), and wherein Y is a substituted phosphorous atom, and M represents a group 4 or group 5 metal ion, V represents the valency of the metal ion, being 3, 4 or 5 L1, L2, L3, and L4 represent a ligand or a group 17 halogen atom on M and may be equal or different, k, l, m, n=0, 1, 2, 3, 4 with k+l+m+n+1=V, and X represents a group 17 halogen atom. The invention further relates to a process for the preparation of a polyolefin by making a metal-organic compound according to the process of the invention, wherein the base is an olefin polymerisation compatible base, which metal-organic compound is activated anywhere in, or before a polymerisation reactor.

    摘要翻译： 本发明涉及一种制备金属有机化合物的方法，其包括至少一种膦亚胺配体，其特征在于将式（1）的膦亚胺配体的HA加合物与式（1）的金属有机试剂 2）在1的存在下，分别为2当量的碱，其中HA表示酸，其中H表示其质子，A表示酸，其Y = NH，如式（1）所示，M < （L 1/2）（L 1/2）（L 3）（L 3） 其中Y是取代的磷原子，并且M代表基团（II） 4或5族金属离子，V表示金属离子的化合价，为3或4或5L 1，L 2，L 3 和L 4代表M上的配体或17族卤素原子，并且可以相同或不同，k，l，m，n = 0,1,2,3,4，其中k + 1 + m + n + 1 = V，X表示17族卤素原子。 本发明还涉及通过制备根据本发明方法的金属 - 有机化合物来制备聚烯烃的方法，其中所述碱是烯烃聚合相容性碱，所述金属 - 有机化合物在任何地方或之前被活化 聚合反应器。

    Catalyst compositon for olefin polymerization
    7.
    发明申请
    Catalyst compositon for olefin polymerization 审中-公开
    催化剂组合物用于烯烃聚合

    公开(公告)号：US20060014633A1

    公开(公告)日：2006-01-19

    申请号：US10518935

    申请日：2003-06-26

    申请人： Herwig Schottenberger ,  Adrian Mueller ,  Klaus Wurst ,  Nicolaas Friederichs ,  Bing Wang ,  Edwin Ijpeij

    发明人： Herwig Schottenberger ,  Adrian Mueller ,  Klaus Wurst ,  Nicolaas Friederichs ,  Bing Wang ,  Edwin Ijpeij

    IPC分类号： B01J31/00 ,  C07F5/00 ,  C07F3/06

    CPC分类号： C07F3/003 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  C08F4/65908 ,  C08F4/80 ,  C08F2500/03 ,  C08F2500/01 ,  C08F2500/04 ,  C08F210/06

    摘要： The invention relates to a catalyst composition comprising a salt of a non- or weakly coordinating anion, said non- or weakly coordinating anion comprising at least one metal or metalloid ion M with valency v+, v representing an integer between 1 and 5, and at least one bidentate ligand coordinating to this metal or metalloid ion, and a catalyst that can be activated by said non- or weakly coordinating anion, characterized in that said bidentate ligand is a bidentate monoanionic ligand of formula (I): (R1qA1-X-A2R2r), wherein X represents a bridging moiety; A1 and A2 are each independently chosen from the group comprising N, O, P, S, and C; R1 and R2 are each independently chosen from the group comprising an optionally substituted linear or branched (hetero)alkyl group, an optionally substituted (hetero)aryl group, and a Si containing group; and q and r each independently represent an integer with 0≦q, r≦2.

    摘要翻译： 本发明涉及包含非配位或弱配位阴离子盐的催化剂组合物，所述非配位或弱配位阴离子包含至少一种价态v +的金属或准金属离子M，v表示1和5之间的整数， 与该金属或准金属离子配位的至少一个二齿配位体和可由所述非配位或弱配位阴离子活化的催化剂，其特征在于所述二齿配体是式（I）的二齿单阴离子配位体：（R） 1＆lt; 1＆gt;＆lt; 1＆gt; -XA 2＆lt; 2＆lt; 2＆gt;＆lt; 2＆gt;＆lt; ，其中X表示桥连部分; A 1和A 2各自独立地选自N，O，P，S和C; R 1和R 2各自独立地选自包括任选取代的直链或支链（杂）烷基，任选取代的（杂）芳基和 含硅组; q和r各自独立地表示0 <= q，r <= 2的整数。

    Process for the preparation of a metal-organic compound comprising at least one imine ligand
    8.
    发明授权
    Process for the preparation of a metal-organic compound comprising at least one imine ligand 有权
    制备包含至少一种亚胺配体的金属 - 有机化合物的方法

    公开(公告)号：US07655592B2

    公开(公告)日：2010-02-02

    申请号：US10567098

    申请日：2004-08-03

    申请人： Edwin Ijpeij ,  Henricus Arts ,  Gerardus van Doremaele ,  Felix Beijer ,  Francis Van Der Burgt ,  Martin Alexander Zuideveld

    发明人： Edwin Ijpeij ,  Henricus Arts ,  Gerardus van Doremaele ,  Felix Beijer ,  Francis Van Der Burgt ,  Martin Alexander Zuideveld

    IPC分类号： C08F4/6592 ,  B01J31/12 ,  C07F17/00

    CPC分类号： C08F10/00 ,  C07F7/00 ,  C07F7/28 ,  C07F7/30 ,  C07F9/00 ,  C07F9/5355 ,  C07F17/00 ,  C07F19/00 ,  C08F4/65908 ,  C08F4/6592 ,  C08F210/06 ,  C08F210/16 ,  C08F2420/04 ,  C08F2500/17

