公开(公告)号：US5304237A

公开(公告)日：1994-04-19

申请号：US6454

申请日：1993-01-21

申请人： Volker Barth ,  Helmut Hartner

发明人： Volker Barth ,  Helmut Hartner

IPC分类号： A01N33/12 ,  A01N55/08 ,  B27K3/15 ,  B27K3/52 ,  C09D5/14 ,  A01N55/02

CPC分类号： A01N59/20 ,  A01N33/08 ,  A01N59/14 ,  B27K3/163 ,  B27K3/22 ,  B27K3/34 ,  B27K3/52 ,  Y10S514/947

摘要： A water-soluble chromium-free wood preservative comprising at least one copper salt and an alkanolamine and a polymeric quaternary ammonium borate formed by simultaneous reaction of (A) an amine selected from the group consisting of ##STR1## wherein R.sub.1 is alkyl or alkenyl of 8 to 22 carbon atoms or when R.sub.2 and R.sub.3 are --(C.sub.2 H.sub.4 O).sub.x --H or --(C.sub.3 H.sub.6 O).sub.x --H, R.sub.1 is alkyl of 1 to 22 carbon atoms, R.sub.2 is selected from the group consisting of hydrogen, alkyl of 1 to 22 carbon atoms, --(C.sub.2 H.sub.4 O).sub.x --H, --(C.sub.3 H.sub.6 O).sub.x --H and --CH.sub.2 --CH.sub.2 --NH.sub.2, R.sub.3 is selected from the group consisting of hydrogen, --(C.sub.2 H.sub.4 O).sub.x --H, --(C.sub.3 H.sub.6 O).sub.x --H and CH.sub.2 --CH.sub.2 --CH.sub.2 NH.sub.2, R.sub.4 and R.sub.6 are individually alkyl of 1 to 4 carbon atoms or --(CH.sub.2 H.sub.4 O).sub.x --H or --(C.sub.3 H.sub.6 O).sub.x --H, R.sub.5 and R.sub.2 are individually --(C.sub.2 H.sub.4 O).sub.x --H or -- (.sub.3 H.sub.6 O).sub.x --H, A is selected from the group consisting of --(CH.sub.2).sub.n --, --(CH.sub.2 --CH.sub.2 OCH.sub.2).sub.n -- and --(CH.sub.2 CH.sub.2 NHCH.sub.2 CH.sub.2).sub.n --, x is an integer of 1 to 55 and n is an integer of 1 to 20, (B) 2 to 20 moles of ethylene oxide or propylene oxide and (C) 0.6 to 1.5 moles of a member of the group consisting of boric acid, boric acid salts and boric acid esters per mole of nitrogen equivalent of (A) useful for impregnating wood exposed to weather conditions or installed in contact with soil.

摘要翻译： 包含至少一种铜盐和链烷醇胺的水溶性无铬木防腐剂和通过（A）选自（* CHEMICAL STRUCTURE *）I（* CHEMICAL）的胺同时反应形成的聚合季铵硼酸盐 结构*）II其中R1是8-22个碳原子的烷基或烯基，或当R2和R3是 - （C2H4O）xH或 - （C3H6O）xH时，R1是1至22个碳原子的烷基，R2选自 由氢，1至22个碳原子的烷基， - （C 2 H 4 O）x H， - （C 3 H 6 O）x H和-CH 2 -CH 2 -NH 2，R 3选自氢， - （C 2 H 4 O）x H， - （C 3 H 6 O ）xH和CH2-CH2-CH2NH2，R4和R6分别是1至4个碳原子的烷基或 - （CH2H4O）xH或 - （C3H6O）xH，R5和R2分别为 - （C2H4O）xH或 - （3H6O）xH ，A选自 - （CH 2）n - ， - （CH 2 -CH 2 OCH 2）n - 和 - （CH 2 CH 2 NHCH 2 CH 2）n - ，x为1〜55的整数，n为1〜20的整数， （B）2-20摩尔环氧乙烷或丙烯 氧化铝和（C）每摩尔氮当量（A）的硼酸，硼酸盐和硼酸酯组成的组中的0.6至1.5摩尔，用于浸渍暴露于天气条件下的木材或与 泥。

公开(公告)号：US06506795B1

公开(公告)日：2003-01-14

申请号：US08622085

申请日：1996-03-26

申请人： Volker Barth ,  Helmut Hartner ,  Volker Beez

发明人： Volker Barth ,  Helmut Hartner ,  Volker Beez

IPC分类号： A01N3702

CPC分类号： A01N59/20 ,  A01N59/14 ,  B27K3/153 ,  B27K3/163 ,  B27K3/34 ,  B27K3/36 ,  B27K3/50 ,  B27K3/52 ,  C08L79/02 ,  C08L97/02 ,  Y10T428/4935 ,  Y10T428/662 ,  A01N2300/00 ,  A01N25/30 ,  A01N33/12

摘要： A chromium-free wood preservative consisting essentially of 1 to 35% by weight of a mixture of 25 to 75 parts by weight of a fatty amine ethoxylate and 75 to 25 parts by weight of at least one member of the group consisting of an unsaturated fatty acid of 3 to 25 carbon atoms and their copper and zinc salts and water.

