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1.发明申请PROCESS FOR PREPARING MATERIALS BY GRAFTING HALOGENATED PHOSPHORUS-CONTAINING GROUPS ONTO AN INORGANIC SURFACE 失效通过将含有含磷酸盐的组合物收集到无机表面上来制备材料的方法公开(公告)号：US20100069618A1
公开(公告)日：2010-03-18
申请号：US12375742
申请日：2007-07-06
申请人： Renaud Revel , Florence Brodard-Severac , Gilles Guerrero , Hubert Mutin , Alain Forestiere , Alexandra Chaumonnot
发明人： Renaud Revel , Florence Brodard-Severac , Gilles Guerrero , Hubert Mutin , Alain Forestiere , Alexandra Chaumonnot
CPC分类号： B01J20/3248 , B01J21/063 , B01J31/0269 , C04B41/009 , C04B41/4584 , C04B41/81 , C07F9/657181 , C04B41/4994 , C04B35/46
摘要： The invention concerns a process for preparing a hybrid organic-inorganic material (HOIM) with phosphorus-containing bridges between the surface of an inorganic substrate containing an element M and one or more organic groups of the covalent M-O-P-R type, said process using, as a precursor for said organic group or groups, at least one organophosphorus acid halide with formula RxP(O)Xy in which x=1 or 2, y=3−x, X being a halogen and R designating at least one organic alkyl, aryl or aryl-alkyl group.Non-exhaustive applications for the hybrid organic-inorganic material obtained by the process of the invention are in the fields of anti-corrosion, lubrication, microelectronics, nanotechnologies, composite materials, heterogeneous catalysis, supported catalysis, depollution and biomedical applications.
摘要翻译： 本发明涉及一种在含有元素M的无机基质的表面与共价MOPR型的一种或多种有机基团的表面之间制备具有含磷桥的杂化有机 - 无机材料（HOIM）的方法，所述方法使用 所述有机基团的前体，至少一种式RxP（O）Xy的有机磷酰卤，其中x = 1或2，y = 3-x，X为卤素，R指定至少一个有机烷基，芳基或 芳基 - 烷基。 通过本发明方法获得的杂化有机 - 无机材料的非穷举应用在抗腐蚀，润滑，微电子学，纳米技术，复合材料，多相催化，负载催化，去污染和生物医学应用领域。
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2.发明授权Process for preparing materials by grafting halogenated phosphorus-containing groups onto an inorganic surface 失效通过将卤代含磷基团接枝到无机表面上制备材料的方法公开(公告)号：US08247539B2
公开(公告)日：2012-08-21
申请号：US12375742
申请日：2007-07-06
申请人： Renaud Revel , Florence Brodard-Severac , Gilles Guerrero , Hubert Mutin , Alain Forestiere , Alexandra Chaumonnot
发明人： Renaud Revel , Florence Brodard-Severac , Gilles Guerrero , Hubert Mutin , Alain Forestiere , Alexandra Chaumonnot
CPC分类号： B01J20/3248 , B01J21/063 , B01J31/0269 , C04B41/009 , C04B41/4584 , C04B41/81 , C07F9/657181 , C04B41/4994 , C04B35/46
摘要： The invention concerns a process for preparing a hybrid organic-inorganic material (HOIM) with phosphorus-containing bridges between the surface of an inorganic substrate containing an element M and one or more organic groups of the covalent M-O-P-R type, said process using, as a precursor for said organic group or groups, at least one organophosphorus acid halide with formula RxP(O)Xy in which x=1 or 2, y=3−x, X being a halogen and R designating at least one organic alkyl, aryl or aryl-alkyl group.Non-exhaustive applications for the hybrid organic-inorganic material obtained by the process of the invention are in the fields of anti-corrosion, lubrication, microelectronics, nanotechnologies, composite materials, heterogeneous catalysis, supported catalysis, depollution and biomedical applications.
摘要翻译： 本发明涉及一种在含有元素M的无机基质的表面与共价MOPR型的一种或多种有机基团的表面之间制备具有含磷桥的杂化有机 - 无机材料（HOIM）的方法，所述方法使用 所述有机基团的前体，至少一种式RxP（O）Xy的有机磷酰卤，其中x = 1或2，y = 3-x，X为卤素，R指定至少一个有机烷基，芳基或 芳基 - 烷基。 通过本发明方法获得的杂化有机 - 无机材料的非穷举应用在抗腐蚀，润滑，微电子学，纳米技术，复合材料，多相催化，负载催化，去污染和生物医学应用领域。
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