公开(公告)号：US07611598B2

公开(公告)日：2009-11-03

申请号：US11638939

申请日：2006-12-14

申请人： Steven E. Baker ,  Jeffrey L. Antle ,  Donald R. Holman

发明人： Steven E. Baker ,  Jeffrey L. Antle ,  Donald R. Holman

IPC分类号： D02G3/00

CPC分类号： C03C25/26 ,  B29C70/50 ,  C03C25/28 ,  C03C25/36 ,  C08L29/04 ,  C08L63/00 ,  C08L2205/02 ,  Y10T428/249924 ,  Y10T428/249944 ,  Y10T428/249946 ,  Y10T428/249948 ,  Y10T428/2933 ,  Y10T428/2962 ,  Y10T428/2964 ,  C08L2666/02

摘要： An aqueous glass fiber sizing composition that includes a polymeric film forming component, at least one silane coupling agent, and one or more lubricants is provided. The polymeric film forming component of the sizing composition includes a silanated polyvinyl acetate, an epoxidized polyvinyl acetate, and a modified epoxy emulsion. In preferred embodiments, the film formers are present in the sizing composition in ratios of 70:25:5, 50:25:25, or 63:18:18 of silanated polyvinyl acetate, epoxidized polyvinyl acetate, and modified epoxy emulsion respectively. Fibers sized with the sizing composition in a sheet molding compound process have improved wet-out characteristics.

摘要翻译： 提供了包含聚合物成膜组分，至少一种硅烷偶联剂和一种或多种润滑剂的含水玻璃纤维上胶组合物。 上浆组合物的聚合物成膜组分包括硅烷化聚乙酸乙烯酯，环氧化聚乙酸乙烯酯和改性环氧乳液。 在优选实施方案中，成膜剂分别以硅烷化聚乙酸乙烯酯，环氧化聚乙酸乙烯酯和改性环氧乳液的比例分别为70:25:5:50:25:25或63:18:18存在于施胶组合物中。 在片状模塑复合方法中用施胶组合物尺寸的纤维具有改善的浸湿特性。

公开(公告)号：US07169463B2

公开(公告)日：2007-01-30

申请号：US10872926

申请日：2004-06-21

申请人： Steven E. Baker ,  Jeffrey L. Antle ,  Donald R. Holman

发明人： Steven E. Baker ,  Jeffrey L. Antle ,  Donald R. Holman

IPC分类号： B32B17/02 ,  D06M13/224

CPC分类号： C03C25/26 ,  B29C70/50 ,  C03C25/28 ,  C03C25/36 ,  C08L29/04 ,  C08L63/00 ,  C08L2205/02 ,  Y10T428/249924 ,  Y10T428/249944 ,  Y10T428/249946 ,  Y10T428/249948 ,  Y10T428/2933 ,  Y10T428/2962 ,  Y10T428/2964 ,  C08L2666/02

摘要： An aqueous glass fiber sizing composition that includes a polymeric film forming component, at least one silane coupling agent, and one or more lubricants is provided. The polymeric film forming component of the sizing composition includes a silanated polyvinyl acetate, an epoxidized polyvinyl acetate, and a modified epoxy emulsion. In preferred embodiments, the film formers are present in the sizing composition in ratios of 70:25:5, 50:25:25, or 63:18:18 of silanated polyvinyl acetate, epoxidized polyvinyl acetate, and modified epoxy emulsion respectively. Fibers sized with the sizing composition in a sheet molding compound process have improved wet-out characteristics.

公开(公告)号：US07083855B2

公开(公告)日：2006-08-01

申请号：US10383372

申请日：2003-03-07

申请人： Adrian C. Lane ,  Jeffrey L. Antle

发明人： Adrian C. Lane ,  Jeffrey L. Antle

IPC分类号： B32B27/38 ,  B32B27/04 ,  D06M15/55 ,  D06M15/643 ,  C03C25/10

CPC分类号： B29C70/50 ,  B29K2061/04 ,  B29K2063/00 ,  B32B5/28 ,  C03C25/36 ,  C03C25/40 ,  C08L63/00 ,  H05K1/0366 ,  Y10T428/24994 ,  Y10T428/249948 ,  Y10T428/31511 ,  Y10T428/31663 ,  Y10T442/2402

