公开(公告)号：US07939681B2

公开(公告)日：2011-05-10

申请号：US11774036

申请日：2007-07-06

申请人： Haibo Zhao ,  Johnathan E. Holladay ,  Zongchao C. Zhang

发明人： Haibo Zhao ,  Johnathan E. Holladay ,  Zongchao C. Zhang

IPC分类号： C07D307/50 ,  C07D307/46

CPC分类号： C07D307/46

摘要： Methods are described for converting carbohydrates including, e.g., monosaccharides, disaccharides, and polysaccharides in ionic liquids to value-added chemicals including furans, useful as chemical intermediates and/or feedstocks. Fructose is converted to 5-hydroxylmethylfurfural (HMF) in the presence of metal halide and acid catalysts. Glucose is effectively converted to HMF in the presence of chromium chloride catalysts. Yields of up to about 70% are achieved with low levels of impurities such as levulinic acid.

摘要翻译： 描述了用于将离子液体中包括例如单糖，二糖和多糖的碳水化合物转化成包括用作化学中间体和/或原料的呋喃的增值化学品的方法。 在金属卤化物和酸催化剂存在下，果糖被转化成5-羟甲基糠醛（HMF）。 在氯化铬催化剂存在下，葡萄糖有效转化为HMF。 通过低水平的杂质如乙酰丙酸实现高达约70％的产率。

公开(公告)号：US20080033187A1

公开(公告)日：2008-02-07

申请号：US11774036

申请日：2007-07-06

申请人： Haibo Zhao ,  Johnathan E. Holladay ,  Zongchao C. Zhang

发明人： Haibo Zhao ,  Johnathan E. Holladay ,  Zongchao C. Zhang

IPC分类号： C07D307/48

CPC分类号： C07D307/46

摘要： Methods are described for converting carbohydrates including, e.g., monosaccharides, disaccharides, and polysaccharides in ionic liquids to value-added chemicals including furans, useful as chemical intermediates and/or feedstocks. Fructose is converted to 5-hydroxylmethylfurfural (HMF) in the presence of metal halide and acid catalysts. Glucose is effectively converted to HMF in the presence of chromium chloride catalysts. Yields of up to about 70% are achieved with low levels of impurities such as levulinic acid.

摘要翻译： 描述了用于将离子液体中包括例如单糖，二糖和多糖的碳水化合物转化成包括用作化学中间体和/或原料的呋喃的增值化学品的方法。 在金属卤化物和酸催化剂存在下，果糖被转化成5-羟甲基糠醛（HMF）。 在氯化铬催化剂存在下，葡萄糖有效转化为HMF。 通过低水平的杂质如乙酰丙酸实现高达约70％的产率。

公开(公告)号：US20200104020A1

公开(公告)日：2020-04-02

申请号：US16146733

申请日：2018-09-28

申请人： Matthew Colin Grantham ,  Jeremy Voss ,  David Whyte ,  Haibo Zhao

发明人： Matthew Colin Grantham ,  Jeremy Voss ,  David Whyte ,  Haibo Zhao

IPC分类号： G06F3/0484 ,  G06F3/0481 ,  G06T11/60 ,  G06F3/0482 ,  H04L29/08

摘要： Embodiments of the present disclosure relate generally to a collaborative achievement system for: detecting, at a client device associated with a first user, a collaborative achievement between at least the first user and a second user; selecting an achievement designator based on attributes of the collaborative achievement, wherein the achievement designator comprises personalization instructions for the achievement designator; retrieving, at the client device, user profile information from a first user account and a second user account associated with the first user and the second user; personalizing the achievement designator based on the user profile information and the personalization instructions; and causing display of a presentation of the personalized achievement designator at the client device.

