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公开(公告)号：US5750324A
公开(公告)日：1998-05-12
申请号：US779539
申请日：1997-01-08
摘要： This invention relates to a silver halide photographic element for digital exposure comprising a cubical silver chloride emulsion precipitated and/or chemically sensitized in the presence of an aryliodonium compound represented by the formula: ##STR1## wherein R.sup.1 and R.sup.2 and R.sup.3 are independently H, or aliphatic, aromatic or heterocyclic groups, alkoxy groups, hydroxy groups, halogen atoms, aryloxy groups, alkylthio groups, arylthio groups, acyl groups, sulfonyl groups, acyloxy groups, carboxyl groups, cyano groups, nitro groups, sulfo groups, alkylsulfoxide or trifluoralkyl groups, or any two of R.sup.1, R.sup.2 and R.sup.3 together represent the atoms necessary to form a five or six-membered ring or a multiple ring system; R.sup.4 is a carboxylate salt or 0.sup.- ; w is 0 or 1; and X.sup.- is an anionic counter ion; with the proviso that when R.sup.3 is a carboxyl or sulfo group, w is 0 and R.sup.4 is 0.sup.-.
摘要翻译： 本发明涉及一种用于数字曝光的卤化银照相元件，包括在下式表示的芳基碘鎓化合物存在下沉淀和/或化学增感的立方氯化银乳剂：其中R1和R2和R3独立地为H，或 脂族，芳族或杂环基，烷氧基，羟基，卤素原子，芳氧基，烷硫基，芳硫基，酰基，磺酰基，酰氧基，羧基，氰基，硝基，磺基，烷基亚砜或三氟烷基 ，或者R 1，R 2和R 3中的任何两个一起表示形成五元或六元环或多环系所必需的原子; R 4是羧酸盐或O- w为0或1; 而X-是阴离子抗衡离子; 条件是当R3为羧基或磺基时，w为0且R4为0-。
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公开(公告)号：US5733717A
公开(公告)日：1998-03-31
申请号：US779538
申请日：1997-01-08
CPC分类号： G03C1/34
摘要： This invention relates to a silver halide photographic element comprising a silver halide emulsion precipitated and/or chemically sensitized in the presence of an aryliodonium compound represented by the formula: ##STR1## wherein R.sup.1 and R.sup.2 and R.sup.3 are independently H, or aliphatic, aromatic or heterocyclic groups, alkoxy groups, hydroxy groups, halogen atoms, aryloxy groups, alkylthio groups, arylthio groups, acyl groups, sulfonyl groups, acyloxy groups, carboxyl groups, cyano groups, nitro groups, sulfo groups, alkylsulfoxide or trifluoralkyl groups, or any two of R.sup.1, R.sup.2 and R.sup.3 together represent the atoms necessary to form a five or six-membered ring or a multiple ring system; R.sup.4 is a carboxylate salt or 0.sup.- ; w is 0 or 1; and X.sup.- is an anionic counter ion; with the proviso that when R.sup.3 is a carboxyl or sulfo group, w is 0 and R.sup.4 is 0.sup.-.
摘要翻译： 本发明涉及一种卤化银照相元件，其包含在由下式表示的芳基碘鎓化合物存在下沉淀和/或化学增感的卤化银乳剂：其中R 1和R 2和R 3独立地为H，或脂族，芳族或 杂环基，烷氧基，羟基，卤原子，芳氧基，烷硫基，芳硫基，酰基，磺酰基，酰氧基，羧基，氰基，硝基，磺基，烷基亚砜或三氟烷基， 的R 1，R 2和R 3一起表示形成五元或六元环或多环体系所必需的原子; R 4是羧酸盐或O- w为0或1; X-是阴离子抗衡离子; 条件是当R3为羧基或磺基时，w为0且R4为0-。
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公开(公告)号：US4092163A
公开(公告)日：1978-05-30
申请号：US779380
申请日：1977-03-21
申请人： Harry W. Gibson , Franklin D. Saeva
发明人： Harry W. Gibson , Franklin D. Saeva
CPC分类号： G03G9/1132 , Y10S430/105 , Y10T428/2998
摘要： Electrostatographic developer compositions for use in developing electrostatic latent images wherein the triboelectric charging potential of functional polymers employed in the carrier materials are controlled through chemical alteration of active hydrogen containing materials by silylation. The controlled variation of the triboelectric behavior of functional polymers by silylation provides a means of attaining optimum triboelectric responses in development systems.
