Membrane-electrode assembly for solid polymer electrolyte fuel cell
    1.
    发明授权
    Membrane-electrode assembly for solid polymer electrolyte fuel cell 有权
    固体聚合物电解质燃料电池膜电极组件

    公开(公告)号:US08273499B2

    公开(公告)日:2012-09-25

    申请号:US12474828

    申请日:2009-05-29

    IPC分类号: H01M8/10

    摘要: A membrane-electrode assembly for a solid polymer electrolyte fuel cell is provided that uses a proton conductive membrane having high proton conductivity and also superior heat resistance and chemical durability. A membrane-electrode assembly for a solid polymer electrolyte fuel cell is provided with an anode on one side of a proton conductive membrane and a cathode on another side thereof, and the proton conductive membrane is a sulfonated polyarylene containing a structure expressed by the general formula (1) below: —Rs—Z—Rh  (1) In the formula (1), Z represents at least one structure selected from the group consisting of —CO—, —SO2—, and —SO—; Rs represents a direct bond or any divalent organic group; and Rh represents a nitrogen-containing heterocyclic group.

    摘要翻译: 提供了一种固体聚合物电解质燃料电池的膜 - 电极组件,其使用具有高质子传导性和优异的耐热性和化学耐久性的质子传导膜。 用于固体聚合物电解质燃料电池的膜 - 电极组件在质子传导膜的一侧和另一侧的阴极上设置有阳极,质子传导膜是含有由通式表示的结构的磺化聚亚芳基 (1)-Rs-Z-Rh(1)式(1)中,Z表示选自-CO - , - SO 2 - 和-SO - 的至少一种结构。 Rs表示直接键或任何二价有机基团; 而Rh表示含氮杂环基。

    Poly(arylenebenzimidazole) polymers and copolymers
    5.
    发明授权
    Poly(arylenebenzimidazole) polymers and copolymers 失效
    聚(亚芳基苯并咪唑)聚合物和共聚物

    公开(公告)号:US07696298B2

    公开(公告)日:2010-04-13

    申请号:US12230626

    申请日:2008-09-02

    IPC分类号: C08G65/40 C08G75/00

    摘要: Polymers and copolymers of formula I: in which m is typically 30 to 500 and n is 0 to 500; Ar is for example, 1,2-phenylene, 1,3-phenylene, 1,4-phenylene, or 2,6-pyridylene; Ar2 and Ar3 are selected from various bivalent aryl and heteroaryl groups; and X is for example, the bivalent SO2 or CO. have high temperature properties which make them useful as films, matrices in carbon fiber reinforced composites and high performance adhesives; processes for preparing the polymers and copolymers employ a novel C—N coupling reaction.

    摘要翻译: 式I的聚合物和共聚物:其中m通常为30〜500,n为0〜500; Ar例如为1,2-亚苯基,1,3-亚苯基,1,4-亚苯基或2,6-亚吡啶; Ar2和Ar3选自各种二价芳基和杂芳基; X为例如二价SO 2或CO具有高温性能,可用作碳纤维增强复合材料中的膜,基体和高性能粘合剂; 制备聚合物和共聚物的方法采用新的C-N偶联反应。

    High temperature poly(aryl ether)s containing a phthalazinone moiety
    6.
    发明申请
    High temperature poly(aryl ether)s containing a phthalazinone moiety 审中-公开
    含有酞嗪酮部分的高温聚(芳基醚)

    公开(公告)号:US20070238853A1

    公开(公告)日:2007-10-11

    申请号:US11728929

    申请日:2007-03-27

    IPC分类号: C08G75/00

    CPC分类号: C08G65/4037 C08G75/23

    摘要: A poly(phthalazinone sulfone) composition for molded articles having such characteristics as high temperature resistance, good electrical properties, good chemical and solvent resistance and toughness consists essentially of a polymer of formula (I): Cp-ZxA-Zy   (I) wherein Z is a bisphenyl sulfone moiety of formula: (II): A is a phthalazinone moiety of formula (III): Cp is A, as defined above, or a biphenol moiety of formula (IV): x is an integer of at least 1; y is an integer of at least 1; and x+y=n, where n is an integer such that the polymer has a weight average molecular weight of about 20,000 to about 170,000, the composition comprising less than 5%, by weight, of low molecular weight oligomers; and having a glass transition temperature (Tg) from 225 to 305° C.

    摘要翻译: 具有耐高温性,良好的电性能,良好的耐化学性和耐溶剂性和韧性等特性的用于模塑制品的聚(酞嗪酮砜)组合物基本上由式(I)的聚合物组成: 在线公式“end =”lead“?>Cp-Zy y y <<<<<<<<<<<<<<<<<

    Polymers derived from phenolphthaleins
    7.
    发明授权
    Polymers derived from phenolphthaleins 失效
    衍生自酚酞的聚合物

    公开(公告)号:US5237062A

    公开(公告)日:1993-08-17

    申请号:US931310

    申请日:1992-08-18

    申请人: Allan S. Hay

    发明人: Allan S. Hay

    摘要: Homopolymers and copolymers with high Tg's are produced from phthalazones which in turn are produced from phenolphthalein as a readily available starting material; the homopolymers may be represented by formula (IX): ##STR1## wherein R.sub.1 and R.sub.2, which may be the same or different, are selected from hydrogen, fluorine, phenyl and fluorophenyl, each m, which may be the same or different, is an integer of 0, 1, 2, 3 or 4, and n is an integer of 2 to 200. Novel phenyl substituted phenolphthaleins and novel hydroxybenzoylbenzoic acids, as well as novel phthalazones, all of which may be employed in the preparation of homopolymers and copolymers of the invention, are also provided.