摘要翻译： 一种无铬木防腐剂，其基本上由1至35重量％的25至75重量份脂肪胺乙氧基化物的混合物和75至25重量份的至少一种不饱和脂肪酸 3至25个碳原子的酸及其铜和锌盐和水。

公开(公告)号：US4970201A

公开(公告)日：1990-11-13

申请号：US391469

申请日：1989-08-09

申请人： Eberhard Giebeler ,  Detlef Wehle ,  Helmut Hartner ,  Franz Konig ,  Helmut Berenbold

发明人： Eberhard Giebeler ,  Detlef Wehle ,  Helmut Hartner ,  Franz Konig ,  Helmut Berenbold

IPC分类号： B27K3/36 ,  A01N55/08 ,  B27K3/15 ,  B27K3/50 ,  C08G65/26

CPC分类号： B27K3/163 ,  B27K3/15 ,  C08G65/2639 ,  C08L97/02 ,  C08L79/02 ,  Y10S514/947

摘要： A biocidal preservative for cellulose-containing products containing a biocidally effective amount of a polymeric quaternary ammonium borate obtained by simultaneous reaction of (A) at least one member of the group consisting of boric acid and salts and esters thereof and (B) an amine of the formula ##STR1## and (C) ethylene oxide or propylene oxide wherein R.sub.1 is alkyl or alkenyl of 8 to 22 carbon atoms and R.sub.2 is hydrogen, alkyl of 1 to 22 carbon atoms or --CH.sub.2 CH.sub.2 NH.sub.2 or R.sub.1 is alkyl of 1 to 4 carbon atoms and R.sub.2 is --(CH.sub.2 CH.sub.2 O).sub.x --H or --(CH.sub.2 CH.sub.2 CH.sub.2 O).sub.x --H, R.sub.3 is selected from the group consisting of hydrogen, --(CH.sub.2 CH.sub.2 O).sub.x --H, (CH.sub.2 CH.sub.2 CH.sub.2 O).sub.x --H and --CH.sub.2 CH.sub.2 CH.sub.2 NH.sub.2, R.sub.4 and R.sub.6 are individually selected from the group consisting of alkyl of 1 to 4 carbon atoms, --(CH.sub.2 CH.sub.2 O).sub.x --H and --(CH.sub.2 CH.sub.2 CH.sub.2 O).sub.x --H, and R.sub.5 and R.sub.7 are individually --(CH.sub.2 CH.sub.2 O).sub.x --H and --(CH.sub.2 CH.sub.2 CH.sub.2 O).sub.x --H, A is selected from the group consisting of --(CH.sub.2).sub.n, --(CH.sub.2 CH.sub.2 --O--CH.sub.2 CH.sub.2).sub.n -- and --(CH.sub.2 CH.sub.2 --NH--CH.sub.2 CH.sub.2).sub.n --x is an integer from 1 to 55 and n is an integer of 1 to 20, the molar ratio of A:B:C being 1:2 to 20:0.6 to 1.5.

摘要翻译： 含有生物有效量的聚合季铵硼酸盐的含有杀生物剂的产品的杀生物防腐剂，其通过（A）由硼酸及其盐和酯组成的组中的至少一个成员同时反应而获得，和（B） 式（IMA）和（C）环氧乙烷或环氧丙烷，其中R1是8-22个碳原子的烷基或烯基，R2是氢，1-22个碳原子的烷基或-CH2CH2NH2或R1是1到4个碳原子的烷基 原子，R 2是 - （CH 2 CH 2 OCH 2）x H或 - （CH 2 CH 2 CH 2 O）x H，R 3选自氢， - （CH 2 CH 2 O）x H，（CH 2 CH 2 CH 2 O）x H和-CH 2 CH 2 CH 2 NH 2，R 4和R 6各自选自 具有1至4个碳原子的烷基， - （CH 2 CH 2 O）x H和 - （CH 2 CH 2 CH 2 O）x H，且R 5和R 7分别为 - （CH 2 CH 2 O）x H和 - （CH 2 CH 2 CH 2 O）x H，A选自 - （CH 2 ）n， - （CH 2 CH 2 -O-CH 2 CH 2）n - 和 - （CH 2 CH 2 -NH-CH 2 CH 2）n x为1〜55的整数，n为整数 r为1〜20，A:B:C的摩尔比为1:2〜20:0.6〜1.5。