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1.发明授权Alkaline persulfate for low-temperature breaking of multi-chain polymer viscosified fluid 有权碱性过硫酸盐用于低温断裂多链聚合物增稠液公开(公告)号：US09062243B2
公开(公告)日：2015-06-23
申请号：US13166442
申请日：2011-06-22
CPC分类号： C09K8/68 , B08B9/02 , C09K8/685 , C09K2208/26
摘要： A persulfate compound activated by a strong base is used for low-temperature breaking of fluids viscosified with a multi-chain polysaccharide. The breaker system can be used in an oilfield or pipeline application where a multi-chain polysaccharide may be used in a fluid. It is particularly useful at low temperatures of less than 100° F. Optionally, the water can be a brine.
摘要翻译： 用强碱活化的过硫酸盐化合物用于低温多破碎的多链多糖粘稠液体的低温断裂。 断路器系统可用于油田或管道应用中，其中多链多糖可用于流体。 它在低于100°F的低温下特别有用。任选地，水可以是盐水。
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公开(公告)号：US08541348B2
公开(公告)日：2013-09-24
申请号：US13433581
申请日：2012-03-29
IPC分类号： C09K8/68
摘要： Emulsions for use in a well including: (a) a water-insoluble resinous material; (b) water; and (c) an emulsifier, wherein the emulsifier comprises a non-ionic, a cationic, or a zwitterionic emulsifier; wherein the continuous phase of the emulsion comprises the water; wherein a dispersed phase of the emulsion comprises the resinous material; wherein the dispersed phase is in the form of droplets having a size distribution range such that at least 50% of the droplets have a size of 0.5 micrometers-500 micrometers; wherein the resinous material of the droplets is in a concentration of at least 5% by weight of the water; and wherein the composition of the droplets has a viscosity of less than 2,000 Poise measured at 20° F. Methods include the steps of: (a) forming an emulsion described above; and (b) introducing the emulsion into a portion of a subterranean formation.
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3.发明申请STABILIZATION OF EMULSIONS CONTAINING RESINOUS MATERIAL FOR USE IN THE FIELD OF OIL OR GAS WELL TREATMENTS 有权用于油田或气井处理领域的含有树脂材料的乳液的稳定性公开(公告)号：US20130130946A1
公开(公告)日：2013-05-23
申请号：US13433581
申请日：2012-03-29
IPC分类号： C09K8/68
摘要： Emulsions for use in a well including: (a) a water-insoluble resinous material; (b) water; and (c) an emulsifier, wherein the emulsifier comprises a non-ionic, a cationic, or a zwitterionic emulsifier; wherein the continuous phase of the emulsion comprises the water; wherein a dispersed phase of the emulsion comprises the resinous material; wherein the dispersed phase is in the form of droplets having a size distribution range such that at least 50% of the droplets have a size of 0.5 micrometers-500 micrometers; wherein the resinous material of the droplets is in a concentration of at least 5% by weight of the water; and wherein the composition of the droplets has a viscosity of less than 2,000 Poise measured at 20° F. Methods include the steps of: (a) forming an emulsion described above; and (b) introducing the emulsion into a portion of a subterranean formation.
摘要翻译： 用于井的乳液，包括：（a）水不溶性树脂材料; （b）水; 和（c）乳化剂，其中所述乳化剂包含非离子型，阳离子型或两性离子型乳化剂; 其中乳液的连续相包含水; 其中所述乳液的分散相包含所述树脂材料; 其中分散相是液滴的形式，其尺寸分布范围使得至少50％的液滴具有0.5微米至500微米的尺寸; 其中所述液滴的树脂材料的浓度为所述水的至少5重量％; 并且其中所述液滴的组成在20°F下测得的粘度小于2,000泊。方法包括以下步骤：（a）形成上述乳液; 和（b）将乳液引入地层的一部分。
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4.发明授权Methods of treating a portion of a well with a polymer or polymer system capable of forming a gel that dissolves at a low and high pH 有权用能够形成在低和高pH下溶解的凝胶的聚合物或聚合物体系处理井的一部分的方法公开(公告)号：US07932215B2
公开(公告)日：2011-04-26
申请号：US12381482
申请日：2009-03-12
摘要： Methods for treating a portion of a well include the steps of: (a) forming a treatment gel comprising a polymer or a polymer system of a mixture of two or more polymers, wherein the polymer or the polymer system is capable of each of the following, when tested at at least one concentration in the range of 2-10 times C* in deionized water, at about 22° C., and at about 1 atmosphere pressure: (i) forming a polymer gel of the polymer and water at at least one pH in the range of 4-9, wherein a bulk form of the polymer gel has a G′ greater than G″ at all frequencies in the range of 1 rad/sec-100 rad/sec; (ii) dissolving at at least one pH in the range of 2-4; and (iii) dissolving at at least one pH in the range of 9-12; (b) dispersing the treatment gel in a fluid to form a treatment fluid; (c) introducing the treatment gel in a treatment fluid into a portion of a well; and (d) after the step of introducing the treatment gel, adjusting the pH of the treatment gel to at least one pH in the range of 2-4 or 9-12.
