Method for the preparation of reactive compositions containing hydrogen peroxide
    1.
    发明申请
    Method for the preparation of reactive compositions containing hydrogen peroxide 失效
    制备含有过氧化氢的反应性组合物的方法

    公开(公告)号:US20090012346A1

    公开(公告)日:2009-01-08

    申请号:US12078004

    申请日:2008-03-26

    CPC classification number: C01B15/027 A62D3/38 A62D2101/02 C01B15/01 C01B15/032

    Abstract: The subject invention provides a potentially economically viable method for the preparation of hydrogen peroxide (H2O2) in deep eutectic solvents (DES). H2O2 is then used for the destruction of small to large quantities of sulfur and nitrogen mustards and lewisite, their homologous/analogues, and similar chemical warfare agents at ambient conditions in DES without producing any toxic by-products. Furthermore, H2O2 has been used for the destruction of small to large quantities of halogenated hydrocarbons, their homologous/analogues, and similar hazardous chemicals at ambient conditions. H2O2 can be formed by either the electrochemical reduction of oxygen in DES in the presence of water or by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in DES in the presence of water, with/without chemicals used for the enhancement of the solubility of the metal superoxide in the DES, e.g. crown ethers.

    Abstract translation: 本发明提供了在深共晶溶剂(DES)中制备过氧化氢(H 2 O 2)的潜在的经济可行的方法。 然后,H 2 O 2用于在环境条件下在DES中破坏小量至大量的硫和氮芥末和蛭石,它们的同源/类似物和类似的化学战剂,而不产生任何有毒的副产物。 此外,H2O2已被用于在环境条件下破坏小到大量的卤代烃,它们的同源/类似物和类似的有害化学物质。 H 2 O 2可以通过在水的存在下在DES中的电化学还原或通过溶解第1族(碱金属)或第2族(碱土金属)超氧化物,例如, 钾过氧化物,在有水存在下的DES中,有/没有用于提高金属超氧化物在DES中的溶解度的化学品,例如。 冠醚。

    Process for the destruction of sulfur and nitrogen mustards and their homologous/analogous at ambient conditions
    2.
    发明申请
    Process for the destruction of sulfur and nitrogen mustards and their homologous/analogous at ambient conditions 有权
    在环境条件下破坏硫和氮芥末及其同源/类似物的方法

    公开(公告)号:US20120149963A1

    公开(公告)日:2012-06-14

    申请号:US12078001

    申请日:2008-03-26

    CPC classification number: A62D3/38 A62D3/11 A62D2101/02 A62D2203/04

    Abstract: The subject invention provides a potentially economically viable process for the destruction of small to large quantities of sulfur and nitrogen mustards and lewisite, their homologous/analogues, and similar chemical warfare agents at ambient conditions without producing any toxic by-products. The process uses the superoxide ion that is either electrochemically generated by the reduction of oxygen in ionic liquids or chemically by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in ionic liquids.

    Abstract translation: 本发明提供了一种潜在的经济可行的方法,用于在环境条件下破坏小量至大量的硫和氮芥末和蛭石,它们的同源/类似物和类似的化学战剂,而不产生任何有毒的副产物。 该方法使用通过在离子液体中还原氧而电化学产生的超氧化物离子,或通过溶解第1族(碱金属)或第2族(碱土金属)超氧化物,例如, 钾离子液体中的超氧化物。

    Method for the preparation of reactive compositions containing superoxide ion
    3.
    发明授权
    Method for the preparation of reactive compositions containing superoxide ion 有权
    制备含超氧化物离子的反应性组合物的方法

    公开(公告)号:US08147792B2

    公开(公告)日:2012-04-03

    申请号:US12078011

    申请日:2008-03-26

    CPC classification number: C25B1/00 C25B3/00

    Abstract: The subject invention provides a potentially economically viable method for the preparation of reactive superoxide ion in deep eutectic solvents (DES). The superoxide ion can be used for many applications, e.g. the degradation of hazardous chemicals at ambient conditions or in the synthesis of some special chemicals, e.g. carboxylic acids, aldehydes, and ketones from the corresponding alcohols. The superoxide ion can be formed by either the electrochemical reduction of oxygen in DES or by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in DES, with/without chemicals used for the enhancement of the solubility of the metal superoxide in the DES, e.g. crown ethers.

    Abstract translation: 本发明提供了在深共晶溶剂(DES)中制备反应性超氧化物离子的潜在的经济可行的方法。 超氧化物离子可用于许多应用,例如 在环境条件下或某些特殊化学品的合成中危险化学品的降解,例如 羧酸,醛和酮。 超氧化物离子可以通过电化学还原DES中的氧或通过溶解第1族(碱金属)或第2族(碱土金属)超氧化物来形成。 超过氧化钾,在DES中,有/没有用于增强金属超氧化物在DES中的溶解度的化学品,例如。 冠醚。

    Process for the destruction of sulfur and nitrogen mustards, lewisite, and their homologous/analogues in deep eutectic solvents
    4.
    发明申请
    Process for the destruction of sulfur and nitrogen mustards, lewisite, and their homologous/analogues in deep eutectic solvents 有权
    在深层共晶溶剂中破坏硫和氮芥末,蛭石及其同源/类似物的方法

    公开(公告)号:US20120149964A1

    公开(公告)日:2012-06-14

    申请号:US12078012

    申请日:2008-03-26

    CPC classification number: A62D3/38 A62D3/11 A62D2101/02 A62D2203/04

    Abstract: The subject invention provides a potentially economically viable process for the destruction of small to large quantities of sulfur and nitrogen mustards and lewisite, their homologous/analogues, and similar chemical warfare agents at ambient conditions without producing any toxic by-products. The process uses the superoxide ion that is either electrochemically generated by the reduction of oxygen in deep eutectic solvents or chemically by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in deep eutectic solvents.

