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1.发明申请Use of copolymerizable sulfonate salts to promote char formation in polyesters and copolyesters 审中-公开使用可共聚磺酸盐促进聚酯和共聚酯中的炭的形成公开(公告)号：US20080167440A1
公开(公告)日：2008-07-10
申请号：US11651816
申请日：2007-01-10
申请人： Deanna L. Pickel , Marc Alan Strand , Gether Irick , Douglas Stephens McWilliams , Michael Eugene Donelson
发明人： Deanna L. Pickel , Marc Alan Strand , Gether Irick , Douglas Stephens McWilliams , Michael Eugene Donelson
IPC分类号： C08G63/688
CPC分类号： C08J5/18 , C08G63/6886 , C08J2367/02
摘要： comonomers have been shown to improve flammability characteristics of polyesters and copolyesters. Incorporation of sulfonate containing monomers such as 5-sodiosulfoisophthalic acid significantly decreases the heat release capacity of copolyesters. These comonomers also increase the formation of char as measured by thermogravimetric analysis. The decrease in the heat release capacity and increase in char formation indicates that these compositions may have reduced flammability and thus are useful for producing products have reduced flammability. In particular, it has also been demonstrated that incorporation of as little as 0.1 mole % 5-sodiosulfoisophthalic acid to a polyester or copolyester significantly increases the char formation independent of composition.
摘要翻译： 已经显示共聚单体改善聚酯和共聚酯的可燃性特征。 含有磺酸盐的单体如5-硫代磺基间苯二甲酸的引入显着降低了共聚酯的放热能力。 这些共聚单体还通过热重分析测量，增加炭的形成。 热释放能力的降低和焦炭形成的增加表明这些组合物可能具有降低的可燃性，因此可用于生产具有降低的可燃性的产品。 特别地，还已经证明，将少至0.1摩尔％的5-磺基二磺酰基间苯二甲酸掺入聚酯或共聚酯中显着地增加了与组成无关的焦炭形成。
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公开(公告)号：US5970988A
公开(公告)日：1999-10-26
申请号：US533218
申请日：1995-09-25
申请人： Charles M. Buchanan , Robert M. Gardner , James E. Harris , Gether Irick, Jr. , David V. Strickler, Jr.
发明人： Charles M. Buchanan , Robert M. Gardner , James E. Harris , Gether Irick, Jr. , David V. Strickler, Jr.
摘要： This invention provides cellulose ester fibers having an intermediate degree of substitution per anhydroglucose unit (DS/AGU) along with pigments which act as photooxidation catalysts. The fibers are useful as filter materials for tobacco products. The filter materials thus provided are easily dispersible and biodegradable and do not persist in the environment.
摘要翻译： 本发明提供了每个脱水葡萄糖单元（DS / AGU）具有中等取代度的纤维素酯纤维以及用作光氧化催化剂的颜料。 纤维可用作烟草制品的过滤材料。 由此提供的过滤材料易于分散和可生物降解，并且不会在环境中持续存在。
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公开(公告)号：US5359134A
公开(公告)日：1994-10-25
申请号：US930887
申请日：1992-08-14
申请人： Bruce L. Gustafson , Charles E. Sumner, Jr. , Michael Bellas , Gether Irick, Jr. , Dewey W. Fuller, Jr. , Ernest W. Arnold , Eric J. Fugate
发明人： Bruce L. Gustafson , Charles E. Sumner, Jr. , Michael Bellas , Gether Irick, Jr. , Dewey W. Fuller, Jr. , Ernest W. Arnold , Eric J. Fugate
IPC分类号： B01J27/128 , B01J29/08 , B01J31/04 , C07C51/265 , C07C51/43 , C07C63/26
CPC分类号： C07C51/265
摘要： Provided is a facile three step process for preparing 2-phenylterephthalic acid starting with p-xylene, followed by alkylation, dehydrogenation, and oxidation of the methyl groups corresponding to the origional p-xylene. The product, 2-phenylterephthalic acid, is useful as an intermediate in the synthesis of polyesters comprised of residues of 2-phenylterephthalic acid.
