公开(公告)号：US08247392B2

公开(公告)日：2012-08-21

申请号：US10485935

申请日：2002-07-19

申请人： François Jerome ,  Géraud Dubois ,  Stéphane Brandes ,  Gabriel Canard ,  Jean-Michel Barbe ,  Roger Guilard ,  Bruno Roux-Fouillet ,  Henry Ledon

发明人： François Jerome ,  Géraud Dubois ,  Stéphane Brandes ,  Gabriel Canard ,  Jean-Michel Barbe ,  Roger Guilard ,  Bruno Roux-Fouillet ,  Henry Ledon

IPC分类号： C07D487/22

CPC分类号： C07D487/22 ,  B01D53/02 ,  B01D2257/502 ,  B01J20/103 ,  B01J20/223 ,  B01J20/28083 ,  B01J20/3204 ,  B01J20/3217 ,  B01J20/3219 ,  B01J20/3257 ,  B01J20/3259 ,  B01J20/3261 ,  B01J20/3265 ,  C01B3/56 ,  C01B13/0262 ,  C01B2203/042 ,  C01B2203/047 ,  C01B2210/005 ,  C07F7/1804 ,  C07F15/025 ,  C07F15/065

摘要： Compounds of formula (I) are disclosed. The tetrapyrole ring in formula (I) can be substituted with a metal cation (M); R1, R2, R3 and R4 separately represent a hydrogen atom, a C1-4 alkyl or alkyloxy radical, or a phenyl radical optionally substituted by vinyl, hydroxy, nitro, amino, bromo, chloro, fluoro, iodo, benzyloxy, or hydroxymethyl radicals; R5, R6, R7 and R8 separately represent a hydrogen atom or a C1-4 alkyl radical; Ra, Rb and Rc separately represent a hydrogen atom, a C1-4 alkyl or alkyloxy radical optionally substituted by a halogen, or a phenyl radical optionally substituted by vinyl, hydroxy, nitro, amino, bromo, chloro, fluoro, iodo, benzyloxy, or hydroxymethyl radicals, wherein at least one of Ra, Rb, and Rc is a phenyl radical. Compounds of formula (I) bound to a silica, a sol-gel material or a mesoporous silica are useful for selective trapping of carbon monoxide.

摘要翻译： 公开了式（I）的化合物。 式（I）中的四氟环可以被金属阳离子（M）取代; R1，R2，R3和R4分别表示氢原子，C1-4烷基或烷氧基，或任选被乙烯基，羟基，硝基，氨基，溴，氯，氟，碘，苄氧基或羟甲基取代的苯基 ; R5，R6，R7和R8分别表示氢原子或C1-4烷基; Ra，Rb和Rc分别表示氢原子，任选被卤素取代的C 1-4烷基或烷氧基，或任选被乙烯基，羟基，硝基，氨基，溴，氯，氟，碘，苄氧基， 或羟甲基，其中Ra，Rb和Rc中的至少一个是苯基。 与二氧化硅，溶胶 - 凝胶材料或介孔二氧化硅结合的式（I）化合物可用于选择性捕获一氧化碳。

公开(公告)号：US06534649B1

公开(公告)日：2003-03-18

申请号：US09624341

申请日：2000-07-24

申请人： Franck Denat ,  Géraud Dubois ,  Raphaël Tripier ,  Roger Guilard ,  Bruno Roux-Fouillet

发明人： Franck Denat ,  Géraud Dubois ,  Raphaël Tripier ,  Roger Guilard ,  Bruno Roux-Fouillet

IPC分类号： C07F718

CPC分类号： C07F7/18

摘要： Compound of formula (I): in which W1, W2 and W3, which are identical or different, each represent, independently of one another, a divalent radical chosen from those represented by the general formula (A): —[(CT5T6)a—(CT1T2)n—[N(R4)]p—(CT3T4)m—(CT7T8)b]1—  (A) as defined in the description and in which R4 represents a hydrogen atom, an alkyl radical, a [(hetero)aryl]alkyl radical or a radical represented by the general formula (B), R5—Si(X1) (X2) (X3), as defined in the description, and R1, R2 and R3, which are identical or different, each represent, independently of one another and of R4, a hydrogen atom, an alkyl radical, a [(hetero)aryl]alkyl radical comprising from 7 to 12 carbon atoms or a radical represented by the general formula (B), it being understood that the compound of formula (I) comprises more than six cyclic nitrogen atoms.

摘要翻译： 式（I）化合物：其中相同或不同的W 1，W 2和W 3彼此独立地表示选自由通式（A）表示的二价基团：如说明书和 其中R 4表示氢原子，烷基，[（杂）芳基]烷基或由通式（B）表示的基团，R5-Si（X1）（X2）（X3） 描述和相同或不同的R 1，R 2和R 3各自彼此独立地表示和R 4表示氢原子，烷基，含有7至12个碳原子的[（杂）芳基]烷基 或由通式（B）表示的基团，应理解式（I）化合物包含六个以上的环状氮原子。