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    Process for preparing conjugated diene polymers
    3.
    发明授权
    Process for preparing conjugated diene polymers 失效
    制备共轭二烯聚合物的方法

    公开(公告)号：US4139690A

    公开(公告)日：1979-02-13

    申请号：US769038

    申请日：1977-02-16

    申请人： Yoshikazu Torigoe ,  Noboru Ohshima ,  Masaaki Watanabe ,  Eitaro Okuya

    发明人： Yoshikazu Torigoe ,  Noboru Ohshima ,  Masaaki Watanabe ,  Eitaro Okuya

    IPC分类号： C08F4/00 ,  C08F2/08 ,  C08F4/42 ,  C08F36/00 ,  C08F36/04 ,  C08F4/56

    CPC分类号： C08F36/04

    摘要： A process for preparing conjugated diene polymers by either polymerization of one or more monomers selected from a group of conjugated diene compounds or copolymerization of a conjugated diene compound with an alkenyl aromatic compound, using an organolithium initiator in a hydrocarbon solvent, characterized in that the polymerization is carried out in the presence of(1) one or more anionic surface active agent having a group --SO.sub.3 M or --OSO.sub.3 M (where M is an alkali metal) and(2) one or more Lewis bases.

    摘要翻译： 通过使用一种或多种选自一组共轭二烯化合物的单体或共轭二烯化合物与烯基芳族化合物的共聚合来制备共轭二烯聚合物的方法，使用有机锂引发剂在烃溶剂中，其特征在于聚合 在（1）具有基团-SO 3 M或-OSO 3 M（其中M是碱金属）的一种或多种阴离子表面活性剂的存在下进行和（2）一种或多种路易斯碱。

    Amino group-containing diene copolymer
    4.
    发明授权
    Amino group-containing diene copolymer 失效
    含氨基二烯共聚物

    公开(公告)号：US4751277A

    公开(公告)日：1988-06-14

    申请号：US525668

    申请日：1983-08-23

    申请人： Eitaro Okuya ,  Hiroji Enyo ,  Shin-ichiro Iwanama

    发明人： Eitaro Okuya ,  Hiroji Enyo ,  Shin-ichiro Iwanama

    IPC分类号： C08F20/00 ,  C08F20/34 ,  C08F36/00 ,  C08F36/04 ,  C08F220/34 ,  C08F236/04 ,  C08F236/12 ,  C08F226/00

    CPC分类号： C08F236/12

    摘要： zs An amino group-containing copolymer which is composed of (A) butadiene, isoprene or both of them, (B) acrylonitrile and (C) a (meth)acrylate represented by the general formula (I): ##STR1## wherein R is H or CH.sub.3, R.sub.1 and R.sub.2 are independently alkyl groups having 2 to 8 carbon atoms, and X is an alkylene group having 2 to 4 carbon atoms, and has a polymer composition (weight %) of (A):(B):(C) of 30 to 89.9:10 to 50:0.1 to 20. Said multi-component copolymer is used as oil-resistant rubber, and is particularly excellent in resistance to growth of crack by solvent.

    摘要翻译： zs由（A）丁二烯，异戊二烯或它们两者组成的含氨基的共聚物，（B）丙烯腈和（C）由通式（I）表示的（甲基）丙烯酸酯：（I） 其中R是H或CH3，R1和R2独立地是具有2至8个碳原子的烷基，X是具有2至4个碳原子的亚烷基，并且具有（A）的聚合物组成（重量％）:( B ）:( C）为30〜89.9:10〜50:0.1〜20。所述多组分共聚物用作耐油橡胶，并且通过溶剂对裂纹生长的耐受性特别优异。

    Polymer particles and process for producing the same
    5.
    发明授权
    Polymer particles and process for producing the same 失效
    聚合物颗粒及其制备方法

    公开(公告)号：US4742137A

    公开(公告)日：1988-05-03

    申请号：US906192

    申请日：1986-09-11

    申请人： Hisao Ono ,  Nobuyuki Ito ,  Kiyoshi Kasai ,  Nobuo Sakurai ,  Eitaro Okuya

    发明人： Hisao Ono ,  Nobuyuki Ito ,  Kiyoshi Kasai ,  Nobuo Sakurai ,  Eitaro Okuya

    IPC分类号： C08F2/16 ,  C08F2/22 ,  C08F36/04 ,  C08F279/02 ,  C08F36/00 ,  C08F36/06

    CPC分类号： C08F36/04 ,  C08F279/02

    摘要： An aqueous dispersion of polymer particles each consisting essentially of (a) a syndiotactic 1,2-polybutadiene having 70% or more of unsaturated hydrocarbon groups in the side chains and having a melting point of 70.degree. C. or higher, (b) a polymer mixture of said polybutadiene (a) and other polymer in the form that (a) and (b) co-exist in the same particle, or (c) a copolymer obtained by graft-polymerizing a conjugated diene and/or other polymerizable monomer on said polybutadiene (a), each of said particles having an average diameter of 10 .mu.m or less. Said aqueous dispersion can be produced by a process comprising steps of adding, to an aqueous dispersion of a first catalyst component solution, a conjugated diene monomer and a second catalyst component and polymerizing said conjugated diene monomer, characterized in that the first catalyst component solution contains (A) a cobalt compound, (B) at least one member selected from the group consisting of alkali metals, organometallic compounds of metals of Groups I to III of the Periodic Table and hydrides of metals of Groups I to III of the Periodic Table, and (C) 1 to 1,000 moles, per mole of the cobalt compound (A), of a conjugated diene compound and then the second catalyst component is at least one compound selected from the group consisting of carbon disulfide, phenylisothiocyanic acid and a xanthogen compound.

    摘要翻译： 聚合物颗粒的水性分散体各自主要由（a）在侧链中具有70％以上不饱和烃基的间同立构1,2-聚丁二烯，熔点为70℃以上，（b） 所述聚丁二烯（a）和（a）和（b）所示形式的其它聚合物的聚合物混合物共存于相同的颗粒中，或（c）通过共轭二烯和/或其它可聚合单体的接枝聚合获得的共聚物 在所述聚丁二烯（a）上，每个所述颗粒具有10μm或更小的平均直径。 所述水分散体可以通过以下步骤制备，所述方法包括向第一催化剂组分溶液的水分散体，共轭二烯单体和第二催化剂组分中加入并聚合所述共轭二烯单体的步骤，其特征在于，所述第一催化剂组分溶液含 （A）钴化合物，（B）选自碱金属，元素周期表I至III族金属的有机金属化合物和元素周期表I至III族金属的氢化物中的至少一种， 和（C）每摩尔钴化合物（A）1至1,000摩尔的共轭二烯化合物，然后第二催化剂组分为选自二硫化碳，苯基异硫氰酸和黄原酸化合物中的至少一种化合物 。