摘要翻译： 用于处理井的一部分的方法包括以下步骤：（a）形成包含两种或更多种聚合物的混合物的聚合物或聚合物体系的处理凝胶，其中聚合物或聚合物体系能够具有以下各项 当在去离子水中，在约22℃和约1大气压下以至少一个2-10倍C *的浓度范围进行测试时，（i）在聚合物和水的聚合物凝胶上形成聚合物凝胶 在4-9范围内的至少一个pH值，其中在1弧度/秒-100弧度/秒范围内的所有频率下，本体形式的聚合物凝胶具有大于G的G' （ii）在2-4的至少一个pH下溶解; 和（iii）在至少一个pH为9-12的范围内溶解; （b）将处理凝胶分散在流体中以形成处理流体; （c）将处理液中的处理凝胶引入井的一部分; 和（d）在引入处理凝胶的步骤之后，将处理凝胶的pH调节至2-4或9-12的至少一个pH。
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5.发明授权Methods of treating a portion of a well with a polymer or polymer system capable of forming a gel that dissolves at a low and high pH 有权用能够形成在低和高pH下溶解的凝胶的聚合物或聚合物体系处理井的一部分的方法公开(公告)号：US07928041B2
公开(公告)日：2011-04-19
申请号：US12381535
申请日：2009-03-12
摘要： Methods for treating a portion of a well include the steps of: (a) forming a treatment gel comprising a polymer or a polymer system of a mixture of two or more polymers, wherein the polymer or the polymer system is capable of each of the following, when tested at least one concentration in the range of 2-10 times C* in deionized water, at about 22° C., and at about 1 atmosphere pressure: (i) forming a polymer gel of the polymer and water at least one pH in the range of 4-9, wherein a bulk form of the polymer gel has a G′ greater than G″ at all frequencies in the range of 1 rad/sec-100 rad/sec; (ii) dissolving at least one pH in the range of 2-4; and (iii) dissolving at least one pH in the range of 9-12; (b) dispersing the treatment gel in a fluid to form a treatment fluid; (c) introducing the treatment gel in a treatment fluid into a portion of a well; and (d) after the step of introducing the treatment gel, adjusting the pH of the treatment gel to at least one pH in the range of 2-4 or 9-12.
摘要翻译： 用于处理井的一部分的方法包括以下步骤：（a）形成包含两种或更多种聚合物的混合物的聚合物或聚合物体系的处理凝胶，其中聚合物或聚合物体系能够具有以下各项 当在去离子水，约22℃和约1大气压下测试2-10倍C *范围内的至少一种浓度时，（i）形成聚合物和水的聚合物凝胶至少一种 pH范围为4-9，其中散装形式的聚合物凝胶在1rad / sec-100rad / sec范围内的所有频率具有大于G的G' （ii）将至少一个pH溶解在2-4的范围内; 和（iii）将至少一种pH溶解在9-12的范围内; （b）将处理凝胶分散在流体中以形成处理流体; （c）将处理液中的处理凝胶引入井的一部分; 和（d）在引入处理凝胶的步骤之后，将处理凝胶的pH调节至2-4或9-12的至少一个pH。
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6.发明申请公开(公告)号：US20100256023A1
公开(公告)日：2010-10-07
申请号：US12768577
申请日：2010-04-27
申请人： Richard W. Pauls , Ian D. Robb , Bobby J. Bums
发明人： Richard W. Pauls , Ian D. Robb , Bobby J. Bums
IPC分类号： C09K8/90
摘要： The invention provides a method for treating a subterranean formation penetrated by a wellbore, the method comprising the steps of formulating a treatment fluid and introducing the treatment fluid through the wellbore. The treatment fluid comprises water; diutan; and a sufficient amount of salt to increase the density of the treatment fluid to at least 8.5 lb/gal, wherein at least 50% by weight of the salt is selected from the group consisting of: bromide salts, non-bromide salts having a higher salting-in effect than bromide according to the Hofmeister series as measured by the salt's effect on the cloud point of poly(ethylene oxide) that has a molecular weight of 4×106, and any combination in any proportion thereof. The invention also provides a treatment fluid for use in a subterranean formation penetrated by a wellbore, the treatment fluid comprising: water; diutan; and a sufficient amount of salt to increase the density of the treatment fluid to at least 8.5 lb/gal, wherein at least 50% by weight of the salt is selected from the group consisting of: bromide salts, non-bromide salts having a higher salting-in effect than bromide according to the Hofmeister series as measured by the salt's effect on the cloud point of poly(ethylene oxide) that has a molecular weight of 4.106, and any combination in any proportion thereof.