摘要： A binder slurry for a continuous filament mat used in a phenolic pultrusion system comprising a phenolic compatible silane, a non-ionic surfactant, a defoamer, water, an organic acid and a bisphenol epoxy powdered resin having a thermally active dicyandiamide cross-linking resin. The binder slurry resin is unique in that the bisphenol epoxy powdered resin having a thermally active dicyandiamide cross-linking resin is compatable with presently available phenolic resins, and as such pultruded parts made have improved surface and mechanical properties as compared with traditional polyester type binder slurries which are not compatable with phenolic resins. Continuous filament mats made with the new binder slurry also may also be made into epoxy prepreg that can be used to make composite parts.

公开(公告)号：US4473618A

公开(公告)日：1984-09-25

申请号：US494204

申请日：1983-05-13

申请人： Leonard J. Adzima ,  Jeffrey L. Antle ,  David E. Musick ,  Fred G. Krautz

发明人： Leonard J. Adzima ,  Jeffrey L. Antle ,  David E. Musick ,  Fred G. Krautz

IPC分类号： C03C25/26 ,  C08K3/40

CPC分类号： C03C25/26 ,  Y10T428/2938 ,  Y10T428/2956 ,  Y10T428/2958 ,  Y10T428/2962 ,  Y10T428/2967

摘要： Chrome-free aqueous sizing composition for glass fiber gun roving contains a mixture of emulsified film-forming polymers, titanium acetyl acetonate, silylated polyazamide, cationic lubricant and methacryloxypropylsilane.

摘要翻译： 用于玻璃纤维枪粗纱的无铬水性施胶组合物含有乳化成膜聚合物，乙酰丙酮钛，甲硅烷基化的叠氮烷，阳离子润滑剂和甲基丙烯酰氧基丙基硅烷的混合物。

公开(公告)号：US08129018B2

公开(公告)日：2012-03-06

申请号：US11362987

申请日：2006-02-27

申请人： David R. Hartman ,  Luc M. Peters ,  Jeffrey L. Antle

发明人： David R. Hartman ,  Luc M. Peters ,  Jeffrey L. Antle

IPC分类号： B32B17/04 ,  D06M13/50 ,  D06M15/55 ,  D06M15/564

CPC分类号： C03C25/326 ,  B29K2105/06 ,  C03C3/087 ,  C03C13/00 ,  C03C25/26 ,  C03C25/36 ,  C03C25/40 ,  C08G59/245 ,  C08G59/621 ,  C08L63/00 ,  C08L75/04 ,  Y10T428/2933 ,  Y10T428/2962 ,  Y10T428/31525 ,  C08L2666/20

摘要： A sizing composition containing an epoxy film former, a urethane film former, a silane package that includes an aminosilane coupling agent and an epoxy silane coupling agent, a cationic lubricant, a non-ionic lubricant, an antistatic agent, and at least one acid is provided. The epoxy resin emulsion includes a low molecular weight liquid epoxy resin and one or more surfactants. The epoxy resin preferably has an epoxy equivalent weight from 185-192. The sizing composition may optionally contain a methacryloxy silane. The sizing composition may be used to size glass fibers used in filament winding applications to form reinforced composite articles with improved mechanical properties, wet tensile properties, improved resistance to cracking, and improved processing characteristics.

摘要翻译： 包含环氧成膜剂，氨基甲酸酯成膜剂，包含氨基硅烷偶联剂和环氧硅烷偶联剂的硅烷组合物，阳离子润滑剂，非离子润滑剂，抗静电剂和至少一种酸的上胶组合物是 提供。 环氧树脂乳液包括低分子量液体环氧树脂和一种或多种表面活性剂。 环氧树脂的环氧当量优选为185-192。 上胶组合物可任选地含有甲基丙烯酰氧基硅烷。 施胶组合物可用于对用于丝缠绕应用中的玻璃纤维进行定型，以形成具有改进的机械性能，湿拉伸性能，改进的抗开裂性能和改善的加工特性的增强复合制品。