Abstract:
Described is a method for the production and recovery of hydrogen cyanide, which includes removing ammonia from a crude hydrogen cyanide stream. The method integrates heat removed from a crude hydrogen cyanide stream into other areas of the hydrogen cyanide recovery process. The crude hydrogen cyanide stream may be passed through a first waste heat boiler and a second waste heat boiler prior to being fed to an ammonia absorber, which produces a hydrogen cyanide rich stream. Hydrogen cyanide is recovered from the hydrogen cyanide rich stream. Equipment fouling with HCN polymer is reduced.
Abstract:
The present invention relates to a system and a process for producing hydrogen cyanide and more particularly, to a process for controlling operational stability of the system and process by blanketing the system with inert gas. More particularly, the present invention relates to the flushing of the system with an inert gas when a crude hydrogen cyanide product exceeds a threshold of oxygen, such as greater than 0.4 vol. % oxygen.
Abstract:
The disclosed process relates to an improved process for manufacturing THF from a reaction mixture comprising BDO in the presence of an acid catalyst in a reaction vessel comprising a distillation reaction zone, wherein the acid catalyst is suspended in a vapor-rich region in the distillation reaction zone.
Abstract:
A method and a system for recovering hydrogen from a process for making hydrogen cyanide are described herein. In the method, hydrogen is recovered from a gaseous waste stream of an Andrussow process. The method comprises the following steps: (a) adjusting a reaction mixture comprising methane, ammonia and oxygen to provide the reaction mixture with sufficient oxygen to generate a gaseous waste stream that has at least 40% hydrogen after removal of ammonia and recovery of hydrogen cyanide; and (b) removing components from the gaseous waste stream to generate recovered hydrogen.