摘要翻译： 本发明提供了一种处理井眼穿透的地层的方法，所述方法包括配制处理流体并通过井筒引入处理流体的步骤。 处理液包含水; di an 和足够量的盐以将处理流体的密度增加至至少8.5lb / gal，其中至少50重量％的盐选自：溴化物盐，具有较高浓度的溴化物盐，非溴化物盐 通过盐对分子量为4×10 6的聚（环氧乙烷）的浊点的影响测定的Hofmeister系列的盐析效果以及任何比例的任何组合。 本发明还提供一种用于在井眼穿透的地层中的处理流体，所述处理流体包括：水; di an 和足够量的盐以将处理流体的密度增加至至少8.5lb / gal，其中至少50重量％的盐选自：溴化物盐，具有较高浓度的溴化物盐，非溴化物盐 通过盐对分子量为4.106的聚（环氧乙烷）的浊点的影响测定的根据Hofmeister系列的溴化物的盐析效果以及任何比例的任何组合。
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7.发明申请Methods of treating a portion of a well with a polymer or polymer system capable of forming a gel that dissolves at a low and high pH 有权用能够形成在低和高pH下溶解的凝胶的聚合物或聚合物体系处理井的一部分的方法公开(公告)号：US20100234251A1
公开(公告)日：2010-09-16
申请号：US12381535
申请日：2009-03-12
IPC分类号： C09K8/588
摘要： Methods for treating a portion of a well include the steps of: (a) forming a treatment gel comprising a polymer or a polymer system of a mixture of two or more polymers, wherein the polymer or the polymer system is capable of each of the following, when tested at least one concentration in the range of 2-10 times C* in deionized water, at about 22° C., and at about 1 atmosphere pressure: (i) forming a polymer gel of the polymer and water at least one pH in the range of 4-9, wherein a bulk form of the polymer gel has a G′ greater than G″ at all frequencies in the range of 1 rad/sec-100 rad/sec; (ii) dissolving at least one pH in the range of 2-4; and (iii) dissolving at least one pH in the range of 9-12; (b) dispersing the treatment gel in a fluid to form a treatment fluid; (c) introducing the treatment gel in a treatment fluid into a portion of a well; and (d) after the step of introducing the treatment gel, adjusting the pH of the treatment gel to at least one pH in the range of 2-4 or 9-12.
摘要翻译： 用于处理井的一部分的方法包括以下步骤：（a）形成包含两种或更多种聚合物的混合物的聚合物或聚合物体系的处理凝胶，其中聚合物或聚合物体系能够具有以下各项 当在去离子水，约22℃和约1大气压下测试2-10倍C *范围内的至少一种浓度时，（i）形成聚合物和水的聚合物凝胶至少一种 pH范围为4-9，其中散装形式的聚合物凝胶在1rad / sec-100rad / sec范围内的所有频率具有大于G的G' （ii）将至少一个pH溶解在2-4的范围内; 和（iii）将至少一种pH溶解在9-12的范围内; （b）将处理凝胶分散在流体中以形成处理流体; （c）将处理液中的处理凝胶引入井的一部分; 和（d）在引入处理凝胶的步骤之后，将处理凝胶的pH调节至2-4或9-12的至少一个pH。
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8.发明申请Methods and Compositions of Controlling the Rheology of a Diutan-Containing Well Treatment Fluid at High Temperatures 有权在高温下控制含二氧化aining井处理液的流变学的方法和组成公开(公告)号：US20100216673A1
公开(公告)日：2010-08-26
申请号：US12543244
申请日：2009-08-18
申请人： Richard W. Pauls , Ian D. Robb , Bobby J. Burns
发明人： Richard W. Pauls , Ian D. Robb , Bobby J. Burns
IPC分类号： C09K8/90
摘要： The invention provides a method for treating a subterranean formation penetrated by a wellbore, the method comprising the steps of formulating a treatment fluid and introducing the treatment fluid through the wellbore. The treatment fluid comprises water; diutan; and a sufficient amount of salt to increase the density of the treatment fluid to at least 8.5 lb/gal, wherein at least 50% by weight of the salt is selected from the group consisting of: bromide salts, non-bromide salts having a higher salting-in effect than bromide according to the Hofmeister series as measured by the salt's effect on the cloud point of poly(ethylene oxide) that has a molecular weight of 4×106, and any combination in any proportion thereof. The invention also provides a treatment fluid for use in a subterranean formation penetrated by a wellbore, the treatment fluid comprising: water; diutan; and a sufficient amount of salt to increase the density of the treatment fluid to at least 8.5 lb/gal, wherein at least 50% by weight of the salt is selected from the group consisting of: bromide salts, non-bromide salts having a higher salting-in effect than bromide according to the Hofmeister series as measured by the salt's effect on the cloud point of poly(ethylene oxide) that has a molecular weight of 4.106, and any combination in any proportion thereof.
摘要翻译： 本发明提供了一种处理井眼穿透的地层的方法，所述方法包括配制处理流体并通过井筒引入处理流体的步骤。 处理液包含水; di an 和足够量的盐以将处理流体的密度增加至至少8.5lb / gal，其中至少50重量％的盐选自：溴化物盐，具有较高浓度的溴化物盐，非溴化物盐 通过盐对分子量为4×10 6的聚（环氧乙烷）的浊点的影响测定的Hofmeister系列的盐析效果以及任何比例的任何组合。 本发明还提供一种用于在井眼穿透的地层中的处理流体，所述处理流体包括：水; di an 和足够量的盐以将处理流体的密度增加至至少8.5lb / gal，其中至少50重量％的盐选自：溴化物盐，具有较高浓度的溴化物盐，非溴化物盐 通过盐对分子量为4.106的聚（环氧乙烷）的浊点的影响测定的根据Hofmeister系列的溴化物的盐析效果以及任何比例的任何组合。
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9.发明授权Methods and compositions for thermally treating a conduit used for hydrocarbon production or transmission to help remove paraffin wax buildup 有权用于热处理用于烃生产或传输的导管以帮助去除石蜡堆积的方法和组合物公开(公告)号：US07624743B2
公开(公告)日：2009-12-01
申请号：US11521530
申请日：2006-09-14
CPC分类号： E21B36/008 , B01J31/04 , B01J31/06 , B08B9/027 , C09K8/524 , C09K8/536 , E21B37/06 , E21B43/01 , F16L53/30 , F17D1/17 , F17D1/18 , F17D3/16
摘要： Methods are provided for increasing the temperature of a section of conduit used for the production or transmission of hydrocarbon. According to one aspect, the method includes the steps of: (a) forming a treatment fluid comprising: (i) a carrier fluid; and (ii) a first reactant and a second reactant; and (b) introducing the treatment fluid into a section of conduit used for the production or transmission of hydrocarbon. The first reactant and second reactant are selected for being capable of reacting together in an exothermic chemical reaction; and the first and second reactant are in at least sufficient concentrations in the carrier fluid to generate a theoretical heat of reaction of at least 1,000 kJ/liter of the treatment fluid. At least some of at least one of the first reactant and the second reactant is suspended in the carrier fluid in a solid form that is adapted to help control the release of the reactant into the carrier fluid.
摘要翻译： 提供了用于增加用于生产或传输烃的导管段的温度的方法。 根据一个方面，该方法包括以下步骤：（a）形成处理流体，包括：（i）载体流体; 和（ii）第一反应物和第二反应物; 和（b）将处理流体引入用于生产或传输碳氢化合物的导管部分。 选择第一反应物和第二反应物以在放热化学反应中一起反应; 并且第一和第二反应物在载体流体中至少具有足够的浓度以产生至少1,000kJ /升处理流体的理论反应热。 第一反应物和第二反应物中的至少一种中的至少一种以固体形式悬浮在载体流体中，其适于帮助控制反应物释放到载体流体中。
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10.发明授权Acidic treatment fluids comprising scleroglucan and/or diutan and associated methods 有权含有硬葡聚糖和/或二萜的酸性处理液和相关方法公开(公告)号：US07621334B2
公开(公告)日：2009-11-24
申请号：US11118028
申请日：2005-04-29
申请人： Thomas D. Welton , Richard W. Pauls , Ian D. Robb
发明人： Thomas D. Welton , Richard W. Pauls , Ian D. Robb
摘要： In one embodiment, a method is provided comprising: providing an acidic treatment fluid that comprises a gelling agent that comprises an aqueous base fluid, an acid, and a gelling agent that comprises scleroglucan and/or diutan; and introducing the acidic treatment fluid into a subterranean formation.
摘要翻译： 在一个实施方案中，提供了一种方法，其包括：提供包含胶凝剂的酸性处理流体，所述胶凝剂包含含水基础流体，酸和包含硬葡聚糖和/或二脱氧的胶凝剂; 并将酸性处理流体引入地层中。
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