    Abstract translation: 本发明提供了一种潜在的经济可行的方法,用于在环境条件下破坏小量至大量的硫和氮芥末和蛭石,它们的同源/类似物和类似的化学战剂,而不产生任何有毒的副产物。 该方法使用超氧化物离子,其通过在低共晶溶剂中的氧还原而电化学产生,或通过将第1族(碱金属)或第2族(碱土金属)超氧化物,例如, 钾超氧化物,在深共晶溶剂中。

    Process for the destruction of sulfur and nitrogen mustards, lewisite, and their homologous/analogues in deep eutectic solvents
    5.
    发明授权
    Process for the destruction of sulfur and nitrogen mustards, lewisite, and their homologous/analogues in deep eutectic solvents 有权
    在深层共晶溶剂中破坏硫和氮芥末,蛭石及其同源/类似物的方法

    公开(公告)号:US08420881B2

    公开(公告)日:2013-04-16

    申请号:US12078012

    申请日:2008-03-26

    CPC classification number: A62D3/38 A62D3/11 A62D2101/02 A62D2203/04

    Abstract: The subject invention provides a potentially economically viable process for the destruction of small to large quantities of sulfur and nitrogen mustards and lewisite, their homologous/analogues, and similar chemical warfare agents at ambient conditions without producing any toxic by-products. The process uses the superoxide ion that is either electrochemically generated by the reduction of oxygen in deep eutectic solvents or chemically by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in deep eutectic solvents.

    Abstract translation: 本发明提供了一种潜在的经济可行的方法,用于在环境条件下破坏小量至大量的硫和氮芥末和蛭石,它们的同源/类似物和类似的化学战剂,而不产生任何有毒的副产物。 该方法使用超氧化物离子,其通过在低共晶溶剂中的氧还原而电化学产生,或通过将第1族(碱金属)或第2族(碱土金属)超氧化物,例如, 钾超氧化物,在深共晶溶剂中。

    Method for the preparation of reactive hydrogen peroxide in deep eutectic solvents
    6.
    发明授权
    Method for the preparation of reactive hydrogen peroxide in deep eutectic solvents 失效
    深层共晶溶剂中反应性过氧化氢的制备方法

    公开(公告)号:US07763768B2

    公开(公告)日:2010-07-27

    申请号:US12078004

    申请日:2008-03-26

    CPC classification number: C01B15/027 A62D3/38 A62D2101/02 C01B15/01 C01B15/032

    Abstract: The subject invention provides a potentially economically viable method for the preparation of hydrogen peroxide (H2O2) in deep eutectic solvents (DES). H2O2 is then used for the destruction of small to large quantities of sulfur and nitrogen mustards and lewisite, their homologous/analogues, and similar chemical warfare agents at ambient conditions in DES without producing any toxic by-products. Furthermore, H2O2 has been used for the destruction of small to large quantities of halogenated hydrocarbons, their homologous/analogues, and similar hazardous chemicals at ambient conditions. H2O2 can be formed by either the electrochemical reduction of oxygen in DES in the presence of water or by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in DES in the presence of water, with/without chemicals used for the enhancement of the solubility of the metal superoxide in the DES, e.g. crown ethers.

    Abstract translation: 本发明提供了在深共晶溶剂(DES)中制备过氧化氢(H 2 O 2)的潜在的经济可行的方法。 然后,H 2 O 2用于在环境条件下在DES中破坏小量至大量的硫和氮芥末和蛭石,它们的同源/类似物和类似的化学战剂,而不产生任何有毒的副产物。 此外,H2O2已被用于在环境条件下破坏小到大量的卤代烃,它们的同源/类似物和类似的有害化学物质。 H 2 O 2可以通过在水的存在下在DES中的电化学还原或通过溶解第1族(碱金属)或第2族(碱土金属)超氧化物,例如, 钾过氧化物,在有水存在下的DES中,有/没有用于提高金属超氧化物在DES中的溶解度的化学品,例如。 冠醚。

    Process for the destruction of sulfur and nitrogen mustards and their homologous/analogous at ambient conditions
    7.
    发明授权
    Process for the destruction of sulfur and nitrogen mustards and their homologous/analogous at ambient conditions 有权
    在环境条件下破坏硫和氮芥末及其同源/类似物的方法

    公开(公告)号:US08618346B2

    公开(公告)日:2013-12-31

    申请号:US12078001

    申请日:2008-03-26

    CPC classification number: A62D3/38 A62D3/11 A62D2101/02 A62D2203/04

    Abstract: The subject invention provides a potentially economically viable process for the destruction of small to large quantities of sulfur and nitrogen mustards and lewisite, their homologous/analogues, and similar chemical warfare agents at ambient conditions without producing any toxic by-products. The process uses the superoxide ion that is either electrochemically generated by the reduction of oxygen in ionic liquids or chemically by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in ionic liquids.

