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公开(公告)号：US4500473A
公开(公告)日：1985-02-19
申请号：US478033
申请日：1983-03-23
CPC分类号： C07C51/56
摘要： Carboxylic acid anhydrides of the formula RCO--O--COR', e.g., acetic anhydride, are facilely prepared by reacting, in an essentially anhydrous, liquid phase containing an aprotic organic solvent, (i) a compound of the formula RX, (ii) a carboxylate of the formula (R'COO.sup.-).sub.n A.sup.n+, and (iii) carbon monoxide, said reaction being carried out in the presence of a catalytically effective amount of a salt of cobalt tetracarbonyl halide, at a temperature ranging from about 0.degree. to 200.degree. C. and under a pressure which is less than or equal to about 600 bars.
摘要翻译： 通过在基本上无水的含有非质子有机溶剂的液相中反应制备式RCO-O-COR'的羧酸酐，例如乙酸酐，（i）式RX的化合物，（ii） 式（R'COO-）nAn +的羧酸酯和（iii）一氧化碳，所述反应在催化有效量的四羰基钴卤化物的存在下进行，温度范围为约0℃至 并且在小于或等于约600巴的压力下。
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公开(公告)号：US4426537A
公开(公告)日：1984-01-17
申请号：US260811
申请日：1981-05-05
IPC分类号： B01J23/00 , B01J27/00 , B01J27/20 , B01J31/00 , C07C51/00 , C07C51/12 , C07C53/00 , C07C53/08 , C07C67/00
CPC分类号： C07C51/12
摘要： Carboxylic acids having the structural formula R.sup.1 COOH, wherein R.sup.1 is a linear, branched or cyclic chain alkyl radical of from 1 to 6 carbon atoms or a phenyl-C.sub.n H.sub.2n -radical wherein 1.ltoreq.n.ltoreq.6, are prepared by carbonylating an alcohol having the formula R.sup.1 -OH with carbon monoxide in liquid phase, in the presence of a catalytically effective amount of nickel and an alkyl or acyl halide promoter therefor, at a temperature of at least about 120.degree. C. and under a total pressure of less than 200 bars, and said carbonylation being carried out in the presence of at least one lanthanide salt, and in an initial carboxylic acid reaction medium having the formula R.sup.2 -COOH, wherein R.sup.2 is defined as was R.sup.1 above, and further wherein R.sup.1 and R.sup.2 may be the same or different.
摘要翻译： 具有结构式R 1 COOH的羧酸，其中R 1是具有1至6个碳原子的直链，支链或环状链烷基或苯基-C n H 2n - ，其中n 1 = n 6，是通过羰基化 具有式R 1 -OH的醇与一氧化碳在液相中，在催化有效量的镍和其烷基或酰卤促进剂存在下，在至少约120℃的温度和总压力 并且所述羰基化在至少一种镧系元素盐存在下进行，并且在具有式R 2 -COOH的初始羧酸反应介质中进行，其中R2定义为R 1，其中R 1和 R2可以相同或不同。
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公开(公告)号：US4997978A
公开(公告)日：1991-03-05
申请号：US261635
申请日：1988-10-24
IPC分类号： C07C67/36 , B01J27/00 , B01J31/00 , C07B61/00 , C07C27/00 , C07C51/12 , C07C67/00 , C07C69/14
CPC分类号： C07C51/12
摘要： Alkyl carboxylates of the formula:R--CO--O--CH.sub.2 R'are prepared by hydrocarbonylating a compound of the formula:R--CO--O--R'in the simultaneous presence, in the reaction medium, of cobalt, ruthenium, an alkyl iodide and an ionic iodide, the atomic ratio Co/Ru being less than or equal to 1, and the total amount of iodine-containing promoters present in the medium being such that I/Ru is greater than or equal to 5.
摘要翻译： 式R-CO-O-CH 2 R'的烷基羧酸盐通过在反应介质中同时存在钴，钌，烷基碘和 离子碘化物，原子比Co / Ru小于或等于1，介质中存在的含碘促进剂的总量使得I / Ru大于或等于5。
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公开(公告)号：US4619791A
公开(公告)日：1986-10-28
申请号：US435752
申请日：1982-10-21
CPC分类号： C07C51/56
摘要： Methyl acetate is carbonylated to acetic anhydride with carbon monoxide, in liquid phase, in an anhydrous reaction medium, in the presence of a catalytically effective amount of (i) nickel, (ii) methyl iodide, (iii) an alkali metal iodide, and (iv) a crown ether.
