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公开(公告)号：US06666935B1
公开(公告)日：2003-12-23
申请号：US08926357
申请日：1997-09-09
申请人： Randall L. Simpson , Ronald S. Lee , Thomas M. Tillotson , Lawrence W. Hrubesh , Rosalind W. Swansiger , Glenn A. Fox
发明人： Randall L. Simpson , Ronald S. Lee , Thomas M. Tillotson , Lawrence W. Hrubesh , Rosalind W. Swansiger , Glenn A. Fox
IPC分类号： C06B4510
CPC分类号： C06B21/0066 , B01J13/0091 , C06B21/0091 , C06B45/00 , Y02P20/544 , Y10S977/70 , Y10S977/775 , Y10S977/835 , Y10S977/895 , Y10S977/896
摘要： Sol-gel chemistry is used for the preparation of energetic materials (explosives, propellants and pyrotechnics) with improved homogeneity, and/or which can be cast to near-net shape, and/or made into precision molding powders. The sol-gel method is a synthetic chemical process where reactive monomers are mixed into a solution, polymerization occurs leading to a highly cross-linked three dimensional solid network resulting in a gel. The energetic materials can be incorporated during the formation of the solution or during the gel stage of the process. The composition, pore, and primary particle sizes, gel time, surface areas, and density may be tailored and controlled by the solution chemistry. The gel is then dried using supercritical extraction to produce a highly porous low density aerogel or by controlled slow evaporation to produce a xerogel. Applying stress during the extraction phase can result in high density materials. Thus, the sol-gel method can be used for precision detonator explosive manufacturing as well as producing precision explosives, propellants, and pyrotechnics, along with high power composite energetic materials.
摘要翻译： 溶胶 - 凝胶化学物质用于制备具有改进的均匀性的高能材料（爆炸物，推进剂和烟火），和/或可以铸造成近净形状和/或制成精密成型粉末。 溶胶 - 凝胶法是将反应性单体混合到溶液中的合成化学方法，发生聚合，导致高度交联的三维固体网络，导致凝胶。 高能材料可以在溶液形成期间或在该过程的凝胶阶段期间被引入。 组合物，孔和一次粒径，凝胶时间，表面积和密度可以通过溶液化学定制和控制。 然后使用超临界萃取干燥凝胶以产生高度多孔的低密度气凝胶或通过受控的缓慢蒸发以产生干凝胶。 在提取阶段施加应力可导致高密度材料。 因此，溶胶 - 凝胶法可用于精密雷管炸药制造，以及生产精密炸药，推进剂和烟火以及大功率复合材料。
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公开(公告)号：US06402960B1
公开(公告)日：2002-06-11
申请号：US09513549
申请日：2000-02-25
IPC分类号： C02F156
CPC分类号： C02F1/683 , B01J20/26 , B01J45/00 , C02F1/285 , C02F1/64 , C02F2101/20 , C02F2303/16 , Y10S210/914
摘要： Thiacrown polymers immobilized to a polystyrene-divinylbenzene matrix react with Hg2+ under a variety of conditions to efficiently and selectively remove Hg2+ ions from acidic aqueous solutions, even in the presence of a variety of other metal ions. The mercury can be recovered and the polymer regenerated. This mercury removal method has utility in the treatment of industrial wastewater, where a selective and cost-effective removal process is required.
摘要翻译： 固定在聚苯乙烯 - 二乙烯基苯基质上的硫辛聚合物在各种条件下与Hg2 +反应，即使在各种其它金属离子存在下也能有效地和选择性地从酸性水溶液中除去Hg2 +离子。 可以回收汞并且聚合物再生。 这种除汞方法在工业废水的处理中具有应用价值，需要选择性和成本有效的去除工艺。
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3.发明授权公开(公告)号：US06924322B2
公开(公告)日：2005-08-02
申请号：US10393492
申请日：2003-03-18
申请人： Glenn A. Fox , Thomas M. Tillotson
发明人： Glenn A. Fox , Thomas M. Tillotson
CPC分类号： B01J13/0091
摘要： An organic aerogel or xerogel formed by a sol-gel reaction using starting materials that exhibit similar reactivity to the most commonly used resorcinol starting material. The new starting materials, including thio-, amine- and nitro-containing molecules and functionalized macrocyclic molecules will produce organic xerogels and aerogels that have improved performance in the areas of detection and sensor technology, as well as water stream remediation. Also, further functionalization of these new organic aerogels or xerogels will yield material that can be extracted with greater facility than current organic aerogels.
摘要翻译： 使用与最常用的间苯二酚起始材料具有相似反应性的起始材料通过溶胶 - 凝胶反应形成的有机气凝胶或干凝胶。 新的起始材料，包括含硫，胺和硝基的分子和官能化的大环分子将产生有机干凝胶和气凝胶，其在检测和传感器技术以及水流修复领域具有改进的性能。 此外，这些新的有机气凝胶或干凝胶的进一步功能化将产生可以比当前有机气凝胶更大的设备提取的材料。
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公开(公告)号：US08075716B1
公开(公告)日：2011-12-13
申请号：US09481043
申请日：2000-01-11
申请人： Randall L. Simpson , Ronald S. Lee , Thomas M. Tillotson , Lawrence W. Hrubesh , Rosalind W. Swansiger , Glenn A. Fox
发明人： Randall L. Simpson , Ronald S. Lee , Thomas M. Tillotson , Lawrence W. Hrubesh , Rosalind W. Swansiger , Glenn A. Fox
IPC分类号： C06B45/00
CPC分类号： C06B45/00 , Y02P20/544
摘要： Sol-gel chemistry is used for the preparation of energetic materials (explosives, propellants and pyrotechnics) with improved homogeneity, and/or which can be cast to near-net shape, and/or made into precision molding powders. The sol-gel method is a synthetic chemical process where reactive monomers are mixed into a solution, polymerization occurs leading to a highly cross-linked three dimensional solid network resulting in a gel. The energetic materials can be incorporated during the formation of the solution or during the gel stage of the process. The composition, pore, and primary particle sizes, gel time, surface areas, and density may be tailored and controlled by the solution chemistry. The gel is then dried using supercritical extraction to produce a highly porous low density aerogel or by controlled slow evaporation to produce a xerogel. Applying stress during the extraction phase can result in high density materials. Thus, the sol-gel method can be used for precision detonator explosive manufacturing as well as producing precision explosives, propellants, and pyrotechnics, along with high power composite energetic materials.
