公开(公告)号：US08414965B2

公开(公告)日：2013-04-09

申请号：US12741389

申请日：2008-10-23

申请人： Yong Jin Cho ,  Chul Jin Kim ,  Chong Tai Kim ,  Sung Wook Choi ,  Jae Ho Kim ,  Hyo Sop Kim ,  Jin Ho Kim

发明人： Yong Jin Cho ,  Chul Jin Kim ,  Chong Tai Kim ,  Sung Wook Choi ,  Jae Ho Kim ,  Hyo Sop Kim ,  Jin Ho Kim

IPC分类号： B05D5/12 ,  C23C14/28 ,  C23C14/30 ,  C23C14/14 ,  H05B6/00 ,  H05B7/00 ,  B05D1/18 ,  B05D3/00

CPC分类号： G01N21/658 ,  G01N21/554 ,  Y10T428/24372 ,  Y10T428/31678

摘要： A method for manufacturing a substrate of an analytical sensor and the substrate thus prepared are disclosed. The method for manufacturing the substrate of the sensor application according to the present invention is characterized in that it comprises (a) the step of preparing a dispersed solution of nanoparticles, which are stable in a volatile organic solvent due to surface modification of nanoparticles having a pre-designed certain size on the nanometer level with an organic functional group (b) the step of preparing a single layer film of nanoparticles surface-modified with the organic functional group on the interface using said dispersed solution of nanoparticles on the basis of the Langmuir-Blodgett method, and then transferring said single layer film of nanoparticles to the substrate; and (c) the step of coating the substrate to which said single layer film of nanoparticles is transferred, with the metal thin film by means of the vacuum vapor deposition, and then optionally removing nanoparticles to manufacture a nanostructure to be used as the analytical sensor using optical characteristics. According to the method for manufacturing the substrate of the sensor application according to the present invention as above, the nanoparticles can be uniformly fixed on the solid substrate having a great area above 10×10 cm2 using the Langmuir-Blodgett method, and by such method the size, distance and shape of nanoparticles can be controlled to manufacture the nanostructures to be used as the analytical sensor, which is possible to reproduce and mass-produce. When the sensitivity property of the sensor is measured using the nanostructure substrate, thus produced, to be used as the analytical sensor, it can be identified that the sensitivity can be highly improved.

摘要翻译： 公开了一种用于制造如此制备的分析传感器和衬底的衬底的方法。 根据本发明的传感器应用的基板的制造方法的特征在于，其包括（a）制备纳米颗粒的分散溶液的步骤，所述分散溶液由于纳米颗粒的表面改性而在挥发性有机溶剂中稳定， 用有机官能团预先设计在纳米级上的一定尺寸（b）制备在界面上用有机官能团表面改性的纳米颗粒单层薄膜的步骤，该纳米粒子基于Langmuir -Blodgett方法，然后将所述单层纳米颗粒膜转移到基底; 和（c）通过真空气相沉积用金属薄膜涂覆纳米颗粒的单层膜转移到其上的基底的步骤，然后任选地除去纳米颗粒以制造用作分析传感器的纳米结构 使用光学特性。 根据如上所述的根据本发明的传感器应用的基板的制造方法，可以使用Langmuir-Blodgett方法将纳米颗粒均匀地固定在具有大于10×10cm 2的大面积的固体基板上，并且通过这种方法 可以控制纳米颗粒的尺寸，距离和形状，以制造用作分析传感器的纳米结构，其可以再现和批量生产。 当使用由此产生的纳米结构基板测量传感器的灵敏度特性作为分析传感器时，可以确定可以高度提高灵敏度。

公开(公告)号：US20100239464A1

公开(公告)日：2010-09-23

申请号：US12741389

申请日：2008-10-23

申请人： Yong Jin Cho ,  Chul Jin Kim ,  Chong Tai Kim ,  Sung Wook Choi ,  Jae Ho Kim ,  Hyo Sop Kim ,  Jin Ho Kim

发明人： Yong Jin Cho ,  Chul Jin Kim ,  Chong Tai Kim ,  Sung Wook Choi ,  Jae Ho Kim ,  Hyo Sop Kim ,  Jin Ho Kim

IPC分类号： G01N21/55 ,  C23C16/44 ,  B32B15/04 ,  B32B5/16 ,  G01N33/543

CPC分类号： G01N21/658 ,  G01N21/554 ,  Y10T428/24372 ,  Y10T428/31678

摘要： A method for manufacturing a substrate of an analytical sensor and the substrate thus prepared are disclosed. The method for manufacturing the substrate of the sensor application according to the present invention is characterized in that it comprises (a) the step of preparing a dispersed solution of nanoparticles, which are stable in a volatile organic solvent due to surface modification of nanoparticles having a pre-designed certain size on the nanometer level with an organic functional group (b) the step of preparing a single layer film of nanoparticles surface-modified with the organic functional group on the interface using said dispersed solution of nanoparticles on the basis of the Langmuir-Blodgett method, and then transferring said single layer film of nanoparticles to the substrate; and (c) the step of coating the substrate to which said single layer film of nanoparticles is transferred, with the metal thin film by means of the vacuum vapor deposition, and then optionally removing nanoparticles to manufacture a nanostructure to be used as the analytical sensor using optical characteristics. According to the method for manufacturing the substrate of the sensor application according to the present invention as above, the nanoparticles can be uniformly fixed on the solid substrate having a great area above 10×10 cm2 using the Langmuir-Blodgett method, and by such method the size, distance and shape of nanoparticles can be controlled to manufacture the nanostructures to be used as the analytical sensor, which is possible to reproduce and mass-produce. When the sensitivity property of the sensor is measured using the nanostructure substrate, thus produced, to be used as the analytical sensor, it can be identified that the sensitivity can be highly improved.

摘要翻译： 公开了一种用于制造如此制备的分析传感器和衬底的衬底的方法。 根据本发明的传感器应用的基板的制造方法的特征在于，其包括（a）制备纳米颗粒的分散溶液的步骤，所述分散溶液由于纳米颗粒的表面改性而在挥发性有机溶剂中稳定， 用有机官能团预先设计在纳米级上的一定尺寸（b）制备在界面上用有机官能团表面改性的纳米颗粒单层薄膜的步骤，该纳米粒子基于Langmuir -Blodgett方法，然后将所述单层纳米颗粒膜转移到基底; 和（c）通过真空气相沉积用金属薄膜涂覆纳米颗粒的单层膜转移到其上的基底的步骤，然后任选地除去纳米颗粒以制造用作分析传感器的纳米结构 使用光学特性。 根据如上所述的根据本发明的传感器应用的基板的制造方法，可以使用Langmuir-Blodgett方法将纳米颗粒均匀地固定在具有大于10×10cm 2的大面积的固体基板上，并且通过这种方法 可以控制纳米颗粒的尺寸，距离和形状，以制造用作分析传感器的纳米结构，其可以再现和批量生产。 当使用由此产生的纳米结构基板测量传感器的灵敏度特性作为分析传感器时，可以确定可以高度提高灵敏度。