    Abstract translation: 本发明提供了一种潜在的经济可行的方法,用于在环境条件下破坏小量至大量的硫和氮芥末和蛭石,它们的同源/类似物和类似的化学战剂,而不产生任何有毒的副产物。 该方法使用通过在离子液体中还原氧而电化学产生的超氧化物离子,或通过溶解第1族(碱金属)或第2族(碱土金属)超氧化物,例如, 钾离子液体中的超氧化物。

    Process for the destruction of halogenated hydrocarbons and their homologous/analogous in deep eutectic solvents at ambient conditions
    8.
    发明授权
    Process for the destruction of halogenated hydrocarbons and their homologous/analogous in deep eutectic solvents at ambient conditions 有权
    在环境条件下,在深层共晶溶剂中破坏卤代烃及其同源/类似物的方法

    公开(公告)号:US07812211B2

    公开(公告)日:2010-10-12

    申请号:US12078002

    申请日:2008-03-26

    CPC classification number: A62D3/38 A62D2101/22

    Abstract: The subject invention provides a potentially economically viable process for the destruction of small to large quantities of halogenated hydrocarbons, their homologous/analogues, and similar hazardous chemicals at ambient conditions using superoxide ion in deep eutectic solvents. The superoxide ion is either electrochemically generated by the reduction of oxygen in deep eutectic solvents or chemically by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in deep eutectic solvents.

    Abstract translation: 本发明提供了在环境条件下使用超低分子离子在深共晶溶剂中破坏小到大量的卤代烃,它们的同源/类似物和类似的有害化学物质的潜在的经济可行的方法。 超氧化物离子是通过在低共晶溶剂中氧还原产生电化学反应,或通过溶解第1族(碱金属)或第2族(碱土金属)超氧化物, 钾超氧化物,在深共晶溶剂中。

    Process for the destruction of halogenated hydrocarbons and their homologous/analogous at ambient conditions
    9.
    发明申请
    Process for the destruction of halogenated hydrocarbons and their homologous/analogous at ambient conditions 有权
    用于在环境条件下破坏卤代烃及其同源/类似物的方法

    公开(公告)号:US20090012345A1

    公开(公告)日:2009-01-08

    申请号:US12078002

    申请日:2008-03-26

    CPC classification number: A62D3/38 A62D2101/22

    Abstract: The subject invention provides a potentially economically viable process for the destruction of small to large quantities of halogenated hydrocarbons, their homologous/analogues, and similar hazardous chemicals at ambient conditions using superoxide ion in deep eutectic solvents. The superoxide ion is either electrochemically generated by the reduction of oxygen in deep eutectic solvents or chemically by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in deep eutectic solvents.

    Abstract translation: 本发明提供了在环境条件下使用超低分子离子在深共晶溶剂中破坏小到大量的卤代烃,它们的同源/类似物和类似的有害化学物质的潜在的经济可行的方法。 超氧化物离子是通过在低共晶溶剂中氧还原产生电化学反应,或通过溶解第1族(碱金属)或第2族(碱土金属)超氧化物, 钾超氧化物,在深共晶溶剂中。

    New method for the preparation of reactive compositions containing superoxide ion
    10.
    发明申请
    New method for the preparation of reactive compositions containing superoxide ion 有权
    用于制备含超氧化物离子的反应性组合物的新方法

    公开(公告)号:US20090008262A1

    公开(公告)日:2009-01-08

    申请号:US12078011

    申请日:2008-03-26

    CPC classification number: C25B1/00 C25B3/00

    Abstract: The subject invention provides a potentially economically viable method for the preparation of reactive superoxide ion in deep eutectic solvents (DES). The superoxide ion can be used for many applications, e.g. the degradation of hazardous chemicals at ambient conditions or in the synthesis of some special chemicals, e.g. carboxylic acids, aldehydes, and ketones from the corresponding alcohols. The superoxide ion can be formed by either the electrochemical reduction of oxygen in DES or by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in DES, with/without chemicals used for the enhancement of the solubility of the metal superoxide in the DES, e.g. crown ethers.

    Abstract translation: 本发明提供了在深共晶溶剂(DES)中制备反应性超氧化物离子的潜在的经济可行的方法。 超氧化物离子可用于许多应用,例如 在环境条件下或某些特殊化学品的合成中危险化学品的降解,例如 羧酸,醛和酮。 超氧化物离子可以通过电化学还原DES中的氧或通过溶解第1族(碱金属)或第2族(碱土金属)超氧化物来形成。 超过氧化钾,在DES中,有/没有用于增强金属超氧化物在DES中的溶解度的化学品,例如。 冠醚。

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