摘要翻译： 用于显影静电潜像的静电显影剂组合物，其中在载体材料中使用的官能聚合物的摩擦带电电位通过甲硅烷基化学改变含活性氢的材料来控制。 通过甲硅烷基化可以控制功能聚合物的摩擦电行为的变化提供了在开发系统中获得最佳摩擦电响应的方法。
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公开(公告)号：US3957348A
公开(公告)日：1976-05-18
申请号：US562305
申请日：1975-03-26
申请人： Franklin D. Saeva
发明人： Franklin D. Saeva
CPC分类号： G02F1/137 , G02F2201/343 , Y10S359/90
摘要： The optical transitions of extrinsically optically active soluble and insoluble materials become circularly dichroic when in contact with twisted nematic liquid crystalline materials. The circularly dichroic optical properties induced in the normally extrinsically optically active materials are utilized to alter the relative amounts of left and right hand circularly polarized light in elliptically polarized light including producing circularly polarized light.
摘要翻译： 当与扭曲的向列型液晶材料接触时，光学活性的可溶性和不溶性材料的光学转变变为圆形二向色。 在通常的二次光学活性材料中诱发的圆二色性光学性质被用来改变包括产生圆偏振光的椭圆偏振光中的左旋和右旋圆偏振光的相对量。
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公开(公告)号：US3957346A
公开(公告)日：1976-05-18
申请号：US562303
申请日：1975-03-26
申请人： Franklin D. Saeva
发明人： Franklin D. Saeva
CPC分类号： G02F1/137 , G02F2201/343 , Y10S359/90
摘要： The optical transitions of twisted nematic liquid crystalline compositions exhibit circular dichroism. The circular dichroism in twisted nematic liquid crystalline compositions is utilized to alter the relative amounts of left and right hand circularly polarized light in elliptically polarized light, including producing circularly polarized light.
摘要翻译： 扭曲向列液晶组合物的光学转变呈现圆二色性。 扭转向列液晶组合物中的圆二色性用于改变椭圆偏振光中的左右圆偏振光的相对量，包括产生圆偏振光。
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公开(公告)号：US5879872A
公开(公告)日：1999-03-09
申请号：US857397
申请日：1997-05-16
摘要： This invention relates to a silver halide photographic element comprising a silver halide emulsion precipitated and/or chemically sensitized in the presence of an sulfenimide compound represented by the formula: ##STR1## wherein M represents the atoms necessary to form, with R.sup.1 and R.sup.2, a five or six-membered ring or a multiple ring system; w is 1 or 0, wherein when w is 0, R.sup.1 and R.sup.2 are independently substituted or unsubstituted aliphatic, aromatic or heterocyclic groups, and when w is 1, R.sup.1 and R.sup.2 are independently carbonyl or sulfonyl groups; R.sup.3 is independently a substituted or unsubstituted aliphatic, aromatic or heterocyclic group and x is 0 or 1.
摘要翻译： 本发明涉及一种卤化银照相元件，其包含在下式表示的亚硫酰亚胺化合物存在下沉淀和/或化学增感的卤化银乳剂：其中M表示与R1和R2形成必需的原子， 五元或六元环或多环系统; w为1或0，其中当w为0时，R 1和R 2独立地为取代或未取代的脂族，芳族或杂环基，当w为1时，R 1和R 2独立地为羰基或磺酰基; R 3独立地是取代或未取代的脂族，芳族或杂环基团，x是0或1。
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7.发明授权
公开(公告)号：US5858640A
公开(公告)日：1999-01-12
申请号：US857750
申请日：1997-05-16
CPC分类号： G03C1/49845 , B41M5/26 , G03C1/34
摘要： This invention provides a thermally processable imaging element comprising a support and a thermographic or photothermographic imaging layer, said imaging layer comprising a sulfenimide compound represented by the formula: ##STR1## wherein M represents the atoms necessary to form, with R.sup.1 and R.sup.2, a five or six-membered ring or a multiple ring system; w is 1 or 0, wherein when w is 0, R.sup.1 and R.sup.2 are independently substituted or unsubstituted aliphatic, aromatic or heterocyclic groups, and when w is 1, R.sup.1 and R.sup.2 are independently carbonyl or sulfonyl groups; R.sup.3 is independently a substituted or unsubstituted aliphatic, aromatic or heterocyclic group and x is 0 or 1.In one embodiment the thermally processable imaging element comprises:(a) photographic silver halide, and(b) an image-forming combination comprising(i) an organic silver salt oxidizing agent, with(ii) a reducing agent for the organic silver salt oxidizing agent.
