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公开(公告)号：US09005538B2
公开(公告)日：2015-04-14
申请号：US13535040
申请日：2012-06-27
CPC分类号： C10G2/00 , B01J8/025 , B01J8/06 , B01J8/067 , B01J23/75 , B01J35/0006 , B01J35/026 , B01J2208/00672 , B01J2208/025 , B01J2219/00038 , B01J2219/0004
摘要： The invention pertains to a reactor tube comprising a fixed bed of Fischer-Tropsch catalyst particles, wherein the catalyst particles in 5%-40% of the fixed bed volume at the upstream end have an average outer surface to volume ratio (S/V) of between 3.0 to 4.5 mm-1, and the remaining catalyst particles have an average S/V of between 4.5 to 8.0 mm-1, and wherein the difference between the average S/V of the particles at the upstream end and the remaining fixed bed volume is at least 0.5 mm-1. Additionally the fixed bed volume at the upstream end shows a full-bed apparent catalytic activity per volume unit lower than the full-bed apparent catalytic activity per volume unit in the remaining fixed bed volume and/or the weight of catalytically active metal per weight unit at the upstream end is more than 70% lower than in the remaining fixed bed volume.
摘要翻译： 本发明涉及一种包含费 - 托催化剂颗粒固定床的反应器管，其中上游端固定床体积的5％-40％的催化剂颗粒具有平均的外表面与体积比（S / V） 为3.0〜4.5mm -1，剩余的催化剂粒子的平均S / V为4.5〜8.0mm -1，上游侧的粒子的平均S / V与剩余的固定 床体积至少为0.5mm-1。 此外，上游端的固定床体积显示出比在剩余固定床体积中每单位体积单体的全床视在催化活性和/或每重量单位的催化活性金属重量的每体积单位的全床表观催化活性 在上游端比剩下的固定床体积低70％以上。
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公开(公告)号：US20130165537A1
公开(公告)日：2013-06-27
申请号：US13535027
申请日：2012-06-27
IPC分类号： B01J8/06
CPC分类号： C10G2/00 , B01J8/025 , B01J8/06 , B01J8/067 , B01J23/75 , B01J35/0006 , B01J35/026 , B01J2208/00663 , B01J2208/00672 , B01J2208/025 , B01J2219/00038 , B01J2219/0004 , C10G2/33 , C10G2/341 , C10G2300/1011 , C10G2300/1025 , Y02E50/32 , Y02P30/20
摘要： The present invention pertains to a reactor tube comprising a fixed bed of Fischer-Tropsch catalyst particles, wherein the catalyst particles in 5% to 40% of the fixed bed volume at the upstream end have an average outer surface to volume ratio (S/V) of between 3.0 to 4.5 mm−1, and the catalyst particles in the remaining fixed bed volume have an average S/V of between 4.5 to 8.0 mm−1, and wherein the difference between the average S/V of the particles at the upstream end and the average S/V of the particles in the remaining fixed bed volume is at least 0.5 mm−1. The weight of catalytically active metal per volume unit in 5% to 33% of the fixed bed volume at the upstream end is 59% to 69% lower than the weight of catalytically active metal per volume unit in the remaining fixed bed volume.
摘要翻译： 本发明涉及一种包含费 - 托催化剂颗粒的固定床的反应器管，其中在上游端固定床体积的5％至40％的催化剂颗粒具有平均的外表面与体积比（S / V ）为3.0〜4.5mm -1，剩余固定床体积中的催化剂粒子的S / V为4.5〜8.0mm -1，平均S / V为 上游端和剩余固定床体积中的颗粒的平均S / V为至少0.5mm-1。 催化活性金属每体积单位的重量在5％至33％的固定床体积的上游端比其余固定床体积中每体积单位催化活性金属的重量低59％至69％。
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公开(公告)号：US08980194B2
公开(公告)日：2015-03-17
申请号：US12969158
申请日：2010-12-15
申请人： Alouisius Nicolaas Renée Bos , Peter John Van Den Brink , Thomas Joris Remans , Erwin Roderick Stobbe , Dominik Johannes Michael Unruh , Ronald Vladimir Wisman
发明人： Alouisius Nicolaas Renée Bos , Peter John Van Den Brink , Thomas Joris Remans , Erwin Roderick Stobbe , Dominik Johannes Michael Unruh , Ronald Vladimir Wisman
CPC分类号： B01J8/06 , B01J2208/00017 , B01J2208/00663 , B01J2208/00672 , B01J2208/00681 , B01J2208/025 , C10G2/341
摘要： The present invention pertains to a reactor tube comprising a fixed bed of Fischer-Tropsch catalyst particles, wherein the catalyst particles in 5% to 40% of the fixed bed volume at the upstream end have an average outer surface to volume ratio (S/V) in the range of between 3.0 to 4.5 mm−1, and the catalyst particles in the remaining fixed bed volume have an average outer surface to volume ratio (S/V) in the range of between 4.5 to 8.0 mm−1, and wherein the difference between the average S/V of the particles at the upstream end and the average S/V of the particles in the remaining fixed bed volume is at least 0.5 mm−1.