公开(公告)号：US09284293B2

公开(公告)日：2016-03-15

申请号：US13819373

申请日：2011-08-19

申请人： Haibo Zhao ,  Mark Posey

发明人： Haibo Zhao ,  Mark Posey

IPC分类号： C07D317/36 ,  C07C269/04 ,  C07D317/38 ,  C07C68/06

CPC分类号： C07D317/36 ,  C07C68/06 ,  C07C269/04 ,  C07D317/38

摘要： A method of producing a carbonate product including mixing a DMC and methanol mixture with an alcohol, reacting the DMC with the alcohol to form carbonate product, and removing a substantial portion of unreacted DMC and methanol. In one embodiment, the method may be repeated to reach a desired alcohol conversion by adding more DMC and methanol mixture.

摘要翻译： 一种制备碳酸酯产品的方法，包括将DMC和甲醇混合物与醇混合，使DMC与醇反应以形成碳酸酯产物，并除去大部分未反应的DMC和甲醇。 在一个实施方案中，可以重复该方法以通过加入更多的DMC和甲醇混合物达到所需的醇转化率。

公开(公告)号：US20100317879A1

公开(公告)日：2010-12-16

申请号：US12862649

申请日：2010-08-24

申请人： Haibo Zhao ,  Johnathan E. Holladay ,  Zongchao C. Zhang

发明人： Haibo Zhao ,  Johnathan E. Holladay ,  Zongchao C. Zhang

IPC分类号： C07D307/50

CPC分类号： C07D307/46

摘要： Methods are described for converting carbohydrates including, e.g., monosaccharides, disaccharides, and polysaccharides in ionic liquids to value-added chemicals including furans, useful as chemical intermediates and/or feedstocks. Fructose is converted to 5-hydroxylmethylfurfural (HMF) in the presence of metal halide and acid catalysts. Glucose is effectively converted to HMF in the presence of chromium chloride catalysts. Yields of up to about 70% are achieved with low levels of impurities such as levulinic acid.

摘要翻译： 描述了用于将离子液体中包括例如单糖，二糖和多糖的碳水化合物转化成包括用作化学中间体和/或原料的呋喃的增值化学品的方法。 在金属卤化物和酸催化剂存在下，果糖被转化成5-羟甲基糠醛（HMF）。 在氯化铬催化剂存在下，葡萄糖有效转化为HMF。 通过低水平的杂质如乙酰丙酸实现高达约70％的产率。

公开(公告)号：US20100105966A1

公开(公告)日：2010-04-29

申请号：US12531895

申请日：2008-03-14

申请人： Haibo Zhao ,  Mattew W. Forkner ,  Wenjin Zhang

发明人： Haibo Zhao ,  Mattew W. Forkner ,  Wenjin Zhang

IPC分类号： C07C29/74 ,  C07C31/20

CPC分类号： C07C29/76 ,  C07C31/205

摘要： A process includes receiving a process stream including at least about 80.0% by weight propylene glycol, and contacting the process stream with an absorbent material to produce a product stream. The absorbent material is configured to preferentially absorb ethylene glycol relative to propylene glycol.

摘要翻译： 一种方法包括接收包含至少约80.0重量％丙二醇的工艺流，并使工艺流与吸收材料接触以产生产物流。 吸收材料配置成相对于丙二醇优先吸收乙二醇。

公开(公告)号：US09428391B2

公开(公告)日：2016-08-30

申请号：US14116361

申请日：2012-05-10

申请人： Yoku Inoue ,  Adrian Ghemes ,  Haibo Zhao

发明人： Yoku Inoue ,  Adrian Ghemes ,  Haibo Zhao

IPC分类号： C01B31/02 ,  B01J19/24 ,  B82Y30/00 ,  B82Y40/00

CPC分类号： C01B31/0226 ,  B01J19/24 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/16 ,  C01B32/162 ,  C01B2202/06 ,  C01B2202/34

摘要： Carbon nanotubes are grown by supplying raw material gas 30 comprising a carbon compound to be a raw material of the carbon nanotubes into the inside of a reaction vessel tube 14 in which a catalyst 26 to grow the carbon nanotubes is charged. At this time, halogen-containing material gas 32 to reduce the amount of a carbon product such as amorphous carbon produced besides carbon nanotubes that deposits on the surface of catalyst particles 44 due to supply of the raw material gas 30 is further supplied into the inside of the reaction vessel tube 14. Thereby, it is possible to produce elongated carbon nanotubes.