摘要翻译： 本发明提供了一种可热加工的成像元件，其包括载体和热成像或光热成像层，所述成像层包含由下式表示的亚磺酰亚胺化合物：其中M表示与R1和R2形成五元素所需的原子 或六元环或多环系统; w为1或0，其中当w为0时，R 1和R 2独立地为取代或未取代的脂族，芳族或杂环基，当w为1时，R 1和R 2独立地为羰基或磺酰基; R 3独立地是取代或未取代的脂族，芳族或杂环基团，x是0或1.在一个实施方案中，热可加工成像元件包括：（a）照相卤化银，和（b）成像组合，其包含（i） 有机银盐氧化剂，（ii）有机银盐氧化剂的还原剂。
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公开(公告)号：US5089374A
公开(公告)日：1992-02-18
申请号：US611631
申请日：1990-11-13
申请人： Franklin D. Saeva
发明人： Franklin D. Saeva
IPC分类号： G03F7/029
CPC分类号： G03F7/029 , Y10S430/115
摘要： Bis-sulfonium, -selenonium, -arsonium, -ammonium, and -phosphonium salts useful as photoinitiators, comprise:an aromatic or heterocyclic aromatic group which absorbs UV or visible radiation and which exhibits a higher energy occupied molecular orbital than at least one other substituent attached to each of the S, Se, As, N or P atoms of said salt;at least one substituent, attached to each of the S, Se, As, N or P atoms of said salt, which comprises an electron-withdrawing group which causes the lowest unoccupied molecular orbital to be localized on the substituent and the S, Se, As, N or P atom of the salt;an insulating group which links said aromatic or heterocyclic aromatic group to each of the S, Se, As, N, or P atoms of said salt, said insulating group essentially preventing .pi. resonance between said aromatic or heterocyclic aromatic group and the other substituents in said salt; andtwo anions;said salt being capable, upon exposure to UV or visible radiation absorbed by said aromatic or heterocyclic aromatic group, of forming a Bronsted acid.The invention also relates to the use of such photoinitiators.
摘要翻译： 可用作光引发剂的双锍，硒鎓，锍，铵和鏻盐包括：吸收UV或可见光辐射的芳香族或杂环芳族基团，其表现出比至少一种其它取代基更高的能量占据的分子轨道 附着于所述盐的S，Se，As，N或P原子中的每一个; 至少一个取代基，其连接到所述盐的S，Se，As，N或P原子中的每一个上，所述取代基包括引起最低未占分子轨道定位在取代基上的吸电子基团和S，Se， As，N或P原子的盐; 将所述芳族或杂环芳族基团与所述盐的S，Se，As，N或P原子中的每一个连接的绝缘基团，所述绝缘基本基本上防止所述芳族或杂环芳族基团与所述芳族或杂环芳族基团中的所有其它取代基之间的π共振 盐; 和两种阴离子; 所述盐在暴露于由所述芳族或杂环芳族基团吸收的UV或可见光辐射时能够形成布朗斯台德酸。 本发明还涉及这种光引发剂的用途。
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公开(公告)号：US3957345A
公开(公告)日：1976-05-18
申请号：US562067
申请日：1975-03-26
申请人： Franklin D. Saeva
发明人： Franklin D. Saeva
CPC分类号： G02F1/137 , G11C13/047 , Y10S359/90
摘要： Circular dichroism within absorption bands of nematic liquid crystalline compositions of positive dielectric anisotropy in the twisted nematic structure is utilized for information transfer applications.
摘要翻译： 在扭转向列结构中正介电各向异性的向列型液晶组合物的吸收带内的圆二色性用于信息传递应用。
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公开(公告)号：US3954906A
公开(公告)日：1976-05-04
申请号：US519330
申请日：1974-10-30
CPC分类号： G03G5/07 , C08G61/02 , C08L65/00 , Y10T428/31678 , Y10T428/31993
摘要： Ambipolar photoconductive composition comprising the product of the in situ polymerization of at least one cyclic compound of the formula: ##EQU1## wherein Ar is a polyaromatic nucleus selected from the group consisting of diradicals of naphthalene, anthracene, pyrene and carbazole;X and Y are independently selected from the group consisting of halogen, NO.sub.2, NH.sub.2 ; lower alkyl, phenyl, phenoxy, lower alkoxy, carboxy, hydroxyl, lower alkyl esters and aryl esters;m and n can range from 0 to the total number of replaceable hydrogens on the polyaromatic nucleus;In a polymeric host resin.By the appropriate in situ polymerization of the above compound in the host polymer, it is possible to produce an interpretating photoconductive netword throughout the host polymer. The resulting photoconductive materials can be incorporated into an imaging member in an electrostatographic imaging system and function in either a positive or negative charging mode.
摘要翻译： 双极光导电组合物，其包含至少一种下式的环状化合物的原位聚合的产物：CH 2 -----CH 2 ||（Y）m -ArAr-（X）n || CH 2 -----CH 2 其中Ar是选自萘，蒽，芘和咔唑的双基的多芳香核; X和Y独立地选自卤素，NO 2，NH 2; 低级烷基，苯基，苯氧基，低级烷氧基，羧基，羟基，低级烷基酯和芳基酯; M和N可以从0到多晶核的可代替氢的总数范围; 在聚合物树脂中。
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