摘要翻译： 提供了一种从对二甲苯开始制备2-苯基对苯二甲酸，然后进行对应于原始对二甲苯的甲基的烷基化，脱氢和氧化的简便的三步法。 产物2-苯基对苯二甲酸可用作合成由2-苯基对苯二甲酸残基组成的聚酯的中间体。
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公开(公告)号：US5286903A
公开(公告)日：1994-02-15
申请号：US993537
申请日：1992-12-21
CPC分类号： C07C51/09
摘要： Disclosed are processes for the preparation of cyclohexanedicarboxylic acids by the non-catalytic hydrolysis or acidolysis of dialkyl cyclohexanedicarboxylate esters. The processes provide a means for converting dialkyl cyclohexanedicarboxylate esters to cyclohexanedicarboxylic acids without the co-production of solid by-products which present disposal problems.
摘要翻译： 公开了通过非催化水解或酸解二烷基环己烷二羧酸酯来制备环己烷二羧酸的方法。 这些方法提供了将二烷基环己烷二羧酸酯转化成环己烷二羧酸而不共同生产出现处置问题的固体副产物的方法。
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5.发明授权Bichromophoric benzotriazole-styrene ester ultraviolet stabilizers and their use in organic compositions 失效双色荧光苯并三唑 - 苯乙烯酯紫外线稳定剂及其在有机组合物中的应用
公开(公告)号：US4235999A
公开(公告)日：1980-11-25
申请号：US43861
申请日：1979-05-29
IPC分类号： C07D249/20 , C08K5/3475
CPC分类号： C07D249/20 , C08K5/3475
摘要： The invention relates to bichromophoric benzotriazole-styrene ester compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing a stabilizing amount of the bichromophoric composition to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may also be incorporated into the organic compositions in the polymer melt or dissolved in the polymer dope, coated on the exterior of the molded article, film or extruded fiber.
摘要翻译： 本发明涉及已被发现是有效的紫外线稳定剂的双色性苯并三唑 - 苯乙烯酯化合物。 本发明还涉及含有稳定量的显色组合物以防止这种降解的紫外可降解有机组合物。 这些稳定剂在通常用于聚合物组合物中的其它添加剂的存在下是有效的，包括例如颜料，着色剂，填料，增强剂等。 这些紫外线稳定剂也可以掺入聚合物熔体中的有机组合物中或溶解在聚合物涂料中，涂覆在模塑制品，薄膜或挤出纤维的外部上。
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公开(公告)号：US4216137A
公开(公告)日：1980-08-05
申请号：US912632
申请日：1978-06-05
IPC分类号： C08K5/5399 , C08L23/02 , C08K5/51 , C08L23/06 , C08L23/12
CPC分类号： C08L23/02 , C08K5/5399 , C08L23/06 , C08L23/10 , C08L57/02
摘要： Polyolefins are rendered resistant to degradation upon exposure to heat by incorporating therein a stabilizing amount of a synergistic combination of a phenol-terpene resin, a sulfur-containing secondary antioxidant and a phosphonitrilic composition derived rom a phosphonitrilic halide and certain hydroxy compounds. The above synergistic combination is especially effective for stabilizing polyolefins containing carbon black.
摘要翻译： 通过在其中加入稳定量的苯酚 - 萜烯树脂，含硫次级抗氧化剂和由膦酰基卤化物衍生的膦酸组合物和某些羟基化合物的协同组合，使聚烯烃暴露于耐热降解。 上述协同组合对于稳定含有炭黑的聚烯烃特别有效。
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7.发明授权Multiheterocyclic ultraviolet stabilizers and their use in organic compositions 失效多杂环紫外线稳定剂及其在有机组合物中的应用
公开(公告)号：US4187213A
公开(公告)日：1980-02-05
申请号：US868087
申请日：1978-01-09
IPC分类号： C07D401/12 , C07D413/12 , C07D417/12 , C08K5/353 , C07D213/28 , C07D213/36 , C07D213/89 , C08K5/35
CPC分类号： C07D417/12 , C07D401/12 , C07D413/12 , C08K5/353
摘要： The invention relates to multiheterocyclic compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing a stabilizing amount of the multiheterocyclic composition to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may also be incorporated into the organic compositions in the polymer melt or dissolved in the polymer dope, coated on the exterior of the molded article, film or extruded fiber.