摘要翻译： 通过将作为碳纳米管的原料的碳化合物的原料气体30供给到反应容器管14的内部而生长碳纳米管，在反应容器管14的内部填充有碳纳米管生长的催化剂26。 此时，为了减少由于原料气体30的供给而沉积在催化剂粒子44的表面上的除了碳纳米管之外产生的无定形碳的碳制品的含量的含卤素材料气体32被进一步供给到内部 由此，可以制造细长的碳纳米管。

公开(公告)号：US08546620B2

公开(公告)日：2013-10-01

申请号：US12531895

申请日：2008-03-14

申请人： Haibo Zhao ,  Matthew W. Forkner ,  Wenjin Zhang

发明人： Haibo Zhao ,  Matthew W. Forkner ,  Wenjin Zhang

IPC分类号： C07C29/76

CPC分类号： C07C29/76 ,  C07C31/205

摘要： A process includes receiving a process stream including at least about 80.0% by weight propylene glycol, and contacting the process stream with an absorbent material to produce a product stream. The absorbent material is configured to preferentially absorb ethylene glycol relative to propylene glycol.

摘要翻译： 一种方法包括接收包含至少约80.0重量％丙二醇的工艺流，并使工艺流与吸收材料接触以产生产物流。 吸收材料配置成相对于丙二醇优先吸收乙二醇。

公开(公告)号：US20110118432A1

公开(公告)日：2011-05-19

申请号：US13003023

申请日：2009-05-21

申请人： Haibo Zhao ,  Ron Herrington ,  Frank Rodriguez

发明人： Haibo Zhao ,  Ron Herrington ,  Frank Rodriguez

IPC分类号： C08G18/32 ,  C07C215/10

CPC分类号： C08G18/36 ,  C08G18/3821

摘要： The present invention relates to a vegetable oil based autocatalytic polyol derived from the reaction product of an epoxidized vegetable oil and an alkanolamine. The autocatalytic polyol according to the present invention may be used as a replacement for all or a portion of petroleum derived polyols generally used in the production of polyurethane materials. The polyurethane materials produced may be used in a variety of applications, such as, foam, elastomer and coating applications.

摘要翻译： 本发明涉及来自环氧化植物油和链烷醇胺的反应产物的植物油基自催化多元醇。 根据本发明的自催化多元醇可用作代替通常用于生产聚氨酯材料的石油衍生多元醇的全部或部分。 生产的聚氨酯材料可用于各种应用，例如泡沫，弹性体和涂料应用。

公开(公告)号：US20140199230A1

公开(公告)日：2014-07-17

申请号：US14116361

申请日：2012-05-10

申请人： Yoku Inoue ,  Adrian Ghemes ,  Haibo Zhao

发明人： Yoku Inoue ,  Adrian Ghemes ,  Haibo Zhao

IPC分类号： C01B31/02 ,  B01J19/24

CPC分类号： C01B31/0226 ,  B01J19/24 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/16 ,  C01B32/162 ,  C01B2202/06 ,  C01B2202/34

摘要： Carbon nanotubes are grown by supplying raw material gas 30 comprising a carbon compound to be a raw material of the carbon nanotubes into the inside of a reaction vessel tube 14 in which a catalyst 26 to grow the carbon nanotubes is charged. At this time, halogen-containing material gas 32 to reduce the amount of a carbon product such as amorphous carbon produced besides carbon nanotubes that deposits on the surface of catalyst particles 44 due to supply of the raw material gas 30 is further supplied into the inside of the reaction vessel tube 14. Thereby, it is possible to produce elongated carbon nanotubes.

摘要翻译： 通过将作为碳纳米管的原料的碳化合物的原料气体30供给到反应容器管14的内部而生长碳纳米管，在反应容器管14的内部填充有碳纳米管生长的催化剂26。 此时，为了减少由于原料气体30的供给而沉积在催化剂粒子44的表面上的除了碳纳米管之外产生的无定形碳的碳制品的含量的含卤素材料气体32被进一步供给到内部 由此，可以制造细长的碳纳米管。