摘要翻译： 在催化有效量的（ⅰ）镍，（ⅱ）甲基碘，（ⅲ）碱金属碘化物和（ⅲ）碱金属碘化物的存在下，乙酸甲酯与一氧化碳在液相中，在无水反应介质中， （iv）冠醚。
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5.发明授权Preparation of alkali or alkaline earth metal cobalttetracarbonylates and catalysts of carbonylation reactions therewith 失效制备碱金属或碱土金属钴四羰基化物及其羰基化反应催化剂
公开(公告)号：US4576809A
公开(公告)日：1986-03-18
申请号：US549553
申请日：1983-11-07
CPC分类号： C01G51/006 , C01G51/02 , C01P2006/82
摘要： Alkali or alkaline earth metal cobalttetracarbonylates well suited for catalyzing carbonylation reactions, e.g., the carbonylation of organic compounds comprising halomethyl functions, are facilely prepared by reacting a cobalt (II) compound with carbon monoxide in the presence of (i) an inorganic base which comprises an alkali or alkaline earth metal hydroxide or an alkali or alkaline earth metal bicarbonate and (ii) at least one sulfur compound having at least one sulfur atom, the oxidation state of which being no greater than +3, and in a reaction medium comprising water, an alcohol, an ether, or admixture of water and an alcohol or an ether.
摘要翻译： 非常适合催化羰基化反应的碱金属或碱土金属钴四钴酸盐，例如羰基化反应，例如包含卤代甲基官能团的有机化合物的羰基化，可以通过在（i）无机碱存在下使钴（II）化合物与一氧化碳反应来制备，所述无机碱包括 碱金属或碱土金属氢氧化物或碱金属或碱土金属碳酸氢盐和（ii）至少一种具有至少一个硫原子的硫化合物，其氧化态不大于+3，并且在包含水的反应介质中 ，醇，乙醚或水和醇或醚的混合物。
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公开(公告)号：US4436889A
公开(公告)日：1984-03-13
申请号：US260810
申请日：1981-05-05
IPC分类号： C07C53/00 , B01J23/00 , B01J27/00 , B01J31/00 , C07C51/00 , C07C51/12 , C07C53/08 , C07C57/32 , C07C67/00 , C07C53/134 , C07C57/30
CPC分类号： C07C51/12
摘要： Carboxylic acids having the structural formula R.sup.1 COOH, wherein R.sup.1 is a linear, branched or cyclic chain alkyl radical of from 1 to 6 carbon atoms or a phenyl-C.sub.n H.sub.2n -radical wherein 1.ltoreq.n.ltoreq.6, are prepared by carbonylating an alcohol having the formula R.sup.1 -OH with carbon monoxide in liquid phase, in the presence of a catalytically effective amount of nickel and an alkyl or acyl halide promoter therefor, at a temperature of at least about 120.degree. C. and under a total pressure of less than 200 bars, and said carbonylation being carried out in the presence of at least one vanadium compound in which the vanadium is in an oxidation state of 4 or 5, and in an initial carboxylic acid reaction medium having the formula R.sup.2 -COOH, wherein R.sup.2 is defined as was R.sup.1 above, and further wherein R.sup.1 and R.sup.2 may be the same or different.
摘要翻译： 具有结构式R 1 COOH的羧酸，其中R 1是具有1至6个碳原子的直链，支链或环状链烷基或苯基-C n H 2n - ，其中n 1 = n 6，是通过羰基化 具有式R 1 -OH的醇与一氧化碳在液相中，在催化有效量的镍和其烷基或酰卤促进剂存在下，在至少约120℃的温度和总压力 所述羰基化反应在至少一种钒化合物的存在下进行，其中钒处于4或5的氧化态，并且在具有式R2-COOH的初始羧酸反应介质中进行，其中 R2定义为上述R 1，并且其中R 1和R 2可以相同或不同。
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公开(公告)号：US4431835A
公开(公告)日：1984-02-14
申请号：US280218
申请日：1981-07-06
IPC分类号： C07C69/14 , B01J23/00 , B01J27/00 , B01J31/00 , C07B61/00 , C07C27/00 , C07C29/147 , C07C29/32 , C07C29/36 , C07C45/00 , C07C45/49 , C07C47/06 , C07C51/12 , C07C67/00 , C07C67/36
摘要： Alkyl carboxylates are hydrocarbonylated and/or carbonylated with carbon monoxide and hydrogen, in an aqueous medium, and in the presence of a catalytically effective amount of a catalyst system comprising (i) ruthenium, (ii) cobalt, (iii) at least one iodine-containing promoter, and (iv) chromium. The subject hydrocarbonylation/carbonylation is admirably well suited, e.g., for the preparation of acetaldehyde, ethanol, ethyl acetate and acetic acid, especially from a methyl carboxylate.
