公开(公告)号：US20080139413A1

公开(公告)日：2008-06-12

申请号：US12001956

申请日：2007-12-12

申请人： Pingmei Wang ,  Jianhui Luo ,  Yuzhang Liu ,  Huaijiang Zhu ,  Chunming Xiong ,  Qiang Liu ,  Ruyi Jiang ,  Yikun Li ,  Ying Zhang

发明人： Pingmei Wang ,  Jianhui Luo ,  Yuzhang Liu ,  Huaijiang Zhu ,  Chunming Xiong ,  Qiang Liu ,  Ruyi Jiang ,  Yikun Li ,  Ying Zhang

IPC分类号： C09K8/588

CPC分类号： C09K8/516 ,  C08F222/26 ,  C08F236/10 ,  C09K2208/18

摘要： Disclosed are a flexible polymer, particles made from same, and a process for preparing the particles. This flexible polymer is obtained from copolymerizing monomer (A) and monomer (B), wherein monomer (A) is one or more water-insoluble unsaturated diene monomers; monomer (B) is at least one compound with the general formula of wherein R is C1-C12alkyl, C1-C12 alkyl aryl, C1-C12 alkyl ether or C1-C12alkyl ester. Monomer (A) is in an amount of 60-90% by weight of the total combined weight of monomer (A) and monomer (B). Monomer (B) is in an amount of 10-40% by weight of the total combined weight of monomer (A) and monomer (B). The flexible polymer particles show excellent flexibility, deformability, elasticity as well as stability. They can be used in oilfields in nearby wellbore profile control and in-depth profile control or as in-depth flooding fluid diverting agents. They can also be applied in water shutoff in high temperature and high salinity production wells; preventing chemical channeling in polymer and ASP (alkali-surfactant-polymer) flooding; temporarily plugging in acidization; huff and puff; and preventing in-depth channeling in steam flooding, loss of circulation control and filtration control, and the like.

摘要翻译： 公开了柔性聚合物，由其制成的颗粒和制备颗粒的方法。 该柔性聚合物由共聚单体（A）和单体（B）得到，其中单体（A）为一种或多种水不溶性不饱和二烯单体; 单体（B）是至少一种具有以下通式的化合物：其中R是C 1 -C 12烷基，C 1 -C 3烷基， C 12 -C 12烷基芳基，C 1 -C 12烷基醚或C 1 -C 12烷基醚或C 1 -C 12烷基醚 >烷基酯。 单体（A）的单体（A）和单体（B）的总组合重量的60-90重量％。 单体（B）的单体（A）和单体（B）的总组合重量的量为10-40重量％。 柔性聚合物颗粒显示出优异的柔韧性，变形性，弹性以及稳定性。 它们可用于油田附近的井筒剖面控制和深度剖面控制，或用作深度淹没液体转向剂。 也可应用于高温高盐生产井的关闭水中; 防止聚合物和ASP（碱 - 表面活性剂 - 聚合物）淹水中的化学通道; 暂时酸化; 气喘吁吁; 并防止蒸汽溢流的深入沟通，流通控制和过滤控制的损失等。

公开(公告)号：US08822389B2

公开(公告)日：2014-09-02

申请号：US13508866

申请日：2010-06-11

申请人： Jianhui Luo ,  Huaijiang Zhu ,  Fengluan Bai ,  Pingmei Wang ,  Bin Ding ,  Jingbo Yang ,  Qiang Liu ,  Yuzhang Liu

发明人： Jianhui Luo ,  Huaijiang Zhu ,  Fengluan Bai ,  Pingmei Wang ,  Bin Ding ,  Jingbo Yang ,  Qiang Liu ,  Yuzhang Liu

IPC分类号： C09K8/588

CPC分类号： C08F228/02 ,  C08F216/08 ,  C08F220/06 ,  C08F220/56 ,  C08F222/04 ,  C08F222/14 ,  C08F226/10 ,  C08G83/002 ,  C09K8/588

摘要： The present invention relates to a dendritic comb-shaped polymer thickening agent and preparation and application thereof; it is a copolymer obtained by copolymerization of monomer (A) and monomer (B). Monomer (A) is one or more water-soluble unsaturated monomers with olefin chain, and monomer (B) is at least one monomer with the following general structure: wherein R1, R2 is selected from H or C1˜C12 alkyl group, respectively; R3, R4, R5 is selected from H or C1˜C8 alkyl group, C1˜C8 alkylaryl group, C1˜C8 alkyl ether or C1˜C8 alkyl ester group, respectively; A′ is selected from COO− or OH. The content of the monomer (A) is 70˜99.99% of the total mass of the monomer (A) and the monomer (B), and the content of monomer (B) is 0.01˜30% of the total mass of the monomer (A) and the monomer (B). The viscosity of the polymer solution with the present polymer is 30% higher than that with common polyacrylamide and it is used in polymer flooding for oil reservoir with permeability lower than 400 mD in oilfields.

