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公开(公告)号：US09199924B2
公开(公告)日：2015-12-01
申请号：US13816526
申请日：2011-08-09
IPC分类号： B01J31/22 , C07C263/00 , C07C269/04 , C07C245/08 , C07C251/24 , C07D215/26 , C07D213/30
CPC分类号： C07C263/00 , B01J31/2243 , B01J2231/70 , B01J2531/0241 , B01J2531/16 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/828 , B01J2531/845 , B01J2531/847 , C07C245/08 , C07C251/24 , C07C269/04 , C07D213/30 , C07D215/26 , C07C271/28
摘要： The invention relates to a method for producing urethanes or ureas or mixtures of urethanes and ureas by oxidative carbonylation of organic amines in the presence of carbon monoxide, oxygen and a catalyst, where the catalyst used is a transition metal complex containing the structural feature: [Mn+(O˜N˜O)2−](n−2)+(L)m(Z−)n−2 and the method is carried out under halogen-free reaction conditions. The invention further relates to transition metal complexes containing said structural feature and also to the use of such transition metal complexes as catalysts in the production of urethanes or ureas or mixtures of urethanes and ureas.
摘要翻译： 本发明涉及通过在一氧化碳，氧气和催化剂存在下通过有机胺的氧化羰基化制备氨基甲酸酯或脲或聚氨酯和脲的混合物的方法，其中使用的催化剂是含有结构特征的过渡金属络合物： Mn +（O〜N〜O）2 - ]（n-2）+（L）m（Z-）n-2，该方法在无卤素反应条件下进行。 本发明进一步涉及含有所述结构特征的过渡金属络合物，以及在生产聚氨酯或脲或者聚氨酯和脲的混合物中使用这种过渡金属配合物作为催化剂。
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2.发明申请DETERGENTS OR CLEANING AGENTS CONTAINING A BLEACH-ENHANCING TRANSITION METAL COMPLEX WHICH IS OPTIONALLY PRODUCED IN SITU 有权含有在本地生产的漂白增强过渡金属复合物的洗涤剂或清洁剂公开(公告)号：US20120264670A1
公开(公告)日：2012-10-18
申请号：US13478464
申请日：2012-05-23
CPC分类号： C11D3/3932 , C11D3/168 , C11D3/26 , C11D3/3917
摘要： The aim of the invention is to improve the cleaning power of detergents and cleaning agents, especially with regard to bleachable stains, while avoiding any damage to the textile treated with said detergents and cleaning agents. For this purpose, a bleach catalyst in the form of a complex of Fe—, Mo—, Mn— and/or W with a ligand having a skeleton of formula (I) is used.
摘要翻译： 本发明的目的是提高洗涤剂和清洁剂的清洁能力，特别是在可漂白污渍方面，同时避免对用所述洗涤剂和清洁剂处理的织物的任何损坏。 为此，使用Fe-，Mo-，Mn-和/或W与具有式（I）骨架的配体的络合物形式的漂白催化剂。
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3.发明申请DETERGENTS OR CLEANING AGENTS CONTAINING A BLEACH-ENHANCING TRANSITION METAL COMPLEX WHICH IS OPTIONALLY PRODUCED IN SITU 有权含有在本地生产的漂白增强过渡金属复合物的洗涤剂或清洁剂公开(公告)号：US20120264668A1
公开(公告)日：2012-10-18
申请号：US13478438
申请日：2012-05-23
CPC分类号： C11D3/168 , C11D3/28 , C11D3/3932
摘要： A bleach catalyst includes a complex of Fe—, Mo—, Mn— and/or W with a ligand having a skeleton of formula (I).
摘要翻译： 漂白催化剂包括Fe-，Mo-，Mn-和/或W与具有式（I）骨架的配体的络合物。
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4.发明申请公开(公告)号：US20140255296A1
公开(公告)日：2014-09-11
申请号：US14111872
申请日：2012-04-18
申请人： Matthias Beller , Ralf Jackstell , Heinrik Junge , Felix Gärtner , Albert Boddien , Doerthe Mellmann
发明人： Matthias Beller , Ralf Jackstell , Heinrik Junge , Felix Gärtner , Albert Boddien , Doerthe Mellmann
IPC分类号： C01B3/22
CPC分类号： C01B3/22 , C01B2203/1041 , C01B2203/1047 , C01B2203/1064
摘要： The invention relates to a method for producing hydrogen by selective dehydration of formic acid using a catalytic system consisting of a transition metal complex of transition metal salt and at least one tripodal, tetradentate ligand, wherein the transition metal is selected from the group comprising Ir, Pd, Pt, Ru, Rh, Co and Fe. The transition metal complex can be used either as a homogeneous catalyst or a heterogenised metal complex, which has been applied to a carrier.
摘要翻译： 本发明涉及一种通过使用由过渡金属盐和至少一种三齿四配位配体的过渡金属络合物组成的催化体系选择性脱水甲酸生产氢的方法，其中过渡金属选自Ir， Pd，Pt，Ru，Rh，Co和Fe。 过渡金属络合物可以用作已经应用于载体的均相催化剂或异质金属络合物。
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公开(公告)号：US20130303740A1
公开(公告)日：2013-11-14
申请号：US13816526
申请日：2011-08-09
IPC分类号： C07C269/04 , C07C263/00
CPC分类号： C07C263/00 , B01J31/2243 , B01J2231/70 , B01J2531/0241 , B01J2531/16 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/828 , B01J2531/845 , B01J2531/847 , C07C245/08 , C07C251/24 , C07C269/04 , C07D213/30 , C07D215/26 , C07C271/28
摘要： The invention relates to a method for producing urethanes or ureas or mixtures of urethanes and ureas by oxidative carbonylation of organic amines in the presence of carbon monoxide, oxygen and a catalyst, where the catalyst used is a transition metal complex containing the structural feature: [Mn+(O˜N˜O)2−](n-2)+(L)m(Z−)n-2 and the method is carried out under halogen-free reaction conditions. The invention further relates to transition metal complexes containing said structural feature and also to the use of such transition metal complexes as catalysts in the production of urethanes or ureas or mixtures of urethanes and ureas.
摘要翻译： 本发明涉及通过在一氧化碳，氧气和催化剂存在下通过有机胺的氧化羰基化制备氨基甲酸酯或脲或聚氨酯和脲的混合物的方法，其中使用的催化剂是含有结构特征的过渡金属络合物： Mn +（O〜N〜O）2 - ]（n-2）+（L）m（Z-）n-2，该方法在无卤素反应条件下进行。 本发明进一步涉及含有所述结构特征的过渡金属络合物，以及在生产聚氨酯或脲或者聚氨酯和脲的混合物中使用这种过渡金属配合物作为催化剂。
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