摘要翻译： 在水性介质中，在催化有效量的催化剂体系存在下，羧酸烷基酯在一氧化碳和氢气下进行烃基化和/或羰基化，包括（ⅰ）钌，（ⅱ）钴，（ⅲ）至少一种碘 （iv）铬。 本发明的烃基化/羰基化是非常适合的，例如用于制备乙醛，乙醇，乙酸乙酯和乙酸，特别是甲酸甲酯。
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公开(公告)号：US4618460A
公开(公告)日：1986-10-21
申请号：US585625
申请日：1984-03-07
CPC分类号： C07C51/56
摘要： The invention relates to a process for the preparation of acetic anhydride by carbonylation. In the process, carbon monoxide is reacted with methyl acetate in the liquid phase, in a carboxylic acid, in the presence of an effective amount of nickel, methyl iodide, an ionic iodide selected from the group consisting of quaternary ammonium iodides, quaternary phosphonium iodides, sodium iodide, potassium iodide and cesium iodide, and a co-catalyst selected from the group consisting of lithium salts and alkaline earth metal salts.
摘要翻译： 本发明涉及通过羰基化制备乙酸酐的方法。 在该过程中，一氧化碳与乙酸甲酯在液相中，在羧酸中，在有效量的镍，碘甲烷，碘化季铵，季碘化鏻， ，碘化钠，碘化钾和碘化铯，以及选自锂盐和碱土金属盐的助催化剂。
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公开(公告)号：US4609504A
公开(公告)日：1986-09-02
申请号：US331828
申请日：1981-12-17
CPC分类号： C07C51/56
摘要： The invention relates to a process for the preparation of acetic anhydride by carbonylation. In the process, carbon monoxide is reacted with methyl acetate in an anhydrous medium, in the liquid phase, in the presence of an effective amount of nickel, methyl iodide, a quaternary ammonium or quaternary phosphonium iodide and a lithium salt, the reaction medium initially containing acetic anhydride, if desired.
摘要翻译： 本发明涉及通过羰基化制备乙酸酐的方法。 在该过程中，一氧化碳与无水介质中的乙酸甲酯在液相中，在有效量的镍，甲基碘，季铵或季碘化鏻和锂盐的存在下反应，反应介质最初 如果需要，含有乙酸酐。
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公开(公告)号：US4500474A
公开(公告)日：1985-02-19
申请号：US387467
申请日：1982-06-11
IPC分类号： C07C53/12 , B01J31/00 , C07B61/00 , C07C51/00 , C07C51/54 , C07C51/56 , C07C67/00 , C07C51/12
CPC分类号： C07C51/56
摘要： Methyl acetate is carbonylated, advantageously to acetic anhydride, in a homogeneous liquid phase, in a virtually anhydrous reaction medium, in the presence of: (a) a cobalt source, (b) a ruthenium source, (c) an ionic iodide of the formula: A.sup.m+ I.sub.m.sup.- in which A.sup.m+ is a nitrogen group quaternary onium cation, an alkali metal or alkaline earth metal cation, or a lanthanide or actinide group metal cation, (c') if appropriate, a carboxylate of the formula: A'.sup.n+ (OCOR).sub.n.sup.-, in which n is 1 or 2 and A'.sup.n+ is defined as was A.sup.m+, with A'.sup.n+ and A.sup.m+ either being the same or different, and R is an alkyl, aralkyl or aryl radical having a maximum of 8 carbon atoms, and (d) hydrogen, the total amount of halogen compounds present in the carbonylation reaction medium (expressed in gram atoms of halogen and designated by X.sub.T) being such that the atomic ratio X.sub.T /(m.A.sup.m+ +n.A'.sup.n+) is less than or equal to 1.
摘要翻译： 在（a）钴源，（b）钌源的存在下，在几乎无水的反应介质中，乙酸甲酯在均相液相中有利地羰基化，有利地为乙酸酐，（c） 式：Am + Im-其中Am +是氮基季鎓阳离子，碱金属或碱土金属阳离子，或镧系元素或锕系金属阳离子，（c'）如果合适，下式的羧酸酯：A' n +（OCOR）n-，其中n为1或2，A'n +定义为Am +，其中A'n +和Am +相同或不同，R为具有最大值的烷基，芳烷基或芳基 8个碳原子和（d）氢，存在于羰基化反应介质中的卤素化合物的总量（用卤素的克原子表示，由XT表示）使原子比XT /（m.Am ++ n .A'n +）小于或等于1。
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