摘要翻译： 本发明涉及树枝状梳状聚合物增稠剂及其制备及应用; 是通过单体（A）和单体（B）的共聚得到的共聚物。 单体（A）是一种或多种具有烯烃链的水溶性不饱和单体，单体（B）是至少一种具有以下一般结构的单体：其中R1，R2分别选自H或C1〜C12烷基; R3，R4，R5分别选自H或C1〜C8烷基，C1〜C8烷基芳基，C1〜C8烷基醚或C1〜C8烷基酯基; A'选自COO-或OH。 单体（A）的含量为单体（A）和单体（B）总质量的70〜99.99％，单体（B）的含量为单体总量的0.01〜30％ （A）和单体（B）。 聚合物溶液与本发明聚合物的粘度比普通聚丙烯酰胺高30％，用于油田渗透率低于400mD的油藏聚合物驱油。

公开(公告)号：US07304116B2

公开(公告)日：2007-12-04

申请号：US11447035

申请日：2006-06-06

申请人： Shiyi Yuan ,  Jianhui Luo ,  Ruoying Pu ,  Yuzhang Liu ,  Huaijiang Zhu ,  Pingmei Wang ,  Chunming Xiong ,  Ying Zhang ,  Fengluan Bai ,  Jingbo Yang

发明人： Shiyi Yuan ,  Jianhui Luo ,  Ruoying Pu ,  Yuzhang Liu ,  Huaijiang Zhu ,  Pingmei Wang ,  Chunming Xiong ,  Ying Zhang ,  Fengluan Bai ,  Jingbo Yang

IPC分类号： C08F20/06 ,  C08F20/26

CPC分类号： C08F222/02 ,  C08F220/06 ,  C08F220/20 ,  C08F220/56 ,  C08F220/58 ,  C08F228/02 ,  C09K8/588

摘要： A braided comb-shaped salt-resistant thickening agent for tertiary oil extraction from class I oil reservoir is disclosed.The agent is polymerized with monomer (A) and monomer (B), and monomer (A) is one or multiple water soluble non-saturated compound(s) with alkenyl chain, while monomer (B) is at least one compound with the following formula: Monomer (A) is preferably acrylamide, ethenyl pyrrolidone, 2-acrylamide-2 methylpropane sulfonic acid, and acrylic acid or the mixture of the above said compounds, and in the formula of monomer (B), A is COOH, OH, SO3H, R1 and R2 are H or C1-C12 alkyl, R3 and R4 represent C1-C12 alkyl, C1-C12 alkylaryl, C1-C12 alkyl ether or C1-C12 alkyl ester group. This thickening agent has fine water solubility and good property to thicken water medium. The polymer's molecules present a braided comb-shaped structure in water solution with fine salt-resistant performances. The agent can be used together with the water extracted from oil mines to compound the polymer for tertiary oil extraction, and the polymer solution's viscosity can reach the level of the comb-shaped salt-resistant polymer solution applied in class I oil reservoir, so it can promote the economic benefits of tertiary oil extraction from class II oil reservoir and expand the application scope.

摘要翻译： 公开了一种用于三级油从I类油藏提取的编织梳形耐盐增稠剂。

公开(公告)号：US20130090269A1

公开(公告)日：2013-04-11

申请号：US13508866

申请日：2010-06-11

申请人： Jianhui Luo ,  Huaijiang Zhu ,  Fengluan Bai ,  Pingmei Wang ,  Bin Ding ,  Jingbo Yang ,  Qiang Liu ,  Yuzhang Liu

发明人： Jianhui Luo ,  Huaijiang Zhu ,  Fengluan Bai ,  Pingmei Wang ,  Bin Ding ,  Jingbo Yang ,  Qiang Liu ,  Yuzhang Liu

