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公开(公告)号:US06333378B1
公开(公告)日:2001-12-25
申请号:US09321610
申请日:1999-05-28
申请人: Mark D. Clark , Bradley J. Helmer , Glenn L. Shoaf
发明人: Mark D. Clark , Bradley J. Helmer , Glenn L. Shoaf
IPC分类号: C08J3100
CPC分类号: C08F273/00 , C08F283/00 , C08F283/006 , C08F283/01 , C08F283/02 , C08F291/00 , C08G63/48 , C08G63/6888 , C08L51/003 , C08L51/08 , C09D151/003 , C09D151/08 , C09D167/07 , C09D167/08 , C08L2666/02 , C08L33/00
摘要: A water-based latex of an acrylic-modified waterborne alkyd or uralkyd dispersion in water is described. The acrylic-modified waterborne alkyd or uralkyd is a hybrid resin prepared by the polymerization of at least one latent oxidatively-functional (LOF) acrylic monomer in the presence of a waterborne alkyd or uralkyd. Alternatively, the acrylic-modified waterborne alkyd or uralkyd is a hybrid resin prepared by shearing a mini-emulsion based on a solvent-borne alkyd or uralkyd dissolved in at least one LOF acrylic monomer. Preparation of the latexes may be achieved by emulsion polymerization of at least one latent oxidatively-functional acrylic monomer in the presence of a waterborne alkyd or uralkyd whereby the latent oxidative functionality of the acrylic polymer survives polymerization. Water-based latexes may also be prepared by polymerizing a sheared mini-emulsion based on a solvent-borne alkyd or uralkyd dissolved in at least one LOF acrylic monomer such that the latent oxidative functionality of the acrylic polymer survives polymerization. Such acrylic-modified waterborne alkyd or uralkyds are useful in a variety of coating compositions.
摘要翻译: 描述了丙烯酸改性水性醇酸树脂或uralkyd分散体在水中的水性胶乳。 丙烯酸改性的水性醇酸或uralkyd是通过在水性醇酸树脂或uralkyd存在下至少一种潜在氧化官能(LOF)丙烯酸类单体的聚合制备的混合树脂。 或者,丙烯酸改性的水性醇酸树脂或uralkyd是通过基于溶解在至少一种LOF丙烯酸类单体中的溶剂型醇酸树脂或uralkyd来剪切微乳液制备的混合树脂。 胶乳的制备可以通过至少一种潜在氧化官能的丙烯酸类单体在水性醇酸树脂或uralkyd存在下的乳液聚合来实现,由此丙烯酸类聚合物的潜氧氧化官能度在聚合过程中存在。 也可以通过将溶解在至少一种LOF丙烯酸类单体中的溶剂型醇酸树脂或uralkyd的剪切微乳液聚合,使得丙烯酸类聚合物的潜在氧化官能度在聚合中存在而制备水性胶乳。 这种丙烯酸改性的水性醇酸或uralkyds可用于各种涂料组合物。