摘要翻译： 本发明涉及一种包含费 - 托催化剂颗粒的固定床的反应器管，其中在上游端固定床体积的5％至40％的催化剂颗粒具有平均的外表面与体积比（S / V ）在3.0至4.5mm -1的范围内，剩余固定床体积中的催化剂颗粒的平均外表面与体积比（S / V）在4.5至8.0mm -1的范围内，其中 在上游端的颗粒的平均S / V与剩余固定床体积中的颗粒的平均S / V之间的差为至少0.5mm-1。
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公开(公告)号：US20130023594A1
公开(公告)日：2013-01-24
申请号：US13535040
申请日：2012-06-27
CPC分类号： C10G2/00 , B01J8/025 , B01J8/06 , B01J8/067 , B01J23/75 , B01J35/0006 , B01J35/026 , B01J2208/00672 , B01J2208/025 , B01J2219/00038 , B01J2219/0004
摘要： The invention pertains to a reactor tube comprising a fixed bed of Fischer-Tropsch catalyst particles, wherein the catalyst particles in 5%-40% of the fixed bed volume at the upstream end have an average outer surface to volume ratio (S/V) of between 3.0 to 4.5 mm-1, and the remaining catalyst particles have an average S/V of between 4.5 to 8.0 mm-1, and wherein the difference between the average S/V of the particles at the upstream end and the remaining fixed bed volume is at least 0.5 mm-1. Additionally the fixed bed volume at the upstream end shows a full-bed apparent catalytic activity per volume unit lower than the full-bed apparent catalytic activity per volume unit in the remaining fixed bed volume and/or the weight of catalytically active metal per weight unit at the upstream end is more than 70% lower than in the remaining fixed bed volume.
摘要翻译： 本发明涉及一种包含费 - 托催化剂颗粒固定床的反应器管，其中上游端固定床体积的5％-40％的催化剂颗粒具有平均的外表面与体积比（S / V） 为3.0〜4.5mm -1，剩余的催化剂粒子的平均S / V为4.5〜8.0mm -1，上游侧的粒子的平均S / V与剩余的固定 床体积至少为0.5mm-1。 此外，上游端的固定床体积显示出比在剩余固定床体积中每单位体积单体的全床视在催化活性和/或每重量单位的催化活性金属重量的每体积单位的全床表观催化活性 在上游端比剩下的固定床体积低70％以上。
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公开(公告)号：US20100160146A1
公开(公告)日：2010-06-24
申请号：US12639707
申请日：2009-12-16
CPC分类号： B01J31/403 , B01J23/75 , B01J38/02 , B01J38/10 , B01J38/66 , B01J2531/845 , C10G2/332 , C10G2300/70
摘要： A process for regenerating one or more deactivated cobalt comprising Fischer-Tropsch catalyst particle(s) in situ in a reactor tube, said process comprising the steps of: (i) oxidising the catalyst particle(s) at a temperature between 20 and 400° C.; (ii) treating the catalyst particle(s) for more than 5 minutes with a solvent, (iii) drying the catalyst particle(s); and (iv) optionally reducing the catalyst with hydrogen or a hydrogen comprising gas. This process may be preceded by a step in which Fischer-Tropsch product is removed from the catalyst particle(s).
摘要翻译： 一种在反应器管中原位再生一种或多种包含费 - 托催化剂颗粒的失活的钴的方法，所述方法包括以下步骤：（i）在20-400℃的温度下氧化催化剂颗粒 C。; （ii）用溶剂处理催化剂颗粒超过5分钟，（iii）干燥催化剂颗粒; 和（iv）任选地用氢或包含气体的氢还原催化剂。 此过程之前可以是从催化剂颗粒中除去费 - 托产物的步骤。
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公开(公告)号：US20110160318A1
公开(公告)日：2011-06-30
申请号：US12969158
申请日：2010-12-15
申请人： Alouisius Nicolaas Renée BOS , Peter John Van Den Brink , Thomas Joris Remans , Erwin Roderick Stobbe , Dominik Johannes Michael Unruh , Ronald Vladimir Wisman
发明人： Alouisius Nicolaas Renée BOS , Peter John Van Den Brink , Thomas Joris Remans , Erwin Roderick Stobbe , Dominik Johannes Michael Unruh , Ronald Vladimir Wisman
CPC分类号： B01J8/06 , B01J2208/00017 , B01J2208/00663 , B01J2208/00672 , B01J2208/00681 , B01J2208/025 , C10G2/341
摘要： The present invention pertains to a reactor tube comprising a fixed bed of Fischer-Tropsch catalyst particles, wherein the catalyst particles in 5% to 40% of the fixed bed volume at the upstream end have an average outer surface to volume ratio (S/V) in the range of between 3.0 to 4.5 mm−1, and the catalyst particles in the remaining fixed bed volume have an average outer surface to volume ratio (S/V) in the range of between 4.5 to 8.0 mm−1, and wherein the difference between the average S/V of the particles at the upstream end and the average S/V of the particles in the remaining fixed bed volume is at least 0.5 mm−1.
摘要翻译： 本发明涉及一种包含费 - 托催化剂颗粒的固定床的反应器管，其中在上游端固定床体积的5％至40％的催化剂颗粒具有平均的外表面与体积比（S / V ）在3.0至4.5mm -1的范围内，剩余固定床体积中的催化剂颗粒的平均外表面与体积比（S / V）在4.5至8.0mm -1的范围内，其中 在上游端的颗粒的平均S / V与剩余固定床体积中的颗粒的平均S / V之间的差为至少0.5mm-1。
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