摘要:
The present invention relates to an acid-doped polymer membrane based on polyazoles. The acid-doped polymer membrane can be used in a variety of applications because of its excellent mechanical properties and is useful as polymer electrolyte membrane (PEM) in PEM fuel cells. A doped polymer membrane based on polyazoles is obtained by a process comprising the steps of: A) casting a film using a solution of polymers based on polyazoles in a polar, aprotic organic solvent; B) drying the film formed in step A) until it is self-supporting; C) treating the film obtained in step B) with a treatment liquid at a temperature in the range from room temperature to the boiling point of the treatment liquid; D) drying and/or dabbing the film treated according to step C) to remove the treatment liquid from step C); and E) doping the film treated according to step D) with a doping agent.
摘要:
The present invention relates to a novel polymer film and also polymer fibers and polymers based on polyazoles, which can, owing to its excellent chemical and thermal properties, be used for a variety of purposes and is particularly useful as film or membrane for gas purification and filtration.
摘要:
The present invention relates to an asymmetric polymer film, in particular based on polazoles, a method for the production of the same and its use. The polyazole-based asymmetric polymer film according to the invention has a smooth and a rough side and enables, on account of its asymmetric structure, rapid and homogeneous doping with acids to form a proton-conducting membrane. The polyazole-based asymmetric polymer film according to the invention can be used in diverse ways on account of its excellent chemical, thermal and mechanical properties and is particularly suitable for the production of polymer electrolyte membranes (PEM) for so-called PEM fuel cells.
摘要:
The present invention relates to a method of preparing a solution of a polymer comprising recurring azole units, which comprises dissolving a sufficiently dried polymer comprising recurring azole units of the formula where the radicals Ar, Ar1 and Ar2 are tetravalent, divalent or trivalent aromatic or heteroaromatic groups and the radicals X, which are identical within a repeating unit, are each an oxygen atom, a sulfur atom or an amino group bearing a hydrogen atom, a group having 1–20 carbon atoms, preferably a branched or unbranched alkyl or alkoxy group, or an aryl group as further radical, in N,N-dimethylacetamide having a sufficiently low water content at a temperature above room temperature under an inert gas atmosphere, wherein a sufficiently dried polymer comprising recurring azole units of the formula (1) or (2) of which 90% by weight based on the total weight of the polymer comprising recurring azole units has a particle size of less than 1 mm is used.
摘要:
In a device for filtering and separating fluids, a plurality of disc-like spaced flow guide elements are disposed in a stack in spaced relationship with filter elements disposed in the spaces between the flow guide elements to which fluid can be supplied through inlet openings to flow over the surfaces of the filter elements. Each flow guide element defines at one end a flow opening for the passage of fluid and at least one channel formed in the flow guide element so as to extend adjacent the opening in a direction transverse to the flow of the fluid from the opening into the space between the flow guide elements to promote fluid flow distribution over the width of the flow path through the device.
摘要:
The present invention relates to polymer films and a polymer membrane having an improved mechanical property profile produced therefrom, to a process for producing them and to their use. The polymer films, polymer membranes and separation membranes of the invention are produced from selected polymer raw materials and have excellent chemical, thermal. and mechanical properties as are required for use as polymer electrolyte membranes (PEMs) in PEM fuel cells or in apparatuses for the filtration and/or separation of gases and/or liquids or for reverse osmosis.
摘要:
The present invention relates to an acid-doped polymer membrane based on polyazoles. The acid-doped polymer membrane can be used in a variety of applications because of its excellent mechanical properties and is useful as polymer electrolyte membrane (PEM) in PEM fuel cells. A doped polymer membrane based on polyazoles is obtained by a process comprising the steps of: A) casting a film using a solution of polymers based on polyazoles in a polar, aprotic organic solvent; B) drying the film formed in step A) until it is self-supporting; C) treating the film obtained in step B) with a treatment liquid at a temperature in the range from room temperature to the boiling point of the treatment liquid; D) drying and/or dabbing the film treated according to step C) to remove the treatment liquid from step C); and E) doping the film treated according to step D) with a doping agent.
摘要:
The present invention relates to a novel polymer film and also polymer fibers and polymers based on polyazoles, which can, owing to its excellent chemical and thermal properties, be used for a variety of purposes and is particularly useful as film or membrane for gas purification and filtration.
摘要:
The present invention relates to an acid-doped polymer membrane based on polyazoles. The acid-doped polymer membrane can be used in a variety of applications because of its excellent mechanical properties and is useful as polymer electrolyte membrane (PEM) in PEM fuel cells. A doped polymer membrane based on polyazoles is obtained by a process comprising the steps of: A) casting a film using a solution of polymers based on polyazoles in a polar, aprotic organic solvent; B) drying the film formed in step A) until it is self-supporting; C) treating the film obtained in step B) with a treatment liquid at a temperature in the range from room temperature to the boiling point of the treatment liquid; D) drying and/or dabbing the film treated according to step C) to remove the treatment liquid from step C); and E) doping the film treated according to step D) with a doping agent.
摘要:
The present invention relates to an asymmetric polymer film, in particular based on polazoles, a method for the production of the same and its use. The polyazole-based asymmetric polymer film according to the invention has a smooth and a rough side and enables, on account of its asymmetric structure, rapid and homogeneous doping with acids to form a proton-conducting membrane. The polyazole-based asymmetric polymer film according to the invention can be used in diverse ways on account of its excellent chemical, thermal and mechanical properties and is particularly suitable for the production of polymer electrolyte membranes (PEM) for so-called PEM fuel cells.