    摘要： The invention relates to a process for the preparation of a metal-organic compound, comprising at least one phosphinimine ligand, characterized in that the HA adduct of a phosphinimine ligand according to formula (1) is contacted with a metal-organic reagent of formula (2) in the presence of at least 2 equivalents of a base, wherein HA represents an acid, of which H represents its proton and A its conjugate base, with Y═N—H as formula (1), and Mv(L1)k(L2)1(L3)m(L4)nX as formula (2), and wherein Y is a substituted phosphorous atom, and M represents a group 4 or group 5 metal ion, V represents the valency of the metal ion, being 3, 4 or 5 L1, L2, L3, and L4 represent a ligand or a group 17 halogen atom on M and may be equal or different, k, l, m, n=0, 1, 2, 3, 4 with k+l+m+n+l=V, and X represents a group 17 halogen atom. The invention further relates to a process for the preparation of a polyolefin by making a metal-organic compound according to the process of the invention, wherein the base is an olefin polymerisation compatible base, which metal-organic compound is activated anywhere in, or before a polymerisation reactor.

    摘要翻译： 本发明涉及一种制备金属有机化合物的方法，其包括至少一种膦亚胺配体，其特征在于将根据式（1）的膦亚胺配体的HA加合物与式（1）的金属有机试剂 2）在至少2当量的碱的存在下，其中HA表示酸，其中H表示其质子，A表示其共轭碱，YNH为式（1），Mv（L1）k（L2）1 （L3）m（L4）nX，其中Y是取代的磷原子，M表示第4族或第5族金属离子，V表示金属离子的化合价，为3,4或5 L1，L2，L3和L4表示M上的配体或17族卤素原子，并且可以相同或不同，k，l，m，n = 0,1,2,3,4，其中k + 1 + m + n + 1 = V，X表示17族卤素原子。 本发明还涉及通过制备根据本发明方法的金属 - 有机化合物来制备聚烯烃的方法，其中所述碱是烯烃聚合相容性碱，所述金属 - 有机化合物在任何地方或之前被活化 聚合反应器。

    Process for the Preparation of a Metal-Organic Compound Comprising at Least One Imine Ligand
    9.
    发明申请
    Process for the Preparation of a Metal-Organic Compound Comprising at Least One Imine Ligand 有权
    用于制备包含至少一种亚胺配体的金属有机化合物的方法

    公开(公告)号：US20080045719A1

    公开(公告)日：2008-02-21

    申请号：US10567098

    申请日：2004-08-03

    申请人： Edwin Ijpeij ,  Henricus Arts ,  Gerardus van Doremaele ,  Felix Beijer ,  Francis Van Der Burgt ,  Martin Alexander Zuideveld

    发明人： Edwin Ijpeij ,  Henricus Arts ,  Gerardus van Doremaele ,  Felix Beijer ,  Francis Van Der Burgt ,  Martin Alexander Zuideveld

    IPC分类号： C07D233/00 ,  C07F9/02

    CPC分类号： C08F10/00 ,  C07F7/00 ,  C07F7/28 ,  C07F7/30 ,  C07F9/00 ,  C07F9/5355 ,  C07F17/00 ,  C07F19/00 ,  C08F4/65908 ,  C08F4/6592 ,  C08F210/06 ,  C08F210/16 ,  C08F2420/04 ,  C08F2500/17

    摘要： The invention relates to a process for the preparation of a metal-organic compound, comprising at least one phosphinimine ligand, characterized in that the HA adduct of a phosphinimine ligand according to formula (1) is contacted with a metal-organic reagent of formula (2) in the presence of at least 2 equivalents of a base, wherein HA represents an acid, of which H represents its proton and A its conjugate base, with Y═N—H as formula (1), and Mv(L1)k(L2)1(L3)m(L4)nX as formula (2), and wherein Y is a substituted phosphorous atom, and M represents a group 4 or group 5 metal ion, V represents the valency of the metal ion, being 3, 4 or 5 L1, L2, L3, and L4 represent a ligand or a group 17 halogen atom on M and may be equal or different, k, l, m, n=0, 1, 2, 3, 4 with k+l+m+n+l=V, and X represents a group 17 halogen atom. The invention further relates to a process for the preparation of a polyolefin by making a metal-organic compound according to the process of the invention, wherein the base is an olefin polymerisation compatible base, which metal-organic compound is activated anywhere in, or before a polymerisation reactor.

    摘要翻译： 本发明涉及一种制备金属有机化合物的方法，其包括至少一种膦亚胺配体，其特征在于将根据式（1）的膦亚胺配体的HA加合物与式（1）的金属有机试剂 2）在至少2当量碱的存在下，其中HA代表酸，其中H代表其质子，A代表其共轭碱，YNH如式（1）所示，M代表氢， （L 1/2）2（L 3）（L 1） （2），其中Y是取代的磷原子，M表示4或4位的基团（L 4） 5金属离子，V表示金属离子的化合价，为3,4或5个L 1，L 2，L 3 3和 L 4代表M上的配位体或17族卤素原子，可以相同或不同，k，l，m，n = 0,1,2,3,4，其中k + 1 + m + n + 1 = V，X表示17族卤素原子。 本发明还涉及通过制备根据本发明方法的金属 - 有机化合物来制备聚烯烃的方法，其中所述碱是烯烃聚合相容性碱，所述金属 - 有机化合物在任何地方或之前被活化 聚合反应器。