公开(公告)号：US20060079661A1

公开(公告)日：2006-04-13

申请号：US11247655

申请日：2005-10-11

申请人： Huide Zhu ,  Andrew Kneisel ,  Syed Mahdi ,  Jeffrey Saracsan

发明人： Huide Zhu ,  Andrew Kneisel ,  Syed Mahdi ,  Jeffrey Saracsan

IPC分类号： C08G18/00

CPC分类号： C08G18/12 ,  C08G18/4812 ,  C08G18/7664 ,  C08G18/7671 ,  C08J5/124 ,  C08J2327/06 ,  C09J175/04 ,  C09J175/08 ,  C09J201/025 ,  C08G18/289 ,  C08G18/2825 ,  C08G18/307 ,  C08G18/792 ,  C08G18/2895

摘要： In one aspect the invention is a composition comprising a prepolymer which is the reaction product of di(isocyanatophenyl)methane or a polymeric di(isocyanatophenyl)methane having an isocyanato functionality of about 2.1 to about 3.0 with a mixture of one or more diols and one or more triols wherein the ratio of isocyanate equivalents to hydroxyl equivalents in the reaction mixtures used to prepare the prepolymer is from about 1.2 to about 1.8 and the ratio of diol to triol where the diisocyanate is a di(isocyanatophenyl)methane in the reaction mixture is from about 5:1 to about 1:1. and where the isocyanate is a polymeric di(isocyanatophenyl)methane is from about 8:1 to about 4:1; wherein the prepolymer could further react with an isocyanate reactive monofunctional compound. The prepolymer herein has an isocyanate content of about 0.5 to about 1.5 percent by weight, a free isocyanate monomer content of about 1.0 percent by weight or less as measured by high pressure liquid chromatography. These prepolymers can be used in many applications including adhesive, sound dampening sealer and coating and especially in making adhesives or adhesive systems with a low content of monomeric isocyanate to bond together similar or dissimilar substrates such as metal, glass, ceramics, plastic and painted steel panel.

摘要翻译： 在一个方面，本发明是一种组合物，其包含预聚物，其是二（异氰酸根合苯基）甲烷或具有约2.1至约3.0的异氰酸酯官能度的聚合二（异氰酸酯基苯基）甲烷的反应产物与一种或多种二醇和一种 或更多的三醇，其中用于制备预聚物的反应混合物中异氰酸酯当量与羟基当量的比例为约1.2至约1.8，二异氰酸酯是反应混合物中二异氰酸酯基甲烷的二醇与三醇的比例为 约5：1至约1：1。 并且其中异氰酸酯是聚合二（异氰酸酯基苯基）甲烷为约8:1至约4:1; 其中所述预聚物可以进一步与异氰酸酯反应性单官能化合物反应。 本文的预聚物具有约0.5至约1.5重量％的异氰酸酯含量，通过高压液相色谱法测量的约1.0重量％或更少的游离异氰酸酯单体含量。 这些预聚物可用于许多用途，包括粘合剂，防声封闭剂和涂料，特别是在制备具有低含量单体异氰酸酯的粘合剂或粘合剂体系以将类似或不同的基材如金属，玻璃，陶瓷，塑料和涂漆钢板粘合在一起 面板。

公开(公告)号：US20080041522A1

公开(公告)日：2008-02-21

申请号：US11924114

申请日：2007-10-25

申请人： Huide Zhu ,  Andrew Kneisel ,  Syed Mahdi ,  Jeffrey Saracsan

发明人： Huide Zhu ,  Andrew Kneisel ,  Syed Mahdi ,  Jeffrey Saracsan

IPC分类号： C09J201/06 ,  C08G18/10

CPC分类号： C08G18/12 ,  C08G18/4812 ,  C08G18/7664 ,  C08G18/7671 ,  C08J5/124 ,  C08J2327/06 ,  C09J175/04 ,  C09J175/08 ,  C09J201/025 ,  C08G18/289 ,  C08G18/2825 ,  C08G18/307 ,  C08G18/792 ,  C08G18/2895

摘要： In one aspect the invention is a composition comprising a prepolymer which is the reaction product of di(isocyanatophenyl) methane or a polymeric di(isocyanatophenyl) methane having an isocyanato functionality of about 2.1 to about 3.0 with a mixture of one or more diols and one or more triols wherein the ratio of isocyanate equivalents to hydroxyl equivalents in the reaction mixtures used to prepare the prepolymer is from about 1.2 to about 1.8 and the ratio of diol to triol where the diisocyanate is a di(isocyanatophenyl) methane in the reaction mixture is from about 5:1 to about 1:1. and where the isocyanate is a polymeric di(isocyanatophenyl) methane is from about 8:1 to about 4:1; wherein the prepolymer could further react with an isocyanate reactive monofunctional compound. The prepolymer herein has an isocyanate content of about 0.5 to about 1.5 percent by weight, a free isocyanate monomer content of about 1.0 percent by weight or less as measured by high pressure liquid chromatography. These prepolymers can be used in many applications including adhesive, sound dampening sealer and coating and especially in making adhesives or adhesive systems with a low content of monomeric isocyanate to bond together similar or dissimilar substrates such as metal, glass, ceramics, plastic and painted steel panel.

摘要翻译： 在一个方面，本发明是一种组合物，其包含预聚物，其是二（异氰酸根合苯基）甲烷或具有约2.1至约3.0的异氰酸酯官能度的聚合二（异氰酸酯基苯基）甲烷的反应产物与一种或多种二醇和一种 或更多的三醇，其中用于制备预聚物的反应混合物中异氰酸酯当量与羟基当量的比例为约1.2至约1.8，二异氰酸酯是反应混合物中二异氰酸酯基甲烷的二醇与三醇的比例为 约5：1至约1：1。 并且其中异氰酸酯是聚合二（异氰酸酯基苯基）甲烷为约8:1至约4:1; 其中所述预聚物可以进一步与异氰酸酯反应性单官能化合物反应。 本文的预聚物具有约0.5至约1.5重量％的异氰酸酯含量，通过高压液相色谱法测量的约1.0重量％或更少的游离异氰酸酯单体含量。 这些预聚物可用于许多用途，包括粘合剂，防声封闭剂和涂料，特别是在制备具有低含量单体异氰酸酯的粘合剂或粘合剂体系以将类似或不同的基材如金属，玻璃，陶瓷，塑料和涂漆钢板粘合在一起 面板。