摘要:
Process for the production of synthesis gas by catalytic steam reforming of a hydrocarbon containing feedstock in parallel in an autothermal steam reformer and in one or more steam reformers in series, the heat for the steam reforming reactions in the one or more steam reformers being provided by indirect heat exchange with the combined effluents from the one or more steam reformers with the autothermal steam reformer, and wherein carbon monoxide containing gas is added to the feedstock prior to the steam reforming in the autothermal steam reformer and/or prior to the steam reforming in the one or more steam reformers, the carbon monoxide containing gas having a molar ratio of hydrogen to carbon of less than 4.5 and being added in an amount resulting in a product stream having a molar ratio of hydrogen to carbon monoxide of between about 1.8 and 2.3.
摘要:
Process and system for the production of synthesis gas from a hydrocarbon feed stock comprising the steps of endothermic and/or adiabatic catalytic steam reforming and autothermal steam reforming in series, wherein the steam reforming is carried out in one or more endothermic stages in series or in one or more adiabatic steam reforming stages in series with intermediate heating of feed stock gas leaving the adiabatic reforming stages and wherein carbon monoxide containing gas characterised by having a molar ratio of hydrogen to carbon of less than 4.5 is added prior to at least one of the endothermic or adiabatic steam reforming stages and/or prior to the autothermal steam reforming step.
摘要:
Process and system for the production of synthesis gas from a hydrocarbon feed stock comprising the steps of endothermic and/or adiabatic catalytic steam reforming and autothermal steam reforming in series, wherein the steam reforming is carried out in one or more endothermic stages in series or in one or more adiabatic steam reforming stages in series with intermediate heating of feed stock gas leaving the adiabatic reforming stages and wherein carbon monoxide containing gas characterised by having a molar ratio of hydrogen to carbon of less than 4.5 is added prior to at least one of the endothermic or adiabatic steam reforming stages and/or prior to the autothermal steam reforming step.
摘要:
Process and apparatus for the preparation of synthesis gas by catalytic steam and/or CO2 reforming of a hydrocarbon feedstock comprising the following steps: (a) heating the reaction mixture of hydrocarbon feedstock and steam and/or CO2 in the flue gas containing waste heat section from the fired tubular reformer (b) adiabatic reforming of the reaction mixture outside the waste heat section by contact with a solid reforming catalyst (c) repeating steps (a) and (b) until the desired reaction mixture composition and temperature is reached (d) feeding the reaction mixture to the fired tubular reformer and further reforming the mixture to the desired composition and temperature, wherein the adiabatic reforming of the reaction mixture is conducted in the process gas piping system in the flue gas-containing waste heat section, the piping system having adiabatic zones outside the heating section and containing solid reforming catalysts comprising one or more catalyzed structured elements.
摘要:
Process and apparatus for the preparation of synthesis gas by catalytic steam and/or CO2 reforming of a hydrocarbon feedstock comprising the following steps: (a) heating the reaction mixture of hydrocarbon and steam and/or CO2 in a heated steam reforming unit integrated with the flue gas containing waste heat section from the fired tubular reformer in which reforming of the reaction mixture takes place by contact with a solid reforming catalyst (b) feeding the partially steam reformed mixture to the fired tubular reformer and further reforming the mixture to the desired composition and temperature, wherein the heated steam reforming unit comprises a piping system containing reaction sections with solid reforming catalyst comprising catalyst pellets and/or catalysed structured elements, the piping system being part of the process gas piping system integrated with the flue gas-containing waste heat section.
摘要:
Process and apparatus for the preparation of synthesis gas by catalytic steam and/or CO2 reforming of a hydrocarbon feedstock comprising the following steps: (a) heating the reaction mixture of hydrocarbon and steam and/or CO2 in a heated steam reforming unit integrated with the flue gas containing waste heat section from the fired tubular reformer in which reforming of the reaction mixture takes place by contact with a solid reforming catalyst (b) feeding the partially steam reformed mixture to the fired tubular reformer and further reforming the mixture to the desired composition and temperature, wherein the heated steam reforming unit comprises a piping system containing reaction sections with solid reforming catalyst comprising catalyst pellets and/or catalysed structured elements, the piping system being part of the process gas piping system integrated with the flue gas-containing waste heat section.
摘要:
Process for preparation of a hydrogen and/or carbon monoxide rich gas by catalytic autothermal reforming of a hydrocarbon feedstock containing higher hydrocarbons in an autothermal reformer comprising the further steps of (a) passing the hydrocarbon feedstock through a reactor containing steam reforming catalyst to remove or reduce the contents of higher hydrocarbons in the hydrocarbon feedstock; (b) passing the effluent from the first reactor to an autothermal reformer; and (c) withdrawing from the autothermal reformer a product gas rich in hydrogen and carbon monoxide.
摘要:
Process for the catalytic steam reforming of a hydrocarbon feed stock with a content of higher hydrocarbons and oxygen comprising the steps of catalytic pre-reforming the feed stock and steam reforming the pre-reformed feed stock, the pre-reforming step is carried out in presence of a fixed bed catalyst comprising at least a portion of a noble metal catalyst being active in oxidation of hydrocarbons to carbon oxides and conversion of higher hydrocarbons to methane, wherein the noble metal catalyst is supported on a carrier of MgO and/or MgAl2O4 spinel.
摘要翻译:具有高级烃和氧含量的烃原料的催化蒸汽重整的方法包括催化预重整原料和对重整前的原料进行蒸汽重整的步骤,预重整步骤在存在下进行 的固定床催化剂,其包含至少一部分贵金属催化剂,其在将烃氧化成碳氧化物和将高级烃转化为甲烷时具有活性,其中所述贵金属催化剂负载在MgO和/或MgAl 2 O 4尖晶石的载体上。
摘要:
Process for the preparation of a hydrogen and/or carbonmonoxide rich gas comprising the step of partial oxidation of a hydrocarbon feedstock with an oxygen containing reactant stream in presence of steam, wherein the steam is present in the hydrocarbon feedstock in an amount higher than in the oxygen containing reactant stream.
摘要:
Process for the steam reforming of hydrocarbons comprising contacting a feed gas with a catalyst consisting of an active compound in the form of an alloy of nickel and one of iridium, rhodium and ruthenium, on a support comprising alumina, zirconia, magnesia, titania, or combinations thereof.