IPC分类号： C08F228/02 ,  C08F226/10 ,  C09K8/588 ,  C08F220/56

CPC分类号： C08F228/02 ,  C08F216/08 ,  C08F220/06 ,  C08F220/56 ,  C08F222/04 ,  C08F222/14 ,  C08F226/10 ,  C08G83/002 ,  C09K8/588

摘要： The present invention relates to a dendritic comb-shaped polymer thickening agent and preparation and application thereof; it is a copolymer obtained by copolymerization of monomer (A) and monomer (B). Monomer (A) is one or more water-soluble unsaturated monomers with olefin chain, and monomer (B) is at least one monomer with the following general structure: wherein R1, R2 is selected from H or C1˜C12 alkyl group, respectively; R3, R4, R5 is selected from H or C1˜C8 alkyl group, C1˜C8 alkylaryl group, C1˜C8 alkyl ether or C1˜C8 alkyl ester group, respectively; A′ is selected from COO− or OH. The content of the monomer (A) is 70˜99.99% of the total mass of the monomer (A) and the monomer (B), and the content of monomer (B) is 0.01˜30% of the total mass of the monomer (A) and the monomer (B). The viscosity of the polymer solution with the present polymer is 30% higher than that with common polyacrylamide and it is used in polymer flooding for oil reservoir with permeability lower than 400 mD in oilfields.

摘要翻译： 本发明涉及树枝状梳状聚合物增稠剂及其制备及应用; 是通过单体（A）和单体（B）的共聚得到的共聚物。 单体（A）是一种或多种具有烯烃链的水溶性不饱和单体，单体（B）是至少一种具有以下一般结构的单体：其中R1，R2分别选自H或C1〜C12烷基; R3，R4，R5分别选自H或C1〜C8烷基，C1〜C8烷基芳基，C1〜C8烷基醚或C1〜C8烷基酯基; A'选自COO-或OH。 单体（A）的含量为单体（A）和单体（B）总质量的70〜99.99％，单体（B）的含量为单体总量的0.01〜30％ （A）和单体（B）。 聚合物溶液与本发明聚合物的粘度比普通聚丙烯酰胺高30％，用于油田渗透率低于400mD的油藏聚合物驱油。

公开(公告)号：US07867952B2

公开(公告)日：2011-01-11

申请号：US12001956

申请日：2007-12-12

申请人： Pingmei Wang ,  Jianhui Luo ,  Yuzhang Liu ,  Huaijiang Zhu ,  Chunming Xiong ,  Qiang Liu ,  Ruyi Jiang ,  Yikun Li ,  Ying Zhang

发明人： Pingmei Wang ,  Jianhui Luo ,  Yuzhang Liu ,  Huaijiang Zhu ,  Chunming Xiong ,  Qiang Liu ,  Ruyi Jiang ,  Yikun Li ,  Ying Zhang

IPC分类号： C07C43/00

CPC分类号： C09K8/516 ,  C08F222/26 ,  C08F236/10 ,  C09K2208/18

摘要： Disclosed are a flexible polymer, particles made from same, and a process for preparing the particles. This flexible polymer is obtained from copolymerizing monomer (A) and monomer (B), wherein monomer (A) is one or more water-insoluble unsaturated diene monomers; monomer (B) is at least one compound with the general formula of wherein R is C1-C12alkyl, C1-C12 alkyl aryl, C1-C12 alkyl ether or C1-C12alkyl ester. Monomer (A) is in an amount of 60-90% by weight of the total combined weight of monomer (A) and monomer (B). Monomer (B) is in an amount of 10-40% by weight of the total combined weight of monomer (A) and monomer (B). The flexible polymer particles show excellent flexibility, deformability, elasticity as well as stability. They can be used in oilfields in nearby wellbore profile control and in-depth profile control or as in-depth flooding fluid diverting agents. They can also be applied in water shutoff in high temperature and high salinity production wells; preventing chemical channeling in polymer and ASP (alkali-surfactant-polymer) flooding; temporarily plugging in acidization; huff and puff; and preventing in-depth channeling in steam flooding, loss of circulation control and filtration control, and the like.