摘要翻译： 本发明涉及已发现是有效的紫外线稳定剂的多杂环化合物。 本发明还涉及含有稳定量的多杂环组合物以防止这种降解的紫外可降解有机组合物。 这些稳定剂在通常用于聚合物组合物中的其它添加剂的存在下是有效的，包括例如颜料，着色剂，填料，增强剂等。 这些紫外线稳定剂也可以掺入聚合物熔体中的有机组合物中或溶解在聚合物涂料中，涂覆在模塑制品，薄膜或挤出纤维的外部上。
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公开(公告)号：US4159270A
公开(公告)日：1979-06-26
申请号：US857732
申请日：1977-12-05
IPC分类号： C07D249/20 , C08K5/3475 , C08L1/14 , C09K15/30
CPC分类号： C08K5/3475 , C07D249/20 , C08L1/14 , C09K15/30
摘要： The invention relates to bichromophoric benzotriazole-styrene compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing a stabilizing amount of the bichromophoric composition to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ulraviolet stablizers may also be incorporated into the organic compositions in the polymer melt or dissolved in the polymer dope, coated on the exterior of the molded article, film or extruded fiber.
摘要翻译： 本发明涉及已发现是有效的紫外线稳定剂的双色荧光苯并三唑 - 苯乙烯化合物。 本发明还涉及含有稳定量的显色组合物以防止这种降解的紫外可降解有机组合物。 这些稳定剂在通常用于聚合物组合物中的其它添加剂的存在下是有效的，包括例如颜料，着色剂，填料，增强剂等。 这些紫外线稳定剂也可以掺入聚合物熔体中的有机组合物中或溶解在聚合物涂料中，涂覆在模制品，膜或挤出纤维的外部。
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9.发明授权Heterocylic ester, ultraviolet stabilizers and their use in organic compositions 失效异辛酯，紫外线稳定剂及其在有机组合物中的用途
公开(公告)号：US4116928A
公开(公告)日：1978-09-26
申请号：US751632
申请日：1976-12-17
CPC分类号： C08K5/353
摘要： The invention relates to heterocyclic ester compounds which have been found to be extremely effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing an amount of a heterocyclic ester composition to prevent such degradation. These stabilizers are effective in the presence of other additives commonly empolyed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may also be incorporated into the organic compositions such as polymers by adding to the polymer melt or dissolved in the polymer dope, coated on the exterior of the shaped or molded article, film or extruded fiber.
摘要翻译： 本发明涉及已被发现是非常有效的紫外线稳定剂的杂环酯化合物。 本发明还涉及含有一定量的用于防止这种降解的杂环酯组合物的紫外可降解有机组合物。 这些稳定剂在通常在聚合物组合物中赋予的其它添加剂的存在下是有效的，包括例如颜料，着色剂，填料，增强剂等。 这些紫外线稳定剂也可以通过添加到聚合物熔体中或溶解在聚合物涂料中而被包含在有机组合物如聚合物中，涂覆在成形或模制品的外部，膜或挤出纤维上。
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10.发明授权Polyurethane foam stabilized against scorch with a mixture of hydroquinone and a phosphite containing secondary antioxidant 失效聚氨酯泡沫使用氢醌和含有次级抗氧化剂的亚磷酸盐的混合物进行稳定防焦
公开(公告)号：UST968002I4
公开(公告)日：1978-03-07
申请号：US771706
申请日：1977-02-24
CPC分类号： C08J9/0038 , C08J9/0023 , C08J2375/04 , C08K5/13 , C08K5/52 , C08K5/524 , C08L75/04
摘要： polyurethane foams are stabilized against scorching when a mixture of hydroquinone and a phosphite containing secondary antioxidant is present in a foam-forming mixture of an organic polyisocyanate with a polyether polyol in the presence of a reaction catalyst and a foaming agent. The proportion of hydroquinone to the phosphite is in the range of 10:1 to about 1:1. Especially advantageous results can be obtained by adding p,p'-dialkylphenylamines containing between 3 and 18 carbon atoms in the alkyl moiety to the above two stabilizers. When the amine is present the stabilizer mixture usually comprises between about 15 and 90% by weight of the amine and the rest of the stabilizer comprises the hydroquinone and the phosphite in the range relative to each other as given above. The proportion of the stabilizer mixture is usually between about 10 and about 50,000 parts per million parts of the polyether polyol. The stabilizer mixture is preferably mixed with the polyol before using the polyol in making urethane foams.
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