Emulsions containing ultrahigh viscosity silicone polymers
    2.
    发明授权
    Emulsions containing ultrahigh viscosity silicone polymers 失效
    含有超高粘度硅氧烷聚合物的乳液

    公开(公告)号:US5998537A

    公开(公告)日:1999-12-07

    申请号:US157688

    申请日:1998-09-21

    CPC classification number: C08G77/06

    Abstract: Emulsions containing particles of an organopolysiloxane with an average particle diameter of less than about 100 nanometer are prepared by (i) adding a polyfunctional silane to an aqueous medium containing a nonionic surfactant, an anionic or cationic surfactant, and a catalyst; (ii) allowing the polyfunctional silane to hydrolyze; (iii) adding a cyclic siloxane to the aqueous medium containing the pre-hydrolyzed polyfunctional silane; (iv) copolymerizing the cyclic siloxane and the pre-hydrolyzed polyfunctional silane to form the organopolysiloxane; and (v) continuing copolymerizing step (iv) until the resulting organopolysiloxane has a viscosity greater than about 100,000,000 centipoise (mPa.multidot.s).

    Abstract translation: 通过(i)在含有非离子表面活性剂,阴离子或阳离子表面活性剂和催化剂的水性介质中加入多官能硅烷,制备含有平均粒径小于约100纳米的有机聚硅氧烷颗粒的乳液; (ii)使多官能硅烷水解; (iii)向包含预水解的多官能硅烷的水性介质中加入环状硅氧烷; (iv)使环状硅氧烷和预水解的多官能硅烷共聚以形成有机聚硅氧烷; 和(v)连续共聚步骤(iv),直到得到的有机聚硅氧烷具有大于约100,000,000厘泊(mPaxs)的粘度。

    Silicone pressure sensitive adhesive compositions
    3.
    发明授权
    Silicone pressure sensitive adhesive compositions 有权
    硅胶压敏粘合剂组合物

    公开(公告)号:US06545086B1

    公开(公告)日:2003-04-08

    申请号:US09969565

    申请日:2001-10-01

    CPC classification number: C08J3/03 C08J2383/04 C08L83/00 C09J183/04

    Abstract: A pressure sensitive adhesive emulsion comprises a disperse silicone phase emulsified in a continuous water phase in the presence of a surfactant. The disperse silicone phase comprises 40-80 percent by weight of a silicone pressure sensitive adhesive, which is the product of mixing a silanol-terminated polydiorganosiloxane of Tg below −20° C. with a silanol-containing silicone resin of Tg above 0° C., dispersed in 60-20 percent by weight of a volatile silicone fluid having a boiling point below 300° C. The emulsion is substantially free of any non-silicon atom containing volatile organic material.

    Abstract translation: 压敏粘合剂乳液包含在表面活性剂存在下在连续水相中乳化的分散硅氧烷相。 分散有机硅相包含40-80重量%的硅氧烷压敏粘合剂,其是将Tg低于-20℃的硅烷醇封端的聚二有机硅氧烷与Tg高于0℃的含硅烷醇的有机硅树脂混合的产物 分散在60-20重量%的沸点低于300℃的挥发性硅氧烷流体中。该乳液基本上不含任何含有非挥发性有机材料的非硅原子。

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