摘要翻译： 公开了柔性聚合物，由其制成的颗粒和制备颗粒的方法。 该柔性聚合物由共聚单体（A）和单体（B）得到，其中单体（A）为一种或多种水不溶性不饱和二烯单体; 单体（B）是至少一种具有通式的化合物，其中R是C 1 -C 12烷基，C 1 -C 12烷基芳基，C 1 -C 12烷基醚或C 1 -C 12烷基酯。 单体（A）的单体（A）和单体（B）的总组合重量的60-90重量％。 单体（B）的单体（A）和单体（B）的总组合重量的量为10-40重量％。 柔性聚合物颗粒显示出优异的柔韧性，变形性，弹性以及稳定性。 它们可用于油田附近的井筒剖面控制和深度剖面控制，或用作深度淹没液体转向剂。 也可应用于高温高盐生产井的关闭水中; 防止聚合物和ASP（碱 - 表面活性剂 - 聚合物）淹水中的化学通道; 暂时酸化; 气喘吁吁; 并防止蒸汽溢流的深入沟通，流通控制和过滤控制的损失等。

公开(公告)号：US20060287456A1

公开(公告)日：2006-12-21

申请号：US11447035

申请日：2006-06-06

申请人： Shiyi Yuan ,  Jianhui Luo ,  Ruoying Pu ,  Yuzhang Liu ,  Huaijiang Zhu ,  Pingmei Wang ,  Chunming Xiong ,  Ying Zhang ,  Fengluan Bai ,  Jingbo Yang

发明人： Shiyi Yuan ,  Jianhui Luo ,  Ruoying Pu ,  Yuzhang Liu ,  Huaijiang Zhu ,  Pingmei Wang ,  Chunming Xiong ,  Ying Zhang ,  Fengluan Bai ,  Jingbo Yang

IPC分类号： C08F228/02

CPC分类号： C08F222/02 ,  C08F220/06 ,  C08F220/20 ,  C08F220/56 ,  C08F220/58 ,  C08F228/02 ,  C09K8/588

摘要： A braided comb-shaped salt-resistant thickening agent for tertiary oil extraction from class I oil reservoir is disclosed. The agent is polymerized with monomer (A) and monomer (B), and monomer (A) is one or multiple water soluble non-saturated compound(s) with alkenyl chain, while monomer (B) is at least one compound with the following formula: Monomer (A) is preferably acrylamide, ethenyl pyrrolidone, 2-acrylamide-2 methylpropane sulfonic acid, and acrylic acid or the mixture of the above said compounds, and in the formula of monomer (B), A is COOH, OH, SO3H, R1 and R2 are H or C1-C12 alkyl, R3 and R4 represent C1-C12 alkyl, C1-C12 alkylaryl, C1-C12 alkyl ether or C1-C12 alkyl ester group. This thickening agent has fine water solubility and good property to thicken water medium. The polymer's molecules present a braided comb-shaped structure in water solution with fine salt-resistant performances. The agent can be used together with the water extracted from oil mines to compound the polymer for tertiary oil extraction, and the polymer solution's viscosity can reach the level of the comb-shaped salt-resistant polymer solution applied in class I oil reservoir, so it can promote the economic benefits of tertiary oil extraction from class II oil reservoir and expand the application scope.

摘要翻译： 公开了一种用于三级油从I类油藏提取的编织梳形耐盐增稠剂。 该试剂与单体（A）和单体（B）聚合，单体（A）是具有烯基链的一种或多种水溶性非饱和化合物，而单体（B）是至少一种具有下列化合物的化合物 式（A）优选为丙烯酰胺，乙烯基吡咯烷酮，2-丙烯酰胺-2-甲基丙烷磺酸，丙烯酸或上述化合物的混合物，在式（B）中，A为COOH，OH， SO 3 H，R 1和R 2均为H或C 1 -C 12烷基， C 1 -C 4烷基，R 3和R 4代表C 1 -C 12烷基，C 1〜 C 1 -C 12烷基芳基，C 1 -C 12烷基醚或C 1 -C 3烷基芳基， 烷基酯基团。 该增稠剂具有良好的水溶性和对增稠水介质的良好性能。 聚合物的分子在水溶液中呈现编织梳状结构，具有良好的耐盐性能。 该试剂可以与从油矿提取的水一起使用，将聚合物复合，用于三级油萃取，聚合物溶液的粘度可以达到应用于I级油藏的梳状耐盐聚合物溶液的水平，因此 可以促进二级油藏三级采油的经济效益，扩大应用范围。