公开(公告)号：US07547332B2

公开(公告)日：2009-06-16

申请号：US11359466

申请日：2006-02-23

申请人： Peter Scier Christensen ,  Thomas Rostrup Nielsen ,  Niels Erikstrup ,  Kim Assberg-Petersen ,  Jens-Henrik Bak Hansen ,  Ib Dybkjer

发明人： Peter Scier Christensen ,  Thomas Rostrup Nielsen ,  Niels Erikstrup ,  Kim Assberg-Petersen ,  Jens-Henrik Bak Hansen ,  Ib Dybkjer

IPC分类号： B01J7/00

CPC分类号： C01B3/382 ,  C01B3/384 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0816 ,  C01B2203/0844 ,  C01B2203/1011 ,  C01B2203/1035 ,  C01B2203/143 ,  Y02P20/129 ,  Y02P20/142

摘要： Process and apparatus for the preparation of synthesis gas by catalytic steam and/or CO2 reforming of a hydrocarbon feedstock comprising the following steps: (a) heating the reaction mixture of hydrocarbon and steam and/or CO2 in a heated steam reforming unit integrated with the flue gas containing waste heat section from the fired tubular reformer in which reforming of the reaction mixture takes place by contact with a solid reforming catalyst (b) feeding the partially steam reformed mixture to the fired tubular reformer and further reforming the mixture to the desired composition and temperature, wherein the heated steam reforming unit comprises a piping system containing reaction sections with solid reforming catalyst comprising catalyst pellets and/or catalysed structured elements, the piping system being part of the process gas piping system integrated with the flue gas-containing waste heat section.

摘要翻译： 用于通过烃原料的催化蒸汽和/或CO 2重整制备合成气的方法和装置，包括以下步骤：（a）在加热的蒸汽重整单元中加热烃和蒸汽和/或CO 2的反应混合物， 含有来自燃烧管式重整器的废热段的烟气，其中通过与固体重整催化剂（b）接触进行反应混合物的重整，所述固体重整催化剂（b）将部分蒸汽重整的混合物进料到烧制的管式重整器中，并进一步将混合物重整成所需组成 和温度，其中所述加热的蒸汽重整单元包括管道系统，其包含具有包含催化剂颗粒和/或催化的结构化元素的固体重整催化剂的反应段，所述管道系统是与含烟道气的废热集成的工艺气体管道系统的一部分 部分。

公开(公告)号：US20060143984A1

公开(公告)日：2006-07-06

申请号：US11359466

申请日：2006-02-23

申请人： Peter Christensen ,  Thomas Nielsen ,  Niels Erikstrup ,  Kim Assberg-Petersen ,  Jens-Henrik Hansen ,  Ib Dybkjer

发明人： Peter Christensen ,  Thomas Nielsen ,  Niels Erikstrup ,  Kim Assberg-Petersen ,  Jens-Henrik Hansen ,  Ib Dybkjer

IPC分类号： B01J7/00 ,  H01M8/06 ,  B01J8/00 ,  B01J8/04

CPC分类号： C01B3/382 ,  C01B3/384 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0816 ,  C01B2203/0844 ,  C01B2203/1011 ,  C01B2203/1035 ,  C01B2203/143 ,  Y02P20/129 ,  Y02P20/142

摘要： Process and apparatus for the preparation of synthesis gas by catalytic steam and/or CO2 reforming of a hydrocarbon feedstock comprising the following steps: (a) heating the reaction mixture of hydrocarbon and steam and/or CO2 in a heated steam reforming unit integrated with the flue gas containing waste heat section from the fired tubular reformer in which reforming of the reaction mixture takes place by contact with a solid reforming catalyst (b) feeding the partially steam reformed mixture to the fired tubular reformer and further reforming the mixture to the desired composition and temperature, wherein the heated steam reforming unit comprises a piping system containing reaction sections with solid reforming catalyst comprising catalyst pellets and/or catalysed structured elements, the piping system being part of the process gas piping system integrated with the flue gas-containing waste heat section.

摘要翻译： 通过烃原料的催化蒸汽和/或CO 2重整制备合成气的方法和装置，包括以下步骤：（a）加热烃和蒸汽和/或CO的反应混合物， 在与来自燃烧的管状重整器的含有废热部分的废气的一体化的加热蒸汽重整单元中，其中反应混合物的重整通过与固体重整催化剂（b）接触而进行的，所述固体重整催化剂（b） 重整混合物到烧制的管式重整器中，并进一步将混合物重整成所需的组成和温度，其中加热的蒸汽重整单元包括含有反应段的管道系统，固体重整催化剂包含催化剂颗粒和/或催化的结构化元素，管道系统 与含烟气的废热段集成的工艺气体管道系统的一部分。

公开(公告)号：US07074347B2

公开(公告)日：2006-07-11

申请号：US10669375

申请日：2003-09-25

申请人： Niels Erikstrup ,  Thomas Rostrup-Nielsen ,  Peter Seier Christensen ,  Jens-Henrik Bak Hansen ,  Ib Dybkjer ,  Kim Aasberg-Petersen

发明人： Niels Erikstrup ,  Thomas Rostrup-Nielsen ,  Peter Seier Christensen ,  Jens-Henrik Bak Hansen ,  Ib Dybkjer ,  Kim Aasberg-Petersen

IPC分类号： C01B3/26

CPC分类号： C10G2/32 ,  C01B3/382 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/062 ,  C01B2203/0844 ,  C01B2203/1011 ,  C01B2203/1023 ,  C01B2203/141 ,  C01B2203/142 ,  C01B2203/148 ,  C01B2203/82 ,  Y02P20/52

摘要： Process for the production of synthesis gas by catalytic steam reforming of a hydrocarbon containing feedstock in parallel in an autothermal steam reformer and in one or more steam reformers in series, the heat for the steam reforming reactions in the one or more steam reformers being provided by indirect heat exchange with the combined effluents from the one or more steam reformers with the autothermal steam reformer, and wherein carbon monoxide containing gas is added to the feedstock prior to the steam reforming in the autothermal steam reformer and/or prior to the steam reforming in the one or more steam reformers, the carbon monoxide containing gas having a molar ratio of hydrogen to carbon of less than 4.5 and being added in an amount resulting in a product stream having a molar ratio of hydrogen to carbon monoxide of between about 1.8 and 2.3.

摘要翻译： 通过在自热蒸汽重整器和一个或多个蒸汽重整器中并联的含烃原料的催化蒸汽重整制备合成气的方法，一个或多个蒸汽重整器中的蒸汽重整反应的热量由 与来自一个或多个蒸汽重整器的混合流出物与自热蒸汽重整器的间接热交换，并且其中在自热蒸汽重整器中的蒸汽重整之前和/或在蒸汽重整之前将一氧化碳的气体加入原料中 所述一种或多种蒸汽重整器，含有一氧化碳的气体，氢与碳的摩尔比小于4.5，加入量使氢与一氧化碳的摩尔比在约1.8至2.3之间的产物流 。