Method of destructing toxic chemicals

    公开(公告)号:US11331527B2

    公开(公告)日:2022-05-17

    申请号:US15775403

    申请日:2015-11-12

    摘要: There are disclosed processes for destructing a toxic chemical including the steps of mixing the toxic chemical with a liquid phase formed by an aqueous mixture of water and an ionic liquid or molten salt which is miscible with water, the ionic liquid or molten salt comprising a tertiary amine group or quaternary ammonium group; and contacting the toxic chemical in the liquid phase with the ionic liquid or molten salt so as to decompose the toxic chemical.

    Method for dehalogenation detoxication of halogenated aromatic and/or cyclic compounds
    5.
    发明授权
    Method for dehalogenation detoxication of halogenated aromatic and/or cyclic compounds 有权
    卤代芳族和/或环状化合物的脱卤解毒方法

    公开(公告)号:US07767873B2

    公开(公告)日:2010-08-03

    申请号:US10582649

    申请日:2004-04-28

    IPC分类号: A62D3/34 A62D101/22

    摘要: A method for dehalogenation detoxication of halogenated aromatic and/or cyclic compounds, based on the fact that at least one halogenated aromatic and/or cyclic compound is heated on a support matrix in a closed system at a temperature of 200 to 500° C. in the presence of copper in metallic form and/or in the form of copper compounds, a hydrogen donor, carbon and at least one additional reducing substance, capable of reducing cupric and cuprous ions to elemental copper at the above temperature.

    摘要翻译: 一种卤代芳族化合物和/或环状化合物的脱卤解毒方法,基于以下事实:至少一种卤代芳族化合物和/或环状化合物在封闭体系中在200至500℃的温度下在载体基质上加热 金属形式的铜和/或铜化合物,氢供体,碳和至少一种另外的还原物质形式的铜的存在,能够在上述温度下将铜和亚铜离子还原成元素铜。

    Method for the preparation of reactive compositions containing hydrogen peroxide
    8.
    发明申请
    Method for the preparation of reactive compositions containing hydrogen peroxide 失效
    制备含有过氧化氢的反应性组合物的方法

    公开(公告)号:US20090012346A1

    公开(公告)日:2009-01-08

    申请号:US12078004

    申请日:2008-03-26

    IPC分类号: A62D3/34 C09K3/00 A62D3/37

    摘要: The subject invention provides a potentially economically viable method for the preparation of hydrogen peroxide (H2O2) in deep eutectic solvents (DES). H2O2 is then used for the destruction of small to large quantities of sulfur and nitrogen mustards and lewisite, their homologous/analogues, and similar chemical warfare agents at ambient conditions in DES without producing any toxic by-products. Furthermore, H2O2 has been used for the destruction of small to large quantities of halogenated hydrocarbons, their homologous/analogues, and similar hazardous chemicals at ambient conditions. H2O2 can be formed by either the electrochemical reduction of oxygen in DES in the presence of water or by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in DES in the presence of water, with/without chemicals used for the enhancement of the solubility of the metal superoxide in the DES, e.g. crown ethers.

    摘要翻译: 本发明提供了在深共晶溶剂(DES)中制备过氧化氢(H 2 O 2)的潜在的经济可行的方法。 然后,H 2 O 2用于在环境条件下在DES中破坏小量至大量的硫和氮芥末和蛭石,它们的同源/类似物和类似的化学战剂,而不产生任何有毒的副产物。 此外,H2O2已被用于在环境条件下破坏小到大量的卤代烃,它们的同源/类似物和类似的有害化学物质。 H 2 O 2可以通过在水的存在下在DES中的电化学还原或通过溶解第1族(碱金属)或第2族(碱土金属)超氧化物,例如, 钾过氧化物,在有水存在下的DES中,有/没有用于提高金属超氧化物在DES中的溶解度的化学品,例如。 冠醚。