Abstract:
An electrode and an electrode material for lithium electrochemical cells are disclosed. The electrode material is in powder form and has a particle size distribution wherein the measured particle size distribution of the electrode material has a median size D50 ranging from 1.5 μm and 3 μm, a D10≧0.5 μm, a D90≦10.0 μm, and a calculated ratio (D90/D10)/D50≧3.0 which is indicative of a peak of the measured particle size distribution on the left of the median D50 which improves the loading and energy density of the electrode produced with this electrode material powder.
Abstract:
A process for making an electrode sheet for lithium electrochemical cells is disclosed. The process comprises the steps of: a) admixing a polyether polymer or copolymer soluble in water, at least one lithium salt, at least one electrochemically active material, water and an organic solvent miscible with water in a water/organic solvent ratio of a maximum of 50% organic solvent by volume to form a water-based solution/suspension containing by weight at least 20% active electrode material, at least 5% of a polyether polymer or copolymer, and at least 1.5% lithium salt; b) coating the water-based solution/suspension in the form of an electrode thin film onto an electrode support; and, c) drying the electrode thin film to obtain an electrode thin sheet having less than 1000 ppm of residual water.
Abstract:
A process for making an electrode sheet for a solid lithium electrochemical cells is disclosed. The process comprises the steps of: a) admixing a polyether polymer or copolymer, at least one lithium salt, at least one electrochemically active material and purified water to form an aqueous solution/suspension containing by weight at least 40% purified water, at least 20% active electrode material, up to 10% electrically conductive material, at least 5% polyether polymer or copolymer, and at least 1.5% lithium salt; b) coating the aqueous solution/suspension in the form of an electrode thin film onto an electrode support; and, c) evaporating the water from the electrode thin film to obtain an electrode sheet having less than 1000 ppm of residual water. The evaporation step is preferably carried out through a dryer/oven tunnel having incremental drying zones.
Abstract:
A process for making an electrode sheet for lithium electrochemical cells is disclosed. The process comprises the steps of: a) admixing a polyether polymer or copolymer soluble in water, at least one lithium salt, at least one electrochemically active material, water and an organic solvent miscible with water in a water/organic solvent ratio of a maximum of 50% organic solvent by volume to form a water-based solution/suspension containing by weight at least 20% active electrode material, at least 5% of a polyether polymer or copolymer, and at least 1.5% lithium salt; b) coating the water-based solution/suspension in the form of an electrode thin film onto an electrode support; and, c) drying the electrode thin film to obtain an electrode thin sheet having less than 1000 ppm of residual water.
Abstract:
An electrode and an electrode material for lithium electrochemical cells are disclosed. The electrode material is in powder form and has a particle size distribution wherein the measured particle size distribution of the electrode material has a median size D50 ranging from 1.5 μm and 3 μm, a D10≧0.5 μm, a D90≦10.0 μm, and a calculated ratio (D90/D10)/D50≧3.0 which is indicative of a peak of the measured particle size distribution on the left of the median D50 which improves the loading and energy density of the electrode produced with this electrode material powder.
Abstract:
A process for making an electrode sheet for a solid lithium electrochemical cells is disclosed. The process comprises the steps of: a) admixing a polyether polymer or copolymer, at least one lithium salt, at least one electrochemically active material and purified water to form an aqueous solution/suspension containing by weight at least 40% purified water, at least 20% active electrode material, up to 10% electrically conductive material, at least 5% polyether polymer or copolymer, and at least 1.5% lithium salt; b) coating the aqueous solution/suspension in the form of an electrode thin film onto an electrode support; and, c) evaporating the water from the electrode thin film to obtain an electrode sheet having less than 1000 ppm of residual water. The evaporation step is preferably carried out through a dryer/oven tunnel having incremental drying zones.
Abstract:
A solid polymer electrolyte for a battery is disclosed. The solid polymer electrolyte includes a first polymer capable of solvating a lithium salt, a lithium salt, and a second polymer which is at least partially miscible with the first polymer or rendered at least partially miscible with the first polymer; at least a portion of_the second polymer being crystalline or vitreous at the internal operating temperature of the battery.