    摘要翻译: 具有高Tg值的均聚物和共聚物是由酞嗪酮制得的,它们又由酚酞作为容易获得的原料制成; 均聚物可以由式(IX)表示:均聚物(IX):其中R 1和R 2可以相同或不同,选自氢,氟,苯基和氟苯基,每个m,其中 可以相同或不同,为0,1,2,3或4的整数,n为2至200的整数。新的苯基取代酚酞和新型羟基苯甲酰基苯甲酸以及新的酞嗪酮,它们都可以 也用于制备本发明的均聚物和共聚物。

    Bisphenols and poly(imidoarylether ketone)s and poly(imidoarylether
sulfone)s produced therefrom
    8.
    发明授权
    Bisphenols and poly(imidoarylether ketone)s and poly(imidoarylether sulfone)s produced therefrom 失效
    双酚和聚(亚胺基醚酮)和由其生产的聚(亚氨基醚醚)

    公开(公告)号:US5169923A

    公开(公告)日:1992-12-08

    申请号:US798577

    申请日:1991-11-26

    摘要: Bisphenols having a pendent imide moiety, of formula (I) ##STR1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, are selected from hydrogen, fluorine, chlorine, bromine, alkyl of 1 to 6 carbon atoms, aryl of 6 to 10 carbon atoms, alkoxy of 1 to 6 carbon atoms and aryloxy of 6 to 10 carbon atoms; R.sub.5 is selected from fluorine, chlorine, bromine and alkyl of 1 to 6 carbon atoms, and m is 0, 1, 2, 3 or 4; and R.sub.7 is alkyl of 1 to 18 carbon atoms, aryl of 6 to 10 carbon atoms, unsubstituted or substituted one or more times by a substituent selected from fluorine, chlorine, trifluoromethyl, alkyl of 1 to 6 carbon atoms, and phenyl, or heteroaryl; are useful in producing poly(imidoarylether ketone)s and poly(-imidoarylether sulfone)s which are amorphous and are soluble in readily available solvents, while displaying high glass transition temperatures and good thermo-oxidative stability.

    摘要翻译: 具有式(I)的侧酰亚胺部分的双酚,其中可以相同或不同的R 1,R 2,R 3和R 4选自氢,氟,氯,溴,1 6个碳原子的芳基,6至10个碳原子的芳基,1至6个碳原子的烷氧基和6至10个碳原子的芳氧基; R5选自氟,氯,溴和1至6个碳原子的烷基,m为0,1,2,3或4; 并且R 7是1至18个碳原子的烷基,6至10个碳原子的芳基,未被取代或被选自氟,氯,三氟甲基,1至6个碳原子的烷基取代或取代一次或多次,以及苯基或杂芳基 ; 可用于生产聚(亚胺基醚酮)和聚(亚氨基醚基砜),它们是无定形的并且易溶于易溶剂,同时显示出高的玻璃化转变温度和良好的热氧化稳定性。

    Bisphenols and poly(imidoarylether ketone)s and poly(imidoarylether
sulfone)s produced therefrom
    9.
    发明授权
    Bisphenols and poly(imidoarylether ketone)s and poly(imidoarylether sulfone)s produced therefrom 失效
    双酚和聚(亚胺基醚酮)和由其生产的聚(亚氨基醚醚)

    公开(公告)号:US5110934A

    公开(公告)日:1992-05-05

    申请号:US704930

    申请日:1991-05-23

    摘要: Bisphenols having a pendent imide moiety, of formula (I) ##STR1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, are selected from hydrogen, fluorine, chlorine, bromine, alkyl of 1 to 6 carbon atoms, aryl of 6 to 10 carbon atoms, alkoxy of 1 to 6 carbon atoms and aryloxy of 6 to 10 carbon atoms; R.sub.5 is selected from fluorine, chlorine, bromine and alkyl of 1 to 6 carbon atoms, and m is 0, 1, 2, 3 or 4; and R.sub.7 is alkyl of 1 to 18 carbon atoms, aryl of 6 to 10 carbon atoms, unsubstituted or substituted one or more times by a substituent selected from fluorine, chlorine, trifluoromethyl, alkyl of 1 to 6 carbon atoms, and phenyl, or heteroaryl; are useful in producing poly(imidoarylether ketone)s and poly(imidoarylether sulfone)s which are amorphous and are soluble in readily available solvents, while displaying high glass transition temperatures and good thermo-oxidative stability.

    摘要翻译: 具有式(I)的侧酰亚胺部分的双酚,其中可以相同或不同的R 1,R 2,R 3和R 4选自氢,氟,氯,溴,1 6个碳原子的芳基,6至10个碳原子的芳基,1至6个碳原子的烷氧基和6至10个碳原子的芳氧基; R5选自氟,氯,溴和1至6个碳原子的烷基,m为0,1,2,3或4; 并且R 7是1至18个碳原子的烷基,6至10个碳原子的芳基,未被取代或被选自氟,氯,三氟甲基,1至6个碳原子的烷基取代或取代一次或多次,以及苯基或杂芳基 ; 可用于生产聚(酰亚胺基醚酮)和聚(酰亚胺基醚砜),它们是无定形的并且易溶于易于获得的溶剂,同时显示出高的玻璃化转变温度和良好的热氧化稳定性。