摘要翻译： 溶胶 - 凝胶化学物质用于制备具有改进的均匀性的高能材料（爆炸物，推进剂和烟火），和/或可以铸造成近净形状和/或制成精密成型粉末。 溶胶 - 凝胶法是将反应性单体混合到溶液中的合成化学方法，发生聚合，导致高度交联的三维固体网络，导致凝胶。 高能材料可以在溶液形成期间或在该过程的凝胶阶段期间被引入。 组合物，孔和一次粒径，凝胶时间，表面积和密度可以通过溶液化学定制和控制。 然后使用超临界萃取干燥凝胶以产生高度多孔的低密度气凝胶或通过受控的缓慢蒸发以产生干凝胶。 在提取阶段施加应力可导致高密度材料。 因此，溶胶 - 凝胶法可用于精密雷管炸药制造，以及生产精密炸药，推进剂和烟火以及大功率复合材料。
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公开(公告)号：US06893518B1
公开(公告)日：2005-05-17
申请号：US10697477
申请日：2003-10-29
申请人： Randall L. Simpson , Ronald S. Lee , Thomas M. Tillotson , Lawrence W. Hrubesh , Rosalind W. Swansiger , Glenn A. Fox
发明人： Randall L. Simpson , Ronald S. Lee , Thomas M. Tillotson , Lawrence W. Hrubesh , Rosalind W. Swansiger , Glenn A. Fox
CPC分类号： C06B21/0066 , B01J13/0091 , C06B21/0091 , C06B45/00 , Y02P20/544 , Y10S977/70 , Y10S977/775 , Y10S977/835 , Y10S977/895 , Y10S977/896
摘要： Sol-gel chemistry is used for the preparation of energetic materials (explosives, propellants and pyrotechnics) with improved homogeneity, and/or which can be cast to near-net shape, and/or made into precision molding powders. The sol-gel method is a synthetic chemical process where reactive monomers are mixed into a solution, polymerization occurs leading to a highly cross-linked three dimensional solid network resulting in a gel. The energetic materials can be incorporated during the formation of the solution or during the gel stage of the process. The composition, pore, and primary particle sizes, gel time, surface areas, and density may be tailored and controlled by the solution chemistry. The gel is then dried using supercritical extraction to produce a highly porous low density aerogel or by controlled slow evaporation to produce a xerogel. Applying stress during the extraction phase can result in high density materials. Thus, the sol-gel method can be used for precision detonator explosive manufacturing as well as producing precision explosives, propellants, and pyrotechnics, along with high power composite energetic materials.
摘要翻译： 溶胶 - 凝胶化学物质用于制备具有改进的均匀性的高能材料（爆炸物，推进剂和烟火），和/或可以铸造成近净形状和/或制成精密成型粉末。 溶胶 - 凝胶法是将反应性单体混合到溶液中的合成化学方法，发生聚合，导致高度交联的三维固体网络，导致凝胶。 高能材料可以在溶液形成期间或在该过程的凝胶阶段期间被引入。 组合物，孔和一次粒径，凝胶时间，表面积和密度可以通过溶液化学定制和控制。 然后使用超临界萃取干燥凝胶以产生高度多孔的低密度气凝胶或通过受控的缓慢蒸发以产生干凝胶。 在提取阶段施加应力可导致高密度材料。 因此，溶胶 - 凝胶法可用于精密雷管炸药制造，以及生产精密炸药，推进剂和烟火以及大功率复合材料。
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公开(公告)号：US06696576B2
公开(公告)日：2004-02-24
申请号：US10061927
申请日：2002-02-01
IPC分类号： C07D33102
CPC分类号： C02F1/683 , B01J20/26 , B01J45/00 , C02F1/285 , C02F1/64 , C02F2101/20 , C02F2303/16 , Y10S210/914
摘要： Thiacrown polymers immobilized to a polystyrene-divinylbenzene matrix react with Hg2+ under a variety of conditions to efficiently and selectively remove Hg2+ ions from acidic aqueous solutions, even in the presence of a variety of other metal ions. The mercury can be recovered and the polymer regenerated. This mercury removal method has utility in the treatment of industrial wastewater, where a selective and cost-effective removal process is required.
摘要翻译： 固定在聚苯乙烯 - 二乙烯基苯基质上的硫辛聚合物在各种条件下与Hg 2+反应，即使在各种其它金属离子存在下也能有效地和选择性地从酸性水溶液中除去Hg 2+离子。 可以回收汞并且聚合物再生。 这种除汞方法在工业废水的处理中具有应用价值，需要选择性和成本有效的去除工艺。
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