公开(公告)号：US5051390A

公开(公告)日：1991-09-24

申请号：US419580

申请日：1989-10-10

申请人： Paul A. Diddams ,  Ian R. Little ,  Steven R. Wade

发明人： Paul A. Diddams ,  Ian R. Little ,  Steven R. Wade

IPC分类号： B01J27/08 ,  B01J23/34 ,  B01J27/10 ,  C07B61/00 ,  C07C2/84 ,  C10G50/00 ,  C10G57/02

CPC分类号： B01J27/10 ,  B01J23/34 ,  C07C2/84 ,  C07C2527/10

摘要： A process for the preparation of a cogel catalyst comprises preparing an aqueous solution containing a soluble compound of an alkali or alkaline earth metal, a soluble metal compound which is thermally decomposable to a metal oxide capable of converting methane to higher hydrocarbons and a hydrolysable silane under such conditions that a homogenous cogel is formed. The cogel catalyst is effective for oxidizing methane to higher hydrocarbons and exhibits greater selectivity and lasts longer than conventional prior art catalysts. A process for using the cogel catalyst to effect oxidation of methane is also described.

公开(公告)号：US5214016A

公开(公告)日：1993-05-25

申请号：US862163

申请日：1992-04-02

申请人： James F. Brazdil ,  Ian R. Little ,  Joseph B. Hazen

发明人： James F. Brazdil ,  Ian R. Little ,  Joseph B. Hazen

IPC分类号： B01J23/14 ,  B01J23/22 ,  B01J37/02 ,  B01J37/08 ,  C07B61/00 ,  C07C253/24 ,  C07C255/07 ,  C07F7/22

CPC分类号： B01J23/14 ,  B01J23/22 ,  B01J37/0236 ,  B01J37/086 ,  C07C253/24 ,  Y02P20/52

摘要： Disclosed is a method of making a catalyst containing vanadium antimony and tin in the oxide state which comprises making an aqueous slurry of a mixture of source batch materials comprising compounds of the elements to be included in the final catalyst followed by drying and heat calcining the mixture to an active catalyst, using as the source batch material for tin a stannous salt of a C.sub.1 to C.sub.18 acyclic, monocarboxylic acid containing no ethylenic or acetylenic